Thermal and mechanical properties of poly(lactic Acid) and poly(ethylene/butylene Succinate) blends

In this study, blends of poly (lactic acid) (PLA) with poly(ethylene/butylene succinate) (Bionolle) have been investigated for their thermal and mechanical properties as a function of the concentration of Bionolle. Differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and tensile tests were used to characterize the blends. From the results of the DMA and DSC, it was found that this blend system was not miscible within the compositions studied. DSC results showed that adding Bionolle aids in crystallization of PLA. It was observed that increasing the Bionolle concentration led to a slight increase in the strain-at-break of the blends but a decrease in the Young’s modulus and ultimate tensile strength. Biaxially oriented films showed an increase in tensile strength, modulus, and strain-at-break.     

Growth performance and proximate profile of Telfairia occidentalis Hook F. (cucurbitaceae) grown in crude oil‒contaminated soil

In this study, the growth performance and nutritional quality of Telfairia occidentalis planted in soil polluted with varied levels of water‐soluble fraction (WSF) of crude oil (Bonny light) were evaluated to assess the effectiveness of organic nutrients (poultry manure and sawdust) in the phytore mediation of WSF‐contaminated soil. The results showed that WSF application delayed germination of vegetables. However, treatment of soils with organic nutrients enhanced the germination rate of vegetables, promoted greenish coloration of leafs and increased the levels of energy‐yielding macronutrients (carbohydrate, lipid, and protein). Also, soils supplemented with poultry manure gave the highest caloric values for all the percentages of WSF studied, followed by sawdust. Our findings suggest that the adverse effects of WSF on soil could be remediated through organic nutrient supplementation. © 2006 Wiley Periodicals, Inc.     

Radiogenic Lead Isotopes and Time Stratigraphy in the Hudson River, New York

Radionuclide, radiogenic lead isotope and trace metal analyses on fine-grained sediment cores collected along 160 km of the upper and tidal Hudson River were used to examine temporal trends of contaminant loadings and to develop radiogenic lead isotopes both as a stratigraphic tool and as tracers for resolving decadal particle transport fluxes. Very large inputs of Cd, Sb, Pb, and Cr are evident in the sediment record, potentially from a single manufacturing facility. The total range in radiogenic lead isotope ratios observed in well-dated cores collected about 24 km downstream of the plant is large (e.g., maximum difference in ²⁰⁶Pb/²⁰⁷Pb is 10%), characterized by four major shifts occurring in the 1950s, 1960s, 1970s and 1980s. The upper Hudson signals in Cd and radiogenic lead isotopes were still evident in sediments collected 160 km downstream in the tidal Hudson. The large magnitude and abrupt shifts in radiogenic lead isotope ratios as a function of depth provide sensitive temporal constraints that complement information derived from radionuclide analyses to significantly improve the precision of dating assignments. Application of a simple dilution model to data from paired cores suggests much larger sediment inputs in one section of the river than previously reported, suggesting particle influxes to the Hudson have been underestimated.     

Assessing the Collection of Urban Solid Wastes: A Step Towards Municipality Benchmarking

The assessment of collection systems for municipal wastes is becoming an issue of increasing importance among local authorities. This paper contributes to this task by addressing and discussing a set of parameters that are characterizing certain aspects of the efficiency and effectiveness of the waste collection process. Case-study area for testing this set is the Thessaloniki Urban Area in Northern Greece. Specifically, a set of four evaluation indicators is initially discussed and quantified for each of the 14 considered municipalities, while the multiple-criteria decision support method of Analytical Hierarchy Process is finally applied to globally rank the municipalities. As a result, a classification of all examined municipalities is derived and various conclusions are drawn on certain efficiency and effectiveness aspects of waste collection systems.     

IMPLICATIONS OF ON‐GROUND NITROGEN LOADING AND SOIL TRANSFORMATIONS ON GROUND WATER QUALITY MANAGEMENT1

ABSTRACT: This paper presents a modeling approach based on a geographic information system (GIS) to estimate the variability of on‐ground nitrogen loading and the corresponding nitrate leaching to ground water. The methodology integrates all point and nonpoint sources of nitrogen, the national land cover database, soil nitrogen transformations, and the uncertainty of key soil and land use‐related parameters to predict the nitrate mass leaching to ground water. The analysis considered 21 different land use classes with information derived from nitrogen sources such as fertilizer and dairy manure applications, dairy lagoons, septic systems, and dry and wet depositions. Simulations were performed at a temporal resolution of one month to capture seasonal trends. The model was applied to a large aquifer of 376 square miles in Washington State that serves more than 100,000 residents with drinking water. The results showed that dairy manure is the main source of nitrogen in the area followed by fertilizers. It was also seen that nitrate leaching is controlled by the recharge rate, and there can be a substantial buildup of soil nitrogen over long periods of time. Uncertainty analysis showed that denitrification rate is the most influential parameter on nitrate leaching. The results showed that combining management alternatives is a successful strategy, especially with the use of nitrification inhibitors. Also, change in the land use pattern has a noticeable impact on nitrate leaching.     

