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291.
Geeta?Mehta Amar?K.?Mohanty Kelby?Thayer Manjusri?Misra Lawrence?T.?DrzalEmail author 《Journal of Polymers and the Environment》2005,13(2):169-175
Biocomposites were made by a novel high volume processing technique named biocomposite sheet molding compound panel (BCSMCP) manufacturing process. This process design was inspired by the commercial glass fiber–polyester resin composite fabrication method called sheet molding compounding (SMC). This process yields continuous production of biocomposites on a large scale, and thus can be easily adopted in industries. A unique fiber dispersion method, which enabled uniform distribution of natural fibers, was used in this process. Consistency of the process was tested by evaluating the repeatability of the resultant materials mechanical properties. The low cost biocomposites produced as a result of the processing will be used for various panel applications such as housing and transportation. The molded samples were tested for various mechanical and thermal properties, in accordance with ASTM procedures. The biocomposites were made with various natural fibers including, big blue stem grass, jute, and industrial hemp. By combining different natural fibers in varying mass fractions, hybrid biocomposites were made using this process. Grass fiber reinforced polyester biocomposites processed by the SMC line showed very promising results. 相似文献
292.
293.
Sustainable Cellular Biocomposites from Natural Fibers and Unsaturated Polyester Resin for Housing Panel Applications 总被引:1,自引:0,他引:1
Rigoberto?Burgue?oEmail author Mario?J.?Quagliata Geeta?Misra?Mehta Amar?K.?Mohanty Manjusri?Misra Lawrence?T.?Drzal 《Journal of Polymers and the Environment》2005,13(2):139-149
Increased environmental awareness and interest in long-term sustainability of material resources has motivated considerable advancements in composite materials made from natural fibers and resins, or biocomposites. In spite of these developments the lower stiffness and strength of biocomposites has limited their applications to non-load-bearing components. This paper presents an overview of a study aimed at showing that the shortcomings of biocomposites can be overcome through hybrid material designs and efficient structural configurations to make them suitable for load bearing structural components. Hybrid blends of natural and synthetic fibers can significantly improve the characteristics of biocomposites with minimal cost and environmental impact, and hierarchical cellular designs can maximize material efficiency in structural components. Periodic and hierarchical cellular plate designs made from natural fibers and unsaturated polyester resin were evaluated experimentally and analytically. Stiffness, strength, and dimensional stability of all-biocomposite and hybrid natural–synthetic material systems were evaluated through material tests while structural performance of cellular plate designs was assessed through flexural tests on laboratory-scale samples. The experimental results were correlated with analytical models for short-fiber composites and cellular structures. The results showed that biocomposites have adequate short-term performance and that they can efficiently compete with housing panels made from conventional structural materials. 相似文献
294.
Hye-Ryoung?Park Sung-Hyo?Chough Yeon-Hum?Yun Soon-Do?YoonEmail author 《Journal of Polymers and the Environment》2005,13(1):81-86
Polymers that can separate toluic acid isomers were synthesized by molecular imprinting technique. Molecular imprinting polymers (MIPs) for each isomer of toluic acids (TA) were synthesized using styrene and 4-vinylpyridine (4-Vpy). The adsorption characteristics of TA isomers, salicylic acid (SA), and benzoic acid (BA) on each MIP were investigated. The materials used for polymerization of TA isomers MIPs were adsorbed relatively well. This verifies that the MIPs which can adsorb template selectively were synthesized. In addition, the quantities of adsorbed TA isomers on the TA isomers MIPs and on the control polymer polymerized without template were compared and discussed. The variation of adsorption ability for MIPs with repeated use was investigated, showing excellent reproducibility. 相似文献
295.
