Assessing Influences of Hydrology,Physicochemistry, and Habitat on Stream Fish Assemblages Across a Changing Landscape1

Abstract: We evaluated the impact of land cover on fish assemblages by examining relationships between stream hydrology, physicochemistry, and instream habitat and their association with fish responses in streams draining 18 watersheds of the Lower Piedmont of western Georgia. Several important relationships between land use and physicochemical, hydrological, and habitat parameters were observed, particularly higher frequency of spate flows, water temperatures, and lower dissolved oxygen (DO) with percentage impervious surface (IS) cover, higher habitat quality with percentage forest cover, and elevated suspended solid concentrations with percentage pasture cover. Fish assemblages were largely explained by physicochemical and hydrological rather than habitat variables. Specifically, fish species diversity, richness, and biotic integrity were lower in streams that received high frequency of spate flows. Also, overall fish assemblage structure as determined by nonmetric multidimensional scaling was best described by total dissolved solids (TDS) and DO, with high TDS and low DO streams containing sunfish‐based assemblages and low TDS and high DO streams containing minnow‐based assemblages. Our results suggest that altered hydrological and physicochemical conditions, induced largely by IS, may be a strong determinant of fish assemblage structure in these lowland streams and allow for a more mechanistic understanding of how land use ultimately affects these systems.     

Estimating Nitrogen Loading to Ground Water and Assessing Vulnerability to Nitrate Contamination in a Large Karstic Springs Basin,Florida1

Abstract: A nitrogen (N) mass‐balance budget was developed to assess the sources of N affecting increasing ground‐water nitrate concentrations in the 960‐km² karstic Ichetucknee Springs basin. This budget included direct measurements of N species in rainfall, ground water, and spring waters, along with estimates of N loading from fertilizers, septic tanks, animal wastes, and the land application of treated municipal wastewater and residual solids. Based on a range of N leaching estimates, N loads to ground water ranged from 262,000 to 1.3 million kg/year; and were similar to N export from the basin in spring waters (266,000 kg/year) when 80‐90% N losses were assumed. Fertilizers applied to cropland, lawns, and pine stands contributed about 51% of the estimated total annual N load to ground water in the basin. Other sources contributed the following percentages of total N load to ground water: animal wastes, 27%; septic tanks, 12%; atmospheric deposition, 8%; and the land application of treated wastewater and biosolids, 2%. Due to below normal rainfall (97.3 cm) during the 12‐month rainfall collection period, N inputs from rainfall likely were about 30% lower than estimates for normal annual rainfall (136 cm). Low N‐isotope values for six spring waters (δ¹⁵N‐NO₃ = 3.3 to 6.3‰) and elevated potassium concentrations in ground water and spring waters were consistent with the large N contribution from fertilizers. Given ground‐water residence times on the order of decades for spring waters, possible sinks for excess N inputs to the basin include N storage in the unsaturated zone and parts of the aquifer with relatively sluggish ground‐water movement and denitrification. A geographical‐based model of spatial loading from fertilizers indicated that areas most vulnerable to nitrate contamination were located in closed depressions containing sinkholes and other dissolution features in the southern half of the basin.     

Reactive transport modeling of remedial scenarios to predict cadmium,copper, and zinc in north fork of Clear Creek,Colorado

The North Fork of Clear Creek (NFCC), Colorado, is an acid‐mine‐drainage‐impacted stream typical of many mountain surface waters affected by historic metal mining in the western United States. The stream is devoid of fish primarily because of high metal concentrations in the water (e.g., copper and zinc) and has large amounts of settled iron oxyhydroxide solids that coat the streambed. The NFCC is part of the Central City/Clear Creek Superfund site, and remediation plans are being implemented that include treatment of three of the main point‐source inputs and cleanup of some tailings and waste rock piles. This article examines dissolved (0.45‐μm filterable) concentrations of cadmium, copper, and zinc following several potential remediation scenarios, simulated using a reactive transport model (WASP4/META4). Results from modeling indicate that for cadmium, remediation of the primary point‐source adit discharges should be sufficient to achieve acute and chronic water‐quality standards under both high‐ and low‐flow conditions. To achieve standards for copper and zinc, however, the modeling scenarios suggest that it may be necessary to treat or remove contaminated streambed sediments in downstream reaches, as well as identify and treat nonpoint sources of metals. Recommendations for improvements to the model for metal transport in acid‐mine drainage impacted streams are made. These recommendations are being implemented by the U.S. Environmental Protection Agency. © 2009 Wiley Periodicals, Inc.     

