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944.
Ramos Marcio Antonio Gomes Bueno de Oliveira Eduardo Schneider Pião Antonio Carlos Simões Nalin de Oliveira Leite Dilza Aparecida de Franceschi de Angelis Dejanira 《Environmental monitoring and assessment》2016,188(5):1-14
Environmental Monitoring and Assessment - Due to the concern with the quality of hydric resources, the monitoring is essential to evaluate and identify the anthropogenic and environmental... 相似文献
945.
Francisco Encina-Montoya Rolando Vega-Aguayo Oscar Díaz Carlos Esse Jorge Nimptsch Andrés Muñoz-Pedreros 《Environmental monitoring and assessment》2017,189(11):584
The suitability of Mazzaella laminarioides and Sarcothalia crispata as heavy metal biomonitors of Cd, Cu, Hg, Pb, and Zn was assessed by comparing bioaccumulation of these elements in different life stages and frond sizes in samples from three locations, San Vicente Bay (industrial area), Coliumo, and Quidico (the latter as a reference station), where different degrees of heavy metal pollution are recorded. Bioaccumulation and bioconcentration factors of Cd, Cu, Hg, Pb, and Zn were evaluated. The two macroalgae species showed similar patterns, with higher values of Cu, Hg, Pb, and Zn in polluted areas. M. laminarioides bioaccumulated higher concentrations of all metals assessed than S. crispata, independent of life stage and frond size. The results also showed significantly higher Cu, Hg, Pb, and Zn concentrations (p < 0.05) in water samples from San Vicente Bay than those measured in Coliumo and Quidico. Concentrations of Cd, Hg, Pb, and Zn in San Vicente Bay and Cd, Hg, and Pb in Coliumo and Quidico exceed the mean values considered to represent natural concentrations (Cu = 3.00 μg L?1; Zn = 5.00 μg L?1; Pb = 0.03 μg L?1; Cd = 0.05 μg L?1; Hg = 0.05 μg L?1); however, the concentrations recorded do not cause negative effects on the growth and survival of macroalgae. The assessment of heavy metals bioaccumulated in M. laminarioides and S. crispata, particularly Hg, Pb, and Zn, offers a reliable approach for pollution assessment in rocky intertidal environments. Cu and Cd concentrations in seawater samples from San Vicente and Coliumo Bays were significantly higher than in those from Quidico (p value < 0.05); no significant differences in Cd concentrations were observed between San Vicente and Coliumo Bays (p < 0.05). Exceptionally, Cd is bioaccumulated at high levels independent of its availability in the water, thus reaching high concentrations in control areas. High concentrations of metals like Cu and Zn may limit or inhibit Cd uptake in macroalgae, since the transport channels are saturated by some metals, reducing the accumulation of others. These macroalgae species offer good potential for the development of suitable heavy metal pollution survey tools in rocky intertidal environments. 相似文献
946.
W. Rogula-Kozłowska B. Błaszczak S. Szopa K. Klejnowski I. Sówka A. Zwoździak M. Jabłońska B. Mathews 《Environmental monitoring and assessment》2013,185(1):581-601
The paper discusses ambient concentrations of PM2.5 (ambient fine particles) and of 29 PM2.5-related elements in Zabrze and Katowice, Poland, in 2007. The elemental composition of PM2.5 was determined using energy dispersive X-ray fluorescence (EDXRF). The mobility (cumulative percentage of the water-soluble and exchangeable fractions of an element in its total concentration) of 18 PM2.5-related elements in Zabrze and Katowice was computed by using sequential extraction and EDXRF combined into a simple method. The samples were extracted twice: in deionized water and in ammonium acetate. In general, the mobility and the concentrations of the majority of the elements were the same in both cities. S, Cl, K, Ca, Zn, Br, Ba, and Pb in both cities, Ti and Se in Katowice, and Sr in Zabrze had the mobility greater than 70%. Mobility of typical crustal elements, Al, Si, and Ti, because of high proportion of their exchangeable fractions in PM, was from 40 to 66%. Mobility of Fe and Cu was lower than 30%. Probable sources of PM2.5 were determined by applying principal component analysis and multiple regression analysis and computing enrichment factors. Great part of PM2.5 (78% in Katowice and 36% in Zabrze) originated from combustion of fuels in domestic furnaces (fossil fuels, biomass and wastes, etc.) and liquid fuels in car engines. Other identified sources were: power plants, soil, and roads in Zabrze and in Katowice an industrial source, probably a non-ferrous smelter or/and a steelwork, and power plants. 相似文献
947.
Alexandra Baeta Ivan Valiela Francesca Rossi Rute Pinto Pierre Richard Nathalie Niquil João C. Marques 《Marine Biology》2009,156(10):2107-2120
In estuaries, eelgrass meadows contribute to fundamental ecosystem functions of estuaries, providing food to several predators
and buffering the negative effects of eutrophication. We asked whether the presence of the eelgrass Zostera noltii decreased the nitrogen concentration in the overlying water, affected the sources of nitrogen sequestrated by primary producers
and changed the benthic and pelagic food web structures. We also studied the importance of these food webs in providing food
to fish. We compared bare sediment to sediment covered by a Z. noltii meadow, and examined nutrient concentrations in the water column and δ15N in primary producers as indicators of anthropogenic inputs of nutrients. We then measured both δ13C and δ15N in the tissues of plants and consumers to establish food web structures. There were no differences in the concentrations
and sources of nitrogen between sites. Rather, δ15N values indicated anthropogenic inputs of N (e.g. sewage discharges, agriculture) in both sites. There were no major differences
in the structure of the planktonic food web, which was in part sustained by particulate organic matter and supported most
predator fish, and in the structure of the benthic food web. Nonetheless, there were differences in the sources of food for
omnivore consumers and for the detritivore Scrobicularia plana. Overall, the benthic food web did not use food derived from the eelgrass or macroalgae deposited on the substratum. Suspension
feeders used particulate and sediment organic matter, whereas the δ13C and δ15N values of the other consumers indicated a likely contribution of benthic microalgae. Furthermore, in both habitats we found
large variability in the isotope signatures of benthic macrofauna consumers, which did not allow distinguishing clearly different
trophic groups and indicated a high level of omnivory and a mixed diet opportunistically making use of the availability of
food in the surroundings. 相似文献
948.
Oliveira C Martins N Tavares J Pio C Cerqueira M Matos M Silva H Oliveira C Camões F 《Chemosphere》2011,83(11):1588-1596
Atmospheric aerosols of four aerodynamic size ranges were collected using high volume cascade impactors in an extremely busy roadway tunnel in Lisbon (Portugal). Dust deposited on the tunnel walls and guardrails was also collected. Average particle mass concentrations in the tunnel atmosphere were more than 30 times higher than in the outside urban background air, revealing its origins almost exclusively from fresh vehicle emissions. Most of the aerosol mass was concentrated in submicrometer fractions (65%), and polycyclic aromatic hydrocarbons (PAH) were even more concentrated in the finer particles with an average of 84% of total PAH present in sizes smaller than 0.49 μm. The most abundant PAH were methylated phenanthrenes, fluoranthene and pyrene. About 46% of the total PAH mass was attributed to lower molecular weight compounds (two and three rings), suggesting a strong influence of diesel vehicle emissions on the production of local particulate PAH. The application of diagnostic ratios confirmed the relevance of this source of PAH in the tunnel ambient air. Deposited dust presented PAH profiles similar to the coarser aerosol size range, in agreement with the predominant origin of coarser aerosol particles from soil dust resuspension and vehicle wear products. 相似文献
949.
Sustainability: characteristics and scientific roots 总被引:1,自引:0,他引:1
950.
Abalos M Parera J Estévez A Solé M Fabregat MC Piña B Navarro A Abad E 《Chemosphere》2011,82(1):64-71
Aquacultured fish gilthead seabream (Sparusaurata), previously exposed to low levels of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) trough the diet for a 13 months period, were fed on a clean feed for another 22 months. Gilthead seabream is a protandrous hermaphrodite species and this “decontamination” period coincided with the stages of sex differentiation, maturity and reproduction of the fish. PCDD/F levels in the fish tissues (i.e. muscle, liver, perivisceral fat and gonads), expressed in pg WHO-TEQ g−1 fresh weight, showed a general decreasing trend during the “decontamination” period. However, this general trend varied among tissues and was also dependent on sex and lipid contents. Toxicological effects affecting fish behaviour and hepatic marker responses were also evaluated. The results pointed out that exposure to PCDD/Fs did not have an impact on fish development and reproduction, since the proportion of sexes found after the sex reversal process was within the normal range described for this species. In addition, long-term exposure to low PCDD/F levels did not significantly affect the response of most of the biochemical markers considered. On the contrary, some of them (e.g. EROD activity) showed variations in their responses during the sex differentiation process and onwards. Finally, the hepatic AhR mRNA levels increased during dioxin exposure but they returned to values typical for non-exposed fish after the “decontamination” period. 相似文献