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841.
This study was conducted to identify the principle selenate carrier phases for two selected soils, by comparing their reactivity with selenate to that of pure phases of the solids. Silica, calcium carbonate, aluminium hydroxide, goethite, bentonite and humic acid were selected as the main soil carrier phases. Comparisons were made first on the parameter values obtained with the best fit of a kinetic sorption model which can discriminate instantaneous sorption from kinetically limited sorption. Then comparisons were made of the ability for each solid to stabilise selenate by measuring the ratio of the partition coefficient for sorption (Kdsorption) over that of the desorption (Kddesorption). Kinetics and stabilisation were used to help elucidate the nature of interactions with the test solid phases for a large range of selenate concentrations. The experiments were conducted over 165 h in batch reactors, the solid being isolated from the solution by dialysis tubing, at two pH (5.4 and 8) and three selenate concentrations (1 × 10−3, 1 × 10−6 and 1 × 10−8 mol L−1). The results obtained showed that only aluminium hydroxide can sorb selenate throughout the studied pH range (pH 5.4 to 8.0). The sorption capacity on this mineral was high (Kdsorption > 100 to 1 × 104 L kg−1) and the selenate was mainly stabilized by the formation of inner sphere complexes. The sorption on goethite occurred at pH 5.4 (Kdsorption 52 L kg−1), mainly as outer sphere complexes, and was null at pH 8. On silica, a weak sorption was observed only at pH 5.4 and at 165 h (Kdsorption 4 L kg−1). On bentonite, calcium carbonate and humic acid no significant sorption was observed. Concerning the two soils studied, different behaviours were observed for selenate. For soil Ro (pH 5.4), Kdsorption was low (8 L kg−1) compared to soil Bu (pH 8) (70 L kg−1). The sorption behaviour of selenate on soil Ro was mainly due to outer sphere complexes, as for goethite, whereas for soil Bu the sorption was mainly attributed to inner sphere complexes followed by reduction mechanisms, probably initiated by microorganisms, in which no steady state was reached at the end of the 165 h experiments. The sorption of selenate decreased when concentrations reached 1 × 10−3 mol L−1, due to solid saturation, except for aluminium hydroxide. Reduction of selenate seemed also to occur on goethite and soil Ro, for the same concentration, but without preventing a decrease in sorption. Thus, this work shows that the comparison of selenate behaviour between soil and pure phases helps to elucidate the main carrier phases and sorption mechanisms in soil. 相似文献
842.
Kurnaz A Kucukomeroglu B Damla N Cevik U 《Journal of environmental radioactivity》2011,102(4):393-399
The activity concentrations and absorbed gamma dose rates due to primordial radionuclides and 137Cs have been ascertained in 222 soil samples in 18 counties of the Trabzon province of Turkey using a HPGe detector. The mean activity concentrations of 238U, 232Th, 40K and 137Cs in soil samples were 41, 35, 437 and 21 Bq kg−1, respectively. Based on the measured concentrations of these radionuclides, the mean absorbed gamma dose in air was calculated as 59 nGy h−1 and hence, the mean annual effective dose due to terrestrial gamma radiation was calculated as 72 μSv y−1. In addition, outdoor in situ gamma dose rate (D) measurements were performed in the same 222 locations using a portable NaI detector and the annual effective dose was calculated to be 66 μSv y−1 from these results. The results presented in this study are compared with other parts of Turkey. Radiological maps of the Trabzon province were composed using the results obtained from the study. 相似文献
843.
Alexandrova M Rozhko T Vydryakova G Kudryasheva N 《Journal of environmental radioactivity》2011,102(4):407-411
The effect of americium-241 (241Am), an alpha-emitting radionuclide of high specific activity, on luminous bacteria Photobacterium phosphoreum was studied. Traces of 241Am in nutrient media (0.16-6.67 kBq/L) suppressed the growth of bacteria, but enhanced luminescence intensity and quantum yield at room temperature. Lower temperature (4 °C) increased the time of bacterial luminescence and revealed a stage of bioluminescence inhibition after 150 h of bioluminescence registration start. The role of conditions of exposure the bacterial cells to the 241Am is discussed. The effect of 241Am on luminous bacteria was attributed to peroxide compounds generated in water solutions as secondary products of radioactive decay. Increase of peroxide concentration in 241Am solutions was demonstrated; and the similarity of 241Am and hydrogen peroxide effects on bacterial luminescence was revealed. The study provides a scientific basis for elaboration of bioluminescence-based assay to monitor radiotoxicity of alpha-emitting radionuclides in aquatic solutions. 相似文献
844.
V. V. Rozhnov E. Yu. Zvychainaya A. N. Kuksin A. D. Poyarkov 《Russian Journal of Ecology》2011,42(6):439-444
Molecular genetic methods were used to perform the species and individual identification of 117 samples of hair and feces
of carnivores collected in natural habitats. The species were identified for 85.5% of the samples. The analysis of the nucleotide
sequences of the cytochrome b mitochondrial gene was used to identify the samples of hair and feces of snow leopards (Uncia uncia, 40%), red foxes (Vulpes vulpes, 48%), wolves (Canis lupus, 6%), and lynx (Lynx lynx, 5%). The analysis of eight microsatellite loci allowed the genotypes of 13 snow leopards to be described. The sex of 11
animals was identified. 相似文献
845.