Modeling Effects of Natural Flow Restoration on Metals Fate and Transport in a Mountain Stream Impacted by Mine Waste1

Abstract: The effects of natural flow restoration on metals fate and transport in the Upper Tenmile Creek Watershed, Montana, were modeled using the Water Quality Analysis Simulation Program developed by the U.S. Environmental Protection Agency (USEPA). This 50‐km² watershed has over 150 historic abandoned mines, including mine waste rock and tailings, as well as adits discharging acid mine drainage, and is the primary drinking water supply for the City of Helena. Water supply diversions almost completely dewater some stream reaches during summer low flows, but the city is considering a new drinking water source and restoration of natural flows in Tenmile Creek as part of acid mine drainage remediation and broader aquatic habitat restoration. One dimensional steady‐state simulation of total recoverable cadmium, copper, lead, and zinc in the mainstem was performed, and the model was calibrated to June 2000 base‐flow data. Representative low‐flows in August and high‐flow snowmelt conditions in June were modeled using mean monthly natural flow estimates from the U.S. Geological Survey and representative USEPA metals concentrations data. The modeling showed that total recoverable metals concentrations, and especially loads, can vary significantly among input locations and over time in the watershed. Some data gaps limit evaluation of variability and increase uncertainty in several locations. Model results indicated, however, that natural low‐ and high‐flow restoration by itself can reduce some metals concentrations in the mainstem compared to June 2000 values, which were influenced by significant water diversion. Some values (such as Zn) may still exceed standards during natural August low flow due to the remaining high concentrations and loads in the primary inputs to the mainstem. Others (such as Cu) can increase during high flow due to remaining mine waste sources and loading of particulate Cu associated with erosion and transport of solids. Greater than 50% reduction in concentrations and loads from some of the main tributaries may be necessary to meet all standards, especially for potential particulate loads with higher flows in June.     

The Scottish Raptor Monitoring Scheme: objectives, achievements in the first four years, and plans for future development

The Scottish Raptor Monitoring Scheme (SRMS) comprises 7 partner organizations and was established in 2002 after i) the publication of the UK Government's Raptor Working Group Report that made recommendations for enhanced monitoring, ii) increased applied data needs (e.g., for site designation), and iii) concerns for the status of some species. The SRMS has 3 major objectives: i) to facilitate cooperation between parties; ii) to provide robust information on Scottish raptor populations by determining trends in numbers, range, survival, and productivity and understanding the causes of change; and iii) to maintain high and uniform standards for the collection, collation, auditing, and analysis of data and reporting of information. Data are collected for 19 species: 14 diurnal raptors, 4 owls, and 1 corvid, the Common Raven. Here we describe the development of the scheme, challenges, and achievements during its first 4 y, the nature and value of the data collected, and plans for the future.     

Dechlorination comparison of mono-substituted PCBs with Mg/Pd in different solvent systems

It is widely recognized that polychlorinated biphenyls (PCBs) are a dangerous environmental pollutant. Even though the use and production of PCBs have been restricted, heavy industrial use has made them a wide-spread environmental issue today. Dehalogenation using zero-valent metals has been a promising avenue of research for the remediation of chlorinated compounds and other contaminants that are present in the environment. However, zero-valent metals by themselves have shown little capability of dechlorinating polychlorinated biphenyls (PCBs). Mechanically alloying the metal with a catalyst, such as palladium, creates a bimetallic system capable of dechlorinating PCBs very rapidly to biphenyl. This study primarily aims to evaluate the effects of solvent specificity on the kinetics of mono-substituted PCBs, in an attempt to determine the mechanism of degradation. Rate constants and final byproducts were determined for the contaminant systems in both water and methanol, and significant differences in the relative rates of reaction were observed between the two solvents.     

