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861.
Characterizing sources of nitrate leaching from an irrigated dairy farm in Merced County, California
Martin L. van der Schans Thomas Harter Anton Leijnse Marsha C. Mathews Roland D. Meyer 《Journal of contaminant hydrology》2009,110(1-2):9-21
Dairy farms comprise a complex landscape of groundwater pollution sources. The objective of our work is to develop a method to quantify nitrate leaching to shallow groundwater from different management units at dairy farms. Total nitrate loads are determined by the sequential calibration of a sub-regional scale and a farm-scale three-dimensional groundwater flow and transport model using observations at different spatial scales. These observations include local measurements of groundwater heads and nitrate concentrations in an extensive monitoring well network, providing data at a scale of a few meters and measurements of discharge rates and nitrate concentrations in a tile-drain network, providing data integrated across multiple farms. The various measurement scales are different from the spatial scales of the calibration parameters, which are the recharge and nitrogen leaching rates from individual management units. The calibration procedure offers a conceptual framework for using field measurements at different spatial scales to estimate recharge N concentrations at the management unit scale. It provides a map of spatially varying dairy farming impact on groundwater nitrogen. The method is applied to a dairy farm located in a relatively vulnerable hydrogeologic region in California. Potential sources within the dairy farm are divided into three categories, representing different manure management units: animal exercise yards and feeding areas (corrals), liquid manure holding ponds, and manure irrigated forage fields. Estimated average nitrogen leaching is 872 kg/ha/year, 807 kg/ha/year and 486 kg/ha/year for corrals, ponds and fields respectively. Results are applied to evaluate the accuracy of nitrogen mass balances often used by regulatory agencies to assess groundwater impacts. Calibrated leaching rates compare favorably to field and farm scale nitrogen mass balances. These data and interpretations provide a basis for developing improved management strategies. 相似文献
862.
863.
R.R. Dalvi T.J. Robbins M.K. Williams D.P. Deoras F. Donastorg C. Banks 《Journal of environmental science and health. Part. B》2013,48(8-9):703-712
Abstract A single i.p. dose (120 mg/kg) of thiram given to male Sprague‐Dawley rats caused a significant increase in the activity of SGOT and SGPT 24 hr post‐treatment indicating liver damage. A considerable diminution in the serum cholinesterase activity was also noted in the treated rats as against the control animals. Additional evidence for thiram‐induced liver toxicity is provided by the observation that there was approximately 50% inhibition of the activity of hepatic microsomal benzphetamine N‐demethylase with a concomitant decrease in the concentration of cytochrome P‐450, an important component of the mixed‐function oxidase system. Although not significant, hepatic glutathione levels were also depleted by thiram, probably making the liver susceptible to toxic injury. 相似文献
864.
Assessment of oxidative stress levels and tissue concentrations of elements in plants growing wild on fly ash basins is critical for realistic hazard identification of fly ash disposal areas. Hitherto, levels of oxidative stress markers in plants growing wild on fly ash basins have not been adequately investigated. We report here concentrations of selected metal and metalloid elements and levels of oxidative stress markers in leaves of Cassia occidentalis growing wild on a fly ash basin (Badarpur Thermal Power Station site) and a reference site (Garhi Mandu Van site). Plants growing on the fly ash basin had significantly high foliar concentration of As, Ni, Pb and Se and low foliar concentration of Mn and Fe compared to the plants growing on the reference site. The plants inhabiting the fly ash basin showed signs of oxidative stress and had elevated levels of lipid peroxidation, electrolyte leakage from cells and low levels of chlorophyll a and total carotenoids compared to plants growing at the reference site. The levels of both protein thiols and nonprotein thiols were elevated in plants growing on the fly ash basin compared to plants growing on the reference site. However, no differences were observed in the levels of cysteine, reduced glutathione and oxidized glutathione in plants growing at both the sites. Our study suggests that: (1) fly ash triggers oxidative stress responses in plants growing wild on fly ash basin, and (2) elevated levels of protein thiols and nonprotein thiols may have a role in protecting the plants from environmental stress. 相似文献
865.