M.?Masudul?Hassan M.?Rabiul?Islam Laurence?T.?Drzal Mubarak?A.?KhanEmail author 《Journal of Polymers and the Environment》2005,13(3):293-300
To improve the mechanical performance of natural lignocellulosic jute yarn, grafting with [3-(trimethoxysilyl) propylmethacrylate] (TMSPM) monomer has been performed on in situ UV radiation and optimized the monomer concentration (30%) and irradiation time (30 min). Effect of various amino acids (1%) as additives in TMSPM with photografted jute yarn at optimized system has been studied. The polymer loading (PL) and tensile properties like tensile strength (TS) and elongation at break (Eb) of treated samples were enhanced by incorporation of amino acids and the highest properties (TS = 300% and Eb = 386%) achieved by the sample treated with l-Arginine (Arg) with 32.5% PL value. Weak acid like 3% acetic acid and inorganic acid like 1% sulfuric acid were also incorporated in the optimized system of TMSPM grafting and compared their effect on the tensile properties with amino acid treated samples. Water absorption and weathering resistance of treated and untreated samples were also performed and treated sample showed lesser water uptake as well as less weight loss and mechanical properties as compared to untreated samples. 相似文献
296.
Application of Cellulose Microfibrils in Polymer Nanocomposites 总被引:1,自引:0,他引:1
William?J.?OrtsEmail author Justin?Shey Syed?H.?Imam Gregory?M.?Glenn Mara?E.?Guttman Jean-Francois?Revol 《Journal of Polymers and the Environment》2005,13(4):301-306
Cellulose microfibrils obtained by the acid hydrolysis of cellulose fibers were added at low concentrations (2–10% w/w) to polymer gels and films as reinforcing agents. Significant changes in mechanical properties, especially maximum load and tensile strength, were obtained for fibrils derived from several cellulosic sources, including cotton, softwood, and bacterial cellulose. For extruded starch plastics, the addition of cotton-derived microfibrils at 10.3% (w/w) concentration increased Young’s modulus by 5-fold relative to a control sample with no cellulose reinforcement. Preliminary data suggests that shear alignment significantly improves tensile strength. Addition of microfibrils does not always change mechanical properties in a predictable direction. Whereas tensile strength and modulus were shown to increase during addition of microfibrils to an extruded starch thermoplastic and a cast latex film, these parameters decreased when microfibrils were added to a starch–pectin blend, implying that complex interactions are involved in the application of these reinforcing agents. 相似文献
297.
Mechanisms of cross-shelf transport of crab megalopae inferred from a time series of daily abundance
From 20 July 1982 to 19 July 1984, crab megalopae were trapped daily from the Scripps Institution of Oceanography pier. Pachygrapsus crassipes, Portunus xantusii, Cancer spp., Hemigrapsus spp., and Majid crab megalopae dominated the catch. Yearly, seasonal, and daily variations in the magnitude of the catch were observed. Yearly and seasonal variations were probably due to a strong El Niño event that occurred during the study and to the timing of spawning and duration of the larval phase, respectively. Daily variation was correlated with oceanographic processes that can transport larvae to shore. Catch of some taxon during some seasons correlated with wind stress suggesting that transport was wind driven. The correlations were, however, weak and the sign of the correlation varied between years. The maximum daily tidal range was significantly correlated (cross-correlations and cross Fourier analysis) to both daily seawater temperature anomalies (surface and bottom) and daily catch of crab megalopae in all taxa enumerated. Significant correlations between tidal range and temperature anomalies suggest that temperature anomalies were primarily due to the shoreward transport of warm and cold water by the internal tides. The consistent and relatively strong relationship between tidal range and catch of megalopae (the cross-Fourier analysis suggests that from 20 to >90% of the variation in catch can be attributed to variation in the tidal range) suggest that much of the shoreward transport of megalopae was via the internal tides. Shoreward transport of larvae by internal tides may be due to internal cold bores or convergences over large tidally generated internal waves (solitons). Peak catches of megalopae, however, were often not associated with cold anomalies suggesting that transport was due to moving convergences over internal waves. 相似文献
298.
Although choristoderes have a good Lower Cretaceous record in Asia, they have never previously been recorded from Jurassic
deposits. Here we describe fragmentary vertebral material referable to Choristodera indet. from the Middle Jurassic Balabansai
Svita of the Fergana Valley, Kyrgyzstan. This provides a significant range extension for the group in Asia and shows that