Oxytetracycline sorption to organic matter by metal-bridging

The sorption of oxytetracycline to metal-loaded ion exchange resin and to natural organic matter by the formation of ternary complexes between polyvalent metal cations and sorbent- and sorbate ligand groups was investigated. Oxytetracycline (OTC) sorption to Ca- and Cu-loaded Chelex-100 resin increased with increasing metal/sorbate ratio at pH 7.6 (OTC speciation: 55% zwitterion, 45% anion). Greater sorption to Cu- than Ca-loaded resin was observed, consistent with the greater stability constants of Cu with both the resin sites and with OTC. Oxytetracycline sorption to organic matter was measured at pH 5.5 (OTC speciation: 1% cation, 98% zwitterion, 1% anion). No detectable sorption was measured for cellulose or lignin sorbents that contain few metal-complexing ligand groups. Sorption to Aldrich humic acid increased from "clean" < "dirty" (no cation exchange pretreatment) < Al-amended < Fe(III)-amended clean humic acid with K(d) values of 5500, 32000, 48000, and 250000 L kg(-1) C, respectively. Calcium amendments of clean humic acid suggested that a portion of the sorbed OTC was interacting by cation exchange. Oxytetracycline sorption coefficients for all humic acid sorbents were well-correlated with the total sorbed Al-plus-Fe(III) concentrations (r(2) = 0.87, log-log plot), suggesting that sorption by ternary complex formation with humic acid is important. Results of this research indicate that organic matter may be an important sorbent phase in soils and sediments for pharmaceutical compounds that can complex metals by the formation of ternary complexes between organic matter ligand groups and pharmaceutical ligand groups.     

Rural industries and water pollution in China

Water pollution from small rural industries is a serious problem throughout China. Over half of all river sections monitored for water quality are rated as being unsafe for human contact, and this pollution is estimated to cost several per cent of GDP. While China has some of the toughest environmental protection laws in the world, the implementation of these laws in rural areas is not effective. This paper explains the reasons for this implementation gap. It argues that the factors that have underpinned the economic success of rural industry are precisely the same factors that cause water pollution from rural industry to remain such a serious problem in China. This means that the control of rural water pollution is not simply a technical problem of designing a more appropriate governance system, or finding better policy instruments or more funding. Instead, solutions lie in changes in the model that underpins rural development in China.     

Adaptive management of the Great Barrier Reef and the Grand Canyon world heritage areas

Conventional perceptions of the interactions between people and their environment are rapidly transforming. Old paradigms that view humans as separate from nature, natural resources as inexhaustible or endlessly substitutable, and the world as stable, predictable, and in balance are no longer tenable. New conceptual frameworks are rapidly emerging based on an adaptive approach that focuses on learning and flexible management in a dynamic social-ecological landscape. Using two iconic World Heritage Areas as case studies (the Great Barrier Reef and the Grand Canyon) we outline how an improved integration of the scientific and social aspects of natural resource management can guide the evolution of multiscale systems of governance that confront and cope with uncertainty, risk, and change in an increasingly human-dominated world.     

Nanomaterials and the environment: uses, methods and measurement

Nanotechnology has emerged as a field of science and engineering which offers many new product possibilities and potential solutions for a variety of problems. Nanomaterials come in many shapes and forms and contribute to potential products that do everything from sense analytes on a molecular level to function as self cleaning surfaces. With new and significant applications, it is likely that nanomaterial containing products may replace many of the products we use on a daily basis, leading to an increased presence of these materials in the environment. This will result in new needs and requirements from detection tools. It is likely that the analytical methods used to monitor nanomaterials in the environment will be very different than those used in risk assessment and exposure studies. This paper briefly outlines the history, impacts, and uses of nanomaterials and discusses possible methods of detection and quantification for environmental samples. The discussions in this article are specific to those matrices relating to wastewaters and sludge.