Levels of polychlorinated biphenyls (PCB) and polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) in fillets of farmed Southern Bluefin Tuna (Thunnus maccoyii)

Southern Bluefin Tuna (SBT) (Thunnus maccoyii) is the only farmed tuna species in the southern hemisphere, with production centred offshore of Port Lincoln, South Australia. SBT farming is a quota-based fishery where farmers fatten wild-caught stock for subsequent sale as fresh-chilled or frozen product, mainly to Japanese markets. Fillets from wild-caught and farmed SBT were analysed and the concentration of polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) are reported for the first time. Time of farming was separated into two periods: a typical farming period of approximately five months and an experimental scenario that involved holding (farming) these fish for an additional 12 months. WHO-PCB and WHO-PCDD/F TEQ concentrations in fillets on a fresh weight basis at the same times and over the same periods were, 0.67-1.18pg-TEQg(-1) and 0.16-0.29pg-TEQg(-1), respectively. All WHO-PCB congeners, and only three WHO-PCDD/F congeners, were found to biomagnify during farming, after blank correction. Caution should be exercised when extrapolating these results to SBT farming as a whole because of the use of varying husbandry and feeding practices employed by different companies.     

Spore release by the green alga Ulva: a quantitative assay to evaluate aquatic toxicants

A toxicity test using spore release of the aquatic green alga, Ulva, was developed and evaluated by assessing the toxicity of different organic and inorganic chemicals and elutriates of sewage or waste sludge. The toxic ranking of four metals was: Cu (EC50 of 0.040mgL(-1))>Cd (0.095mgL(-1))>Pb (0.489mgL(-1))>Zn (0.572mgL(-1)). The EC50 for TBTO ranged from 24 to 63microgL(-1). The most toxic VOC was formalin (EC50 of 0.788microlL(-1)) and the least toxic was acetone. Spore release was significantly inhibited in all elutriates; the greatest and least toxic effects were for industrial sewage (3.29%) and filtration bed (10.08%), respectively. The bioassay is simple, inexpensive and sensitive. The cosmopolitan distribution of Ulva means that the test would have a potential application worldwide.     

Processing of antifouling paint particles by Mytilus edulis

Particles of spent antifouling paint collected from a marine boatyard were ground and subsequently administered to the filter-feeding bivalve, Mytilus edulis, maintained in static aquaria. Concentrations of Cu and Zn were measured in seawater throughout a 16 h feeding phase and a 24 h depuration phase, in rejected and egested particles collected during the respective phases, and in the organisms themselves at the end of the experiments. Concentrations and distributions of Cu and Zn in processed particles indicated that M. edulis was able to ingest paint particles, regardless of whether nutritionally viable silt was present, and no mechanism of particle discrimination was evident. Enrichment of Cu and Zn in the visceral mass of individuals and in the aqueous phase during depuration supported these assertions, although elevated concentrations in other compartments of the organism (e.g. shell, gill) suggested that biotic and abiotic uptake of aqueous metal was also important.     

Australian firefighters' exposure to air toxics during bushfire burns of autumn 2005 and 2006

Bushfire fighting is a hazardous occupation and control strategies are generally in place to minimize the hazards. However, little is known regarding firefighters' exposure to bushfire smoke, which is a complex mixture of toxic gases and particles. In Australia, during the prescribed burning season, firefighters are likely to be exposed on a regular basis to bushfire smoke, but whether these exposures affect health has yet to be determined. There are a number of factors that govern whether exposure to smoke will result in short-term and/or long-term health problems, including the concentrations of air pollutants within the breathing zone of the firefighter, the exposure duration, and health susceptibility of the individual, especially for pre-existing lung or heart disease. This paper presents measurements of firefighters' personal exposure to bushfire smoke, the first step within a risk management framework. It provides crucial information on the magnitude, extent and frequency of personal exposure to bushfire smoke for a range of typical scenarios. It is found that the primary air toxics of concern are carbon monoxide (CO), respirable particles and formaldehyde. Also, work activity is a major factor influencing exposure with exposure standards (both average and short-term limits) likely to be exceeded for activities such as suppression of spot fires, holding the fireline, and patrolling at the edge of a burn area in the urban-rural interface.     

Residual veterinary antibiotics in swine manure from concentrated animal feeding operations in Shandong Province, China

The scientific interest in the occurrence and fate of antibiotics in animal husbandry has increased during the past decades because of the emergence and development of antimicrobial resistance in pathogenic bacteria. This study developed a method for simultaneous detection of five sulfonamides, three tetracyclines and one macrolide in swine manure with stable recoveries (73.0-110.6%) and high sensitivity (limit of quantification <90 μg kg⁻¹). Thereafter, a total of 126 swine manure samples, collected from 21 concentrated animal feeding operations (CAFOs) in Shandong Province of China during summer and winter, were analyzed. The potential influences of different sampling seasons, swine types and food sources on residual antibiotic concentrations were examined in detail. The maximum concentration of residual antibiotic could reach up to 764.4 mg kg⁻¹ (chlortetracycline), and the detection frequencies were 84.9-96.8% for tetracyclines, 0.8-51.6% for sulfonamides and 4.8% for macrolide. These data reveal that antibiotics were extensively used in CAFOs in this district and the manure may act as a non-specific source of antibiotic residue in farmlands and aquatic environments.     