H.C. Agarwal D.K. Singh V.B. Sharma 《Journal of environmental science and health. Part. B》2013,48(1):189-194
Abstract Persistence, metabolism and binding of 14C‐parathion in alkaline sandy loam soil under sub‐tropical conditions of Delhi were studied for 545 days. After 3 days of treatment, 14C‐residues declined to 41% of the amount applied. The dissipation curve was biphasic; an initial rapid phase (up to 7 days) followed by slow dissipation. The half life of dissipation was only 3.36 days for the first phase and 84 days for the slow phase. The overall half life was 64.5 days. The total residues at zero‐time were 10.65 μg/g dry soil and were almost totally extractable. The extracts consisted of parathion, 4‐aminophenol, 4‐nitrophenol and paraoxon. The bound residues gradually increased and accounted for the total residue at the end of one year (0.7 μg/g). 相似文献
866.
Ernest D. King 《Journal of the Air & Waste Management Association (1995)》2013,63(5):537-539
Simultaneous measurements of individual hydrocarbons and individual carbonyls were carried out at a downtown Los Angeles location. Concentrations are presented for 50 compounds in morning air samples. While paraffins (C ≥ 4) were a major hydrocarbon subclass on a ppmC basis, higher aromatics (C ≥ 8) were the major component when taking reactivity considerations into account. Comparison of the results with emission inventory data showed good agreement for many hydrocarbons and for paraffins as a subclass. Measured olefins and aromatics concentrations were substantially lower and higher, respectively, than those expected from inventory data. 相似文献
867.
868.
Z. Szigeti I. Rácz É. Darkól D. Lásztity E. Lehoczki 《Journal of environmental science and health. Part. B》2013,48(3):599-604
Abstract Paraquat/atrazine coresistant (PqAR) and paraquat resistant (PqR) horseweed (Conyza canadensis /L./ Cronq.) plants showed ‐ in the first hour after 0.5 mM paraquat spraying ‐ a decreased catalase activity followed by a slight increase. However, the enzyme activity remained always below the initial value. Sensitive plants showed a significant increase of catalase activity in the first 4 hour after spraying. The transient character of paraquat inhibition, the recovery of photosyn‐thetic activity of the PqAR Conyza plants (characterized by variable fluorescence) after spraying remained unaffected by the Superoxide dismutase (SOD) inhibitor, diethyldithiocarbamate. This indicates that SOD is not involved in the resistance mechanism. Untreated resistant biotypes showed about 2.5 times higher total polyamine and putrescine level than the sensitive one. 100 μM of exogenously added putrescine was observed as having a protecting effect against paraquat in floated leaves of the sensitive biotype only. The resistant leaves were unaffected probably on account of their higher endogenous polyamine level. It is concluded that polyamines may play a role in the paraquat resistance of Conyza canadensis. 相似文献
869.
870.
Recovery of lotic macroinvertebrate communities from disturbance 总被引:7,自引:0,他引:7
J. Bruce Wallace 《Environmental management》1990,14(5):605-620
Ecosystem disturbances produce changes in macrobenthic community structure (abundances, biomass, and production) that persist
for a few weeks to many decades. Examples of disturbances with extremely long-term effects on benthic communities include
contamination by persistent toxic agents, physical changes in habitats, and altered energy inputs. Stream size, retention,
and local geomorphology may ameliorate the influence of disturbances on invertebrates. Disturbances can alter food webs and
may select for favorable genotypes (e.g., insecticidal resistance). Introductions of pesticides into lotic ecosystems, which
do not result in major physical changes within habitats, illustrate several factors that influence invertebrate recovery time
from disturbance. These include: (1) magnitude of original contamination, toxicity, and extent of continued use; (2) spatial
scale of the disturbance; (3) persistence of the pesticide; (4) timing of the contamination in relation to the life history
stages of the organisms; (5) vagility of populations influenced by pesticides; and (6) position within the drainage network.
The ability of macroinvertebrates to recolonize denuded stream habitats may vary greatly depending on regional life histories,
dispersal abilities, and position within the stream network (e.g., headwaters vs larger rivers). Although downstream drift
is the most frequently cited mechanism of invertebrate recolonization following disturbance in middle- and larger-order streams,
evidence is presented that shows aerial recolonization to be potentially important in headwater streams. There is an apparent
stochastic element operating for aerial recolonization, depending on the timing of disturbance and flight periods of various
taxa. Available evidence indicates that recolonization of invertebrate taxa without an aerial adult stage requires longer
periods of time than for those that possess winged, terrestrial adult stages (i.e., most insects). Innovative, manipulative
experiments are needed in order to address recolonization mechanisms of animals inhabiting streams that differ in size, latitude,
disturbance frequency and magnitude, as well as the potential influence of early colonists on successional sequences of species
following disturbance. 相似文献