City hazardous gas monitoring network

In our today's societies, many dangerous chemicals are produced and transported. Due to the vast use of chemicals, more chemical accidents are taking place with huge losses. In this study a city hazardous gas monitoring network was designed to detect the dispersion of toxic and combustible gases in the primary stages. The network could cover hazardous chemical facilities, important hazardous chemical routes, warehouses and special locations which may be the targets of terrorist attacks. The network is consisted of several local networks and a central control panel complex. Each local network has a local control panel in the center and many detectors and sounders around it at distances less than 3000 m that communicate with the local control panels wirelessly. In each location there are two types of gas detectors, toxic and combustible, and a sounder which are equipped with a wireless, radio frequency modem allowing the units to communicate readings and other information on a real-time basis with a remotely located local control panel. High sensitive Photo Ionization Detectors, PIDs, are used to provide fast and low-level on-site screening for chemicals contamination. Combustible gas detectors are the second choice to sense the combustible gas and verify the readings of PIDs in this regard. The central panel consists of several connected control panels work uniquely helping a computer set and the appropriate software and communicate with local control panels via telephone lines. All of the network components are shown on the monitor of central panel with special symbols by geographical information system program. The system is fully addressable so that the high level detection of a detector produces a blinking color double-circle around its symbol in GIS plan. In case of high level gas detection, a team of experts who are fully equipped with different portable detectors depart to the site to test the field to identify the chemicals. All readings of detectors are saved in a data bank and then analyzed to find any chemicals spills and leakages. The network was simulated by a special program so that the components of local networks and the central panel are shown in separate windows. By clicking on one detector on environmental window the formerly designed responses will be activated in central panel window.     

The effects of parental altruism on the governance of family‐managed firms

We draw on the economic, corporate governance, and family business literatures to explain why the effects of family on family firms makes this governance form theoretically distinct from those of public and private non‐family firms. Our thesis is that parental altruism, when combined with private ownership and owner‐management, influences the ability of the firm's owner‐manager to exercise self‐control, which, in turn, can expose some family firms to conflicts rooted in the agency threats of moral hazard, hold‐up, and adverse selection. We then discuss why some other family firms are able to minimize these dark side threats and thereby attain altruism's brighter side. Finally, we discuss how altruism's influence changes over time as ownership becomes dispersed among family members and across generations. Copyright © 2005 John Wiley & Sons, Ltd.     

An automated wet deposition system to compare the effects of reduced and oxidised N on ombrotrophic bog species: Practical considerations

Critical N loads for ombrotrophic bogs, which often contain rare and N-sensitive plants (especially those in lower plant groups: lichens, mosses and liverworts), are based on very few experimental data from measured, low background N deposition areas. Additionally the relative effects of reduced versus oxidised N are largely unknown. This paper describes an automated field exposure system (30 km S. of Edinburgh, Scotland) for treating ombrotrophic bog vegetation with fine droplets of oxidised N (NaNO₃) and reduced N (NH₄Cl). Whim Moss exists in an area of low ambient N deposition (ca. 8 kg N ha^?1 y^?1), the sources and quantification of which are described. The wet N treatment system is run continuously, and is controlled/activated by wind speed and rainfall to provide a unique simulation of “real worl” treatment patterns (no rain=no treatment). Simulated precipitation is supplied at ionic concentrations below 4 mM in rainwater collected on site. Treatments provide a replicated dose response to 16, 32 and 64 kg N ha^?1 y^?1 adjusted for ambient deposition (8 kg N ha^?1 y^?1). The 16 and 64 kg N ha^?1 y^?1 are duplicated with a P+K supplement. Baseline soil chemistry and foliar nutrient status was established for all 44 plots for Calluna vulgaris, Sphagnum capillifolium, Hypnum jutlandicum and Cladonia portentosa.     

Linking field experiments to long-term simulation of impacts of nitrogen deposition on heathlands and moorlands

The results from three long-term field manipulation studies of the impacts of increased nitrogen deposition (0–120 kg N ha^?1 yr^?1) on lowland and upland heathlands in the UK were compared, to test if common responses are observed. Consistent increases in Calluna foliar N content and decreases in litter C:N ratios were found across all sites, while increases in N leaching were not observed at any site over the range 0–80 kg ha^?1 yr^?1. However, the response of Calluna biomass did vary between sites, possibly reflecting site differences in nutrient status and management histories. Five versions of a simulation model of heathland responses to N were developed, each reflecting different assumptions about the fate and turnover of soil N. Model outputs supported the deduction from mass balance calculations at two of the field sites that N additions have resulted in an increase in immobilisation; the latter was needed to prevent the model overestimating measured N leaching. However, this version of the model significantly underestimated Calluna biomass. Model versions, which included uptake of organic N by Callunaand re-mobilisation of N from the soil organic store provided some improvement in the fit between modelled and field biomass data, but re-mobilisation also led to an overestimation of N leaching. Quantification of these processes and their response to increased N deposition are therefore critical to interpreting experimental data and predicting the long-term impacts of atmospheric deposition on heathlands and moorlands.