Direct and indirect methods for chromium identification in industrial wastes

The examinations of selected wastes and stream sediments from the vicinity of a chemical plant by sequential extraction procedures and direct methods, SEM/EDX and XRD, were carried out in order to identify the different forms of chromium, particularly as they are released to potential mobility. The results show that the top and bottom waste samples contain 37,756 and 53,650 μg g¹ Cr, respectively, but about 7% and 2% of the total chromium type Cr(VI). The chemical extraction results show that the mobility of Cr in the upper part of the waste pile is significantly higher than in the bottom section; the exchangeable form of Cr accounts for 25% and < 1%, respectively, the last one irrespective of redox conditions. About 50% of Cr is associated with the reducible fraction of the top waste, and similar with the residual fraction in the bottom waste. Oxidation of the bottom waste shift some portion of Cr from residual to the moderately reducible fraction. The major Cr-forms in the river sediments are compounded with Fe-oxides. The < 2 μm size fraction of the selected sediment sample, particular enriched in chromium contained up to 73,000 μg g¹ Cr with about 95% of this in the moderately reducible fraction, predominantly bound with oxyhydroxides. SEM/EDX and XRD analysis of wastes and river sediment indicate that the main insoluble Cr-phase is ferroan — (Mg, Fe) (Cr, Al)²O⁴ which would be dissolved mainly in the residual fraction.     

Euro-trash: searching Europe for a more sustainable approach to waste management

How an economically affordable, environmentally effective and socially acceptable municipal solid waste management system can be developed is currently unclear. Considerable research has been carried out on the practical aspects of municipal waste management (i.e. transport, treatment and disposal) and how citizens feel about source separation, recycling, incineration and landfill but the perspective of the waste manager within the context of long term planning is often ignored. In this study, waste managers from 11 different leading-edge European municipal solid waste programs in nine different countries were interviewed. The economic, social, political, environmental, legal and technical factors of their specific programs were explored and analyzed. The transition of municipal solid waste management to urban resources management was observed and key ‘system drivers’ for more sustainable waste management practices were identified. Programs visited were: Brescia (I), Copenhagen (DK), Hampshire (UK), Helsinki (FI), Lahn-Dill-Kreis (D), Malmö (SE), Pamplona (E), Prato (I), Saarbrücken (D), Vienna (A), and Zürich (CH).     

Evaluation of the electrochemical behavior of pentachlorophenol by cyclic voltammetry on carbon paste electrode modified by humic acids.

Humic substances, or natural recalcitrant organic matter, have an important role in the environment for their plant nutritional functions or for their capability to control the mobility of xenobiotic substances, such as pesticides. To verify the electrochemical behavior of pentachlorophenol (PCP), cyclic voltammetry was used because of its versatility. The following two different electrodes were used: carbon paste electrode (CPE) and carbon paste electrode chemically modified with humic acid (HACMCPE). The results demonstrated that PCP was better accumulated at the HACMCPE electrode, as a consequence of a larger current signal than at the CPE electrode. Cyclic voltammograms showed oxidation steps of PCP itself and probable production of quinonelike compounds.     

Systems model of carbon transformations in soil subsidence

A system model was designed to simulate the interaction of climatologic and biologic factors in the biological oxidation of organic soils in ordert to stimulate research on this diminishing resource and attendant water quality problems in the Florida Everglades area. This is a mass balance model in which carbon and nitrogen are conserved in the transformations. It was designed to test different management alternatives for slowing the rate of soil subsidence and to estimate their potential effect on water quality by simulating subsidence rates and the release rates of nitrates, nitrites, and organic acids to ground and surface waters.The biological submodel is structured about two major compartments — the total non-living carbon compartment and a living carbon compartment that includes the microbial biomass and functioning extracellular enzymes.Simulations of the model show the effects of temperature, organic composition, and water table height on carbon dioxide evolution from the soil.     

Governing local sustainability

This paper draws upon the DISCUS (Developing Institutional and Social Capacity for Sustainable Development) research project, co-funded by the European Commission. The project was undertaken during 2001 – 2004 and involved an in-depth study of 40 European towns and cities in order to understand the institutional and social factors and conditions that might contribute to policy ‘achievement' or ‘failure' in local sustainable development policy and practice. Based on the findings of this research it proposes a conceptual framework for local sustainable development, linking the concepts of institutional capital, social capital and governance to provide a model for understanding the governing of local sustainability. The research shows that in those cases that exhibit sustainable development policy achievements, there are also greater levels of civil society activity and knowledge regarding sustainability issues, and high levels of institutional capacity. Confident local government is crucial to the development of institutional capacity and to institutional learning. One aspect of this is local authorities being equipped to address the longer-term issues and to have a strategic vision for a sustainable future.     

Thermally induced biological effects caused by once-through cooling systems: A rationale for evaluation

The thermally induced biological effects of power plants with once-through cooling systems can be evaluated in a logical, scientifically defensible manner. First, we combined a near-field integral model (the Shirazi-Davis model) with a far-field model (the Okubo-Pritchard model) to predict the fields of excess temperature and velocity associated with a hypothetical power plant sited on a river and an estuary, and to establish the time-excess temperature exposure histories resulting from the interaction of an assumed distribution of organisms with these fields. Next, we developed a new thermal response model to assess the thermal effects of these exposures on these organisms.Our thermal response model can be used with data from existing and proposed power plants to estimate what fraction of plankton in waters contiguous to the plant will be exposed to thermal doses greater than those that cause death at any stated level. The model can also be used to aid in the design of once-through cooling systems to keep the mortality rate caused by thermal stresses below any designated threshold. The inputs to the model are the frequency distribution of time-excess temperature histories experienced by particular plankton (the Representative Important Species), thermal resistance curves for those organisms, and the spatial and temporal variations of the natural temperature of the receiving waters.To illustrate, we applied our thermal response model to three important aquatic environments of New York State, Long Island Sound, the lower Hudson River, and Lake Ontario. The Representative Important Species were identified for each of these environments and the thermal resistance data for their early (entrainable) life stages were reviewed. Fromall of the thermal resistance data available for any of the entrainable species composing these three communities, we constructed community thermal resistance curves and showed how they could be combined in graphic form with the distribution of thermal doses computed from the physical models and an assumed distribution of organisms in the receiving waters. For each community it appeared that the most sensitive organisms were the ichthyoplankton and juvenile fish; therefore, protection of these organisms from thermal stress should protect the entrainable populations as a whole.Finally, we made several recommendations for future research so that the full management potential of our approach can be achieved.