The states of the populations of five dominant species of predatory mammals living in the area affected by the Kalinin Nuclear
Power Plant (NPP) and in remote districts of Tver’ oblast have been compared. A total of 1120 skulls, including 708 skulls
from the vicinity of the NPP, have been examined. The data on parameters characterizing similarities between the samples,
the degree and structure of intrapopulation diversity, and ontogenetic stability suggest with a high probability that the
Kalinin NPP has no effect on wild populations of predatory mammals. 相似文献
846.
The results of studies on the radial increment of larch and pine in central Yakutia are presented. The application of dendroclimatological
methods to the study of tree-ring chronologies has made it possible to evaluate tree growth response to the dynamics of climatic
factors over the past 120 years. The results of analysis of radial tree increment show that the onset of the growing season
has shifted to earlier dates by the end of the 20th century. 相似文献
847.
The World Bank used the Consumer Price Index (CPI) to calculate changes in the world poverty level (measured in U.S. dollars)
prior to 1982. In 1983, the U.S. Bureau of Labor Statistics (BLS) replaced the CPI with several indices including CPI-W which
was then adopted by the World Bank. This caused the inflated rate of the U.S. dollars and the percentage of the world population
in poverty to be dramatically underestimated. This new incorrect procedure gives 25% (1.5 million) below the poverty line
in 2005, while the more appropriate procedure (described herein) gives 52% (3.3 million in 2005). The rapid rise of the poverty
line (using the preferable CPI) starting in 1987 occurred at nearly the same time as the peak in per capita annual cereal
production. 相似文献
848.
Pesticide use among smallholder rice farmers in Tanzania 总被引:1,自引:0,他引:1
Nadja Stadlinger Aviti J. Mmochi Sonja Dobo Emma Gyllb?ck Linda Kumblad 《Environment, Development and Sustainability》2011,13(3):641-656
In an interview study conducted among smallholder rice farmers in Rufiji, Tanzania coastal mainland, and in Cheju, Zanzibar, farmer??s pesticide use and risk awareness were assessed. The farmers generally lacked knowledge or possibilities to manage the pesticides as prescribed by the manufacturers. Few farmers knew what kind of pesticides they were using and had never seen the original packages, as pesticides were usually sold per weight or already diluted without labeling. Protective equipment was rarely used since they were not aware of risks associated with pesticides or did not know where to purchase protective gear. Only half of the farmers were aware of pesticides?? health hazards and few associated pesticides with environmental problems. The pesticide use was relatively low, but based on farmers?? pesticide handling and application practices, health risks were a major concern. Most farmers did not believe in successful rice cultivation without using pesticides to control pests. However, estimated yields did not differ between pesticide users or farmers using conventional methods or neem tree extract. To avoid negative effects on human health and the environment, the farmers need basic education and better assistance in their farming practices and pesticide management. 相似文献
849.
Matilda Palm Madelene Ostwald Indu K. Murthy Rajiv K. Chaturvedi N. H. Ravindranath 《Regional Environmental Change》2011,11(2):423-435
This paper analyses environmental and socio-economic barriers for plantation activities on local and regional level and investigates
the potential for carbon finance to stimulate the increased rates of forest plantation on wasteland, i.e., degraded lands,
in southern India. Building on multidisciplinary field work and results from the model GCOMAP, the aim is to (1) identify
and characterize the barriers to plantation activities in four agro-ecological zones in the state of Karnataka and (2) investigate
what would be required to overcome these barriers and enhance the plantation rate and productivity. The results show that
a rehabilitation of the wasteland based on plantation activities is not only possible but also anticipated by the local population
and would lead to positive environmental and socio-economic effects at a local level. However, in many cases, the establishment
of plantation activities is hindered by a lack of financial resources, low land productivity and water scarcity. Based on
the model used and the results from the field work, it can be concluded that certified emission reductions such as carbon
credits or other compensatory systems may help to overcome the financial barrier; however, the price needs to be significantly
increased if these measures are to have any large-scale impact. 相似文献
850.
P. Valkering R. van der Brugge A. Offermans N. Rijkens-Klomp 《Regional Environmental Change》2011,11(2):229-241
Climate adaptation is a complex task surrounded by uncertainty. To support climate adaptation policies, a new scenario approach
is pursued to explore possible discontinuous future developments of societal perspectives on climate adaptation issues. The
scenario approach was tested for a case study on Dutch river management. In a series of scenario development workshops, a
select group of stakeholders explored the perspectives on the management of the River Meuse in the past, present, and future.
The process was supported by an analytical perspectives mapping tool to illustrate and analyze the development of perspectives
over time. The process and analytical tools contributed to insight into the drivers of perspective change for the case study
at hand. Moreover, the stakeholders highlighted the potential of the approach for water management policy for creating awareness
about the plurality of perspectives and the dynamics of perspective change, monitoring perspectives and perspective change
as part of a flexible policy approach, and anticipating on the occurrence of shock events. Further work is required to better
represent the social dynamics of perspectives change, to better empirically ground the perspective change model, and to apply
integrated water models in the scenario development process to assess water–society interactions. 相似文献