Field demonstration of surfactant-enhanced solubilization of DNAPL at Dover Air Force Base, Delaware

This study reports on a surfactant-based flood for tetrachloroethylene (PCE) removal from a control test cell at the Dover National Test Site. The surfactant formulation (sodium dihexyl sulfosuccinate (Aerosol-MA or AMA), isopropanol and calcium chloride) was able to achieve a high concentration of PCE in swollen micelles (supersolubilization) without vertical PCE migration. The hydraulic system included eight screened wells that were operated in both vertical circulation and line drive configurations. After 10 pore volumes of flushing, the overall PCE removal was 68% (65% of which corresponded to the surfactant flooding alone). In addition, the residual PCE saturation was reduced from 0.7% to 0.2%, and the concentration of PCE in the groundwater was reduced from 37-190 mg/L before the flushing to 7.3 mg/L after flooding. Recycling the surfactant solution reduced the required surfactant mass (and thus cost, and waste) by 90%. Close to 80% of the total PCE removal was obtained during the first five pore volumes which were operated in an upward vertical circulation flow scheme. No free oil phase was observed during the test. Further analysis of multilevel sampler data suggests that most of the trapped oil remaining in the cell was likely localized in secluded regions of the aquifer, which helps explain the lower PCE groundwater concentration after remedial activities. In summary, this field study demonstrated the feasibility of surfactant-enhanced remediation to reduce the mass in the source zone and significantly reduce the PCE aqueous concentration and therefore the risk associated with the contaminant plume.     

高速铁路对沿线地区可达性的影响研究——以皖北地区为例

区域交通可达性的改变是高速铁路对区域发展的最直接影响。在GIS技术的支持下,以皖北地区为实证研究对象,利用日常可达性、加权平均时间等指标分析了在有无高铁两种情景下皖北地区的可达性空间格局变化。结果表明：高铁开通后,皖北区域内部可达性和区域外部可达性均获得了较大提升,但区外可达性的改善要优于区内可达性;皖北整体可达性空间格局没有因高铁发生大的改变,可达性空间分布呈现的区域交通主干道指向性特征在高铁通车后更为明显;可达性改善的地区分布并不均匀,不同地区可达性受惠程度不一,皖北整体以及各城市内部的可达性均衡性程度都在降低,两极分化趋势在加剧     

中国生态保护政策的县域经济效应——来自国家重点生态功能区的证据

为保障生态产品供给，中国设立了限制开发的国家重点生态功能区，建立了生态保护转移支付制度.本文首次在县域层面构建2002~2017年县级面板数据，运用倾向得分匹配法构造政策组的“反事实”情形，基于双重差分法评估重点生态功能区政策的县域经济效应.结果表明，该政策提高了县域财力、长期来看一定程度改善了产业结构；以标准财政缺口为主的资金分配机制弱化了县域经济发展激励，资金补助不能完全抵消限制开发对县域经济带来的负向影响；固定资产投资和内资企业受影响较大.随着投入资金累积、生态产品价值的转化，该负向效应随时间而减弱、经济促增效应逐渐显现.政策效应在不同生态功能和经济区位间表现出明显的异质性.建议持续增加生态转移支付资金、将生态产品供给数量和质量作为资金分配依据，考虑按生态功能类型设计差异化政策，更好激励县域生态产品高水平供给与经济价值实现的双赢，促进区域均衡发展.     

Estimating uncertainties in the life cycle assessment of composting household biowaste and urban green waste in Germany

Life cycle assessment (LCA) of waste treatment processes is often associated with considerable uncertainties. The aim of this study is to estimate the total uncertainty in the modelled composting system and the influence of material and process parameters on the uncertainty. Four composting combinations with fresh (FC) and mature substrate compost (MSC) from partially enclosed (PEC) and open composting (OC) were investigated. Perturbation analysis was used to determine the effect of parameters on the result and Monte Carlo simulation was used to estimate the total uncertainty. This study showed that the production of MSC using PEC had the lowest overall impacts across all impact categories except ozone depletion. Results of the Monte Carlo simulation showed that comparing composting options was challenging. The sensitivity ratios obtained from the perturbation analysis showed that the process parameter percentage of carbon fraction degraded was the most influential for FC. In MSC, the moisture content in the input material and the substitution factor used for peat were the most influential. Monte Carlo simulations demonstrated the overall uncertainty of the model and its relevance when comparing results between combinations. The perturbation analysis identified the parameters that required more accurate data to reduce the uncertainty in the model.

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Pyrolysis of lemon peel waste in a fixed-bed reactor and characterization of innovative pyrolytic products

Journal of Material Cycles and Waste Management - Lemon peel waste (LPW) were pyrolysed in a laboratory fixed-bed reactor at final temperature of 300 °C, 400 °C and...     

Extraction and characterization of chitin,chitosan, and protein hydrolysate from the invasive Pacific blue crab,Portunus segnis (Forskål, 1775) having potential biological activities

Environmental Science and Pollution Research - The diversity of marine biomasses is a set of exploitable and renewable resources with application in several sectors. In this context, a co-culture...     

Exposure to microplastics leads to a defective ovarian function and change in cytoskeleton protein expression in rat

Environmental Science and Pollution Research - Microplastics (MPs) are ubiquitous environmental contaminants; through their physicochemical properties, they can have potentially negative effects on...     

Contribution of warm habitat to cold-water fisheries

A central tenet of landscape ecology is that mobile species depend on complementary habitats, which are insufficient in isolation, but combine to support animals through the full annual cycle. However, incorporating the dynamic needs of mobile species into conservation strategies remains a challenge, particularly in the context of climate adaptation planning. For cold-water fishes, it is widely assumed that maximum temperatures are limiting and that summer data alone can predict refugia and population persistence. We tested these assumptions in populations of redband rainbow trout (Oncorhynchus mykiss newberrii) in an arid basin, where the dominance of hot, hyperproductive water in summer emulates threats of climate change predicted for cold-water fish in other basins. We used telemetry to reveal seasonal patterns of movement and habitat use. Then, we compared contributions of hot and cool water to growth with empirical indicators of diet and condition (gut contents, weight–length ratios, electric phase angle, and stable isotope signatures) and a bioenergetics model. During summer, trout occurred only in cool tributaries or springs (<20 °C) and avoided Upper Klamath Lake (>25 °C). During spring and fall, ≥65% of trout migrated to the lake (5–50 km) to forage. Spring and fall growth (mean [SD] 0.58% per day [0.80%] and 0.34 per day [0.55%], respectively) compensated for a net loss of energy in cool summer refuges (–0.56% per day [0.55%]). In winter, ≥90% of trout returned to tributaries (25–150 km) to spawn. Thus, although perennially cool tributaries supported thermal refuge and spawning, foraging opportunities in the seasonally hot lake ultimately fueled these behaviors. Current approaches to climate adaptation would prioritize the tributaries for conservation but would devalue critical foraging habitat because the lake is unsuitable and unoccupied during summer. Our results empirically demonstrate that warm water can fuel cold-water fisheries and challenge the common practice of identifying refugia based only on summer conditions.