A compilation of field surveys on gaseous elemental mercury (GEM) from contrasting environmental settings in Europe,South America,South Africa and China: separating fads from facts

Mercury is transported globally in the atmosphere mostly in gaseous elemental form (GEM, \( {\text{Hg}}_{\text{gas}}^{0} \) ), but still few worldwide studies taking into account different and contrasted environmental settings are available in a single publication. This work presents and discusses data from Argentina, Bolivia, Bosnia and Herzegovina, Brazil, Chile, China, Croatia, Finland, Italy, Russia, South Africa, Spain, Slovenia and Venezuela. We classified the information in four groups: (1) mining districts where this contaminant poses or has posed a risk for human populations and/or ecosystems; (2) cities, where the concentration of atmospheric mercury could be higher than normal due to the burning of fossil fuels and industrial activities; (3) areas with natural emissions from volcanoes; and (4) pristine areas where no anthropogenic influence was apparent. All the surveys were performed using portable LUMEX RA-915 series atomic absorption spectrometers. The results for cities fall within a low GEM concentration range that rarely exceeds 30 ng m^?3, that is, 6.6 times lower than the restrictive ATSDR threshold (200 ng m^?3) for chronic exposure to this pollutant. We also observed this behavior in the former mercury mining districts, where few data were above 200 ng m^?3. We noted that high concentrations of GEM are localized phenomena that fade away in short distances. However, this does not imply that they do not pose a risk for those working in close proximity to the source. This is the case of the artisanal gold miners that heat the Au–Hg amalgam to vaporize mercury. In this respect, while GEM can be truly regarded as a hazard, because of possible physical–chemical transformations into other species, it is only under these localized conditions, implying exposure to high GEM concentrations, which it becomes a direct risk for humans.     

The consequences of unexpected emotional sounds on driving behaviour in risky situations

Recent development of systems for assisted driving has raised questions about what features of the stimuli perceived by a driver may improve driving behaviour and road safety. The present study aimed to uncover whether emotional auditory stimuli can affect risky behaviour in hazardous situations. Forty-nine volunteers rode a motorcycle in a virtual environment and went through a number of preset risky scenarios, some of which were cued by a sound (a beep, a positive emotional sound or a negative sound). Results showed that hearing the beep reduced the frequency of accidents in the upcoming risky situation, while the emotional cues did not. Likewise, the beep induced the drivers to decrease their speed and focus their gaze on relevant areas of the visual field, while the emotional sounds did not. These results suggest that auditory warning systems for vehicles should avoid using emotion-laden sounds, as their affective content might diminish their utility to increase driving alertness. These findings could provide important information for the development of new advanced driver assistance systems and in general for the specification of future Human–Machine-Interaction design guidelines.     

Remediation effect of compost on soluble mercury transfer in a crop of Phaseolus vulgaris

We studied the dynamics of mercury (Hg) transfer in Phaseolus vulgaris plants grown in soil with Hg-doped compost at the maximum levels permitted by Colombian law on organic amendments. Quantitative evaluation of transfer was made in different plant organs: roots, stem, leaves, pods and seeds. Matrix effect was determined in doped soil assays, using soil with and without addition of compost. Results showed that the use of organic matter reduced Hg transfer to the plant and the amount transferred was differentially distributed to the organs. We observed an inverse relationship between concentration and distance from the body to the root. It was evident that transfer was mediated by quantitative factors; the greater the presence of mercury in soil, the larger the amount that will be transferred. Results also indicate the remedial effect of compost and the presence of a barrier, at the root level, against mercury translocation to the plant aerial parts.     

Towards a cleaner production in developing countries: a case study in a Chilean tannery.

A Chilean leather tanning industry (tannery) was studied in terms of input/output (I/O) analysis of beamhouse, tanyard and retanning processes. The physical-chemical characterization of 19 streams were investigated. Streams from the beamhouse process and some streams from the retanning process were found to have high organic contents ranging from 2.5 to 18.1 g COD L(-1). The pH ranged between 3.45 and 12.28. Sulphur was found in most of the streams whereas chromium was detected in two wastewaters from the tanyard and in seven streams from the retanning process. Pollution prevention opportunities were evaluated and an appropriate treatment strategy was proposed. The main emphasis was on determining waste reduction measures that can be easily implemented and are not particularly expensive. Measures for reduction at source were proposed to reduce water and chemicals consumption and wastewater pollution. A so-called S(index) strategy was used to evaluate proposals on segregation and specific treatment of the main chromium- and sulphur-containing wastewaters. It was suggested that some streams may be re-used, but it is necessary to apply anaerobic or aerobic treatment first, depending on their organic load. Solid wastes were also evaluated and a proposal for their reduction and disposal was made.     

Comparative Life Cycle Assessment of four alternatives for using by-products of cane sugar production

Cane sugar production by-products can be considered either as waste, affecting the environment, or as a resource when an appropriate valorization technology is implemented.This study is made with the objective of identifying and quantifying the aspects which have the largest environmental impact of four alternatives for using by-products and wastes from the cane sugar process and suggest improvements in the systems.For this analysis a cane sugar mill was chosen in Cuba and four alternatives were designed for the by-product valorization. The first alternative represents the conventional sugar production; its main characteristics are the use of synthetic fertilizers, pesticides, the bagasse combustion and the usage of molasses and agricultural wastes as animal food. Other wastes constitute emissions to the environment. Alternatives II, III and IV incorporate more use of by-products and wastes. Alternative II considers the use of wastewater, filter cake and ashes for the substitution of synthetic fertilizers. In Alternative III, the filter cake and wastewater are used for biogas production and Alternative IV integrates alcohol and biogas production into the sugar production process.The assessment is done by means of Life Cycle Assessment, according to the ISO 14040 series by using the SimaPro 6.0 LCA software, Ecoinvent database and the Eco-indicator 99 methodology. As a functional unit the daily sugar production of the mill was defined (216 t/d). The sugar was selected as main product and all the by-products were assumed to substitute other products on the market, avoided products.For the four alternatives, the agricultural stage shows the greatest impact due to land use, fuel and agrochemicals consumption. In the industrial stage, the electricity cogeneration with bagasse has the highest impact as to respiratory effects due to the emission of tiny particle material into the atmosphere. The major difference between the alternatives is found in the resource impact category. The advantage of producing alcohol, biogas, animal food and fertilizers from the by-products is made obvious through the comparative study for resource savings.     

Metallic Composition and Sources of Airborne Atmospheric Particulates in the Industrial Belt of the City of Madrid

The characteristics of the airborne particulates in the industrial belt of the city of Madrid were studied and their metal content in Pb, Ca, Cu, Ni, Fe, Mn, Cr, Mg, Zn and K were determined, with the purpose of assessing any differences when compared to typical urban particulates. The object was to examine the sources of the trace metals analysed and to evaluate their spatial and temporal variations. Six sample collection points were chosen in the industrial belt of the city of Madrid and more than 320 samples were collected over a period of one year. Various forms of source identification were used in order to study the origins of each of the analysed metals. The data obtained indicates that the area studied has a different kind of pollution from that which typically occurs in urban or industrial areas. We were also able to explain a high percentage of the inorganic pollution investigated using a small number of sources: resuspended ground dust, vehicle exhaust, building, industrial combustion and metal processes, and fuel-oil combustion.