Effects of VOCs on herbaceous plants in an open-top chamber experiment

A selection of herbaceous plants representing the ground flora around a typical chemical installation in the UK was exposed continuously for 7 weeks to a mixture of six VOCs (acetone, acetonitrile, dichloromethane, ethanol, methyl t-butyl ether and toluene) in open-top chambers. Exposure concentrations were based on predictions of atmospheric dispersion from a single source, at a distance of approximately 2 km. The effects of continuous exposure, representing a worst-case, were measured in terms of uncontrolled water loss from leaves, leaf wettability, chlorophyll content and fluorescence, dry matter production and detailed observations of changes in plant growth and phenology. There were significant effects of VOC exposure on seed production, leaf water content and photosynthetic efficiency in some plant species. Such effects may be detectable in vegetation close to major industrial point sources of VOCs, or as a result of an accidental release of material during manufacture or transport. Some of the species tested e.g. birdsfoot trefoil (Lotus corniculatus L.) seem to be promising as potential bioindicators for VOCs, but there may be other even more sensitive species waiting to be discovered. However, the most obvious and conveniently measured response to VOCexposure in the birdsfoot trefoil (premature senescence i.e. advanced timing of seed pod production) could easily be confused in the field with climatic influences. It is also uncertain at this stage whether any of the effects observed would lead to longer term ecological changes in natural plant communities, through biased competition between sensitive and more tolerant species.     

Fly-ash-amended sand as filter media in bioretention cells to improve phosphorus removal.

This study identified material with high phosphorus sorption suitable for bioretention filter media. Materials examined were fly ash, two expanded shales, peat moss, limestone, and two common Oklahoma soils--Teller loam and Dougherty sand. The peat moss was a phosphorus source, while the two soils, limestone, and one expanded shale had only modest sorption capacity. One expanded shale and the fly ash had significant phosphorus sorption. Fly ash is unsuitable for use in a pure form, as a result of its low permeability, but phosphorus sorption on the sand was increased significantly with the incorporation of small amounts of fly ash. Column leaching experiments found that the sand with 2.5 and 5% fly ash and the better expanded shale had linear, non-equilibrium transport retardation factors of 272, 1618, and 185, with first-order rate coefficients of 0.153, 0.0752, and 0.113 hour(-1), respectively. Desorption experiments showed that the phosphorus sorption on the sand/fly ash mixture is largely nonreversible. Transport simulation assuming a 1-m-deep sand/fly ash treatment layer, with 5% of the watershed area, showed that the sand/fly ash filter media could effectively treat 1 mg/L influent for 12 years in a paved watershed and 34 years in a grassed watershed before exceeding Oklahoma's scenic rivers' phosphorus criterion of 0.037 mg/L. Significant phosphorus removal would continue for over 100 years.     

FIBAX纤维滤料在再生水工艺中的应用研究

针对某化工厂甲醇冷凝液再生处理工艺中生化出水浊度较高,对后续离子交换树脂产生不利影响等问题,考察了新型FIBAX纤维过滤对浊度的去除情况.当采用微絮凝后FIBAX过滤(滤速50 m/h)时,混凝剂PAC最佳投加量2 mg/L(以Al2O3计),其对浊度的去除率为99.9%,出水浊度达到小于0.50 NTU的目标要求,此时其过滤周期36 h,并且其投资和运行费用均较低.上述结果表明,FIBAX纤维滤料能有效去除来水中的细少悬浮物,满足后续工艺要求,是一种新型的固液分离材料.     

中西方国家环境影响评价中公众参与制度的对比分析

阐明了环境影响评价中公众参与的定义及特点,对中西方国家环境影响评价中公众参与的起源、法律规定、形式、内容与要求等方面进行了对比分析,并对我国公众参与制度的完善提出了建议。     

Trace contamination with dioxin-like chemicals: evaluation of bioassay-based TEQ determination for hazard assessment and regulatory responses

Many recent dioxin contamination events have been traced back to poisoned animal feed or feed ingredients. Therefore, enforcement authorities placed limits on the levels of dioxins in food and feed or implemented strict monitoring and control programs. The levels in force are generally expressed as TEQ values, which inherently accepts the underlying hypothesis that the effects of dioxin-like chemicals are additive. TEQ determination involves either chemo-analysis, with high-resolution gas chromatography in combination with high-resolution mass spectroscopy, or bio-analysis. Bio-analytical methods, more particularly the reporter gene expression method CALUX, are advantageous due to their high throughput rate and low cost. Moreover, the CALUX methodology detects the overall dioxin-like toxicity, rather than the limited number of compounds investigated by chemo-analysis. Bioanalytical methods such as CALUX also differ from chemo-analysis in that the contribution of antagonistic as well as synergistic effects, which violate the additivity principle, can be detected. The application of bio-analytical methods can facilitate a broader assessment of public health risks by intensifying the current monitoring programs in terms of both sample numbers and types. Bio-analysis provides information on the total dioxin-like activity of the samples under study (hazard assessment); however, chemo-analysis is still needed to identify the predominant contaminants (congener identification) for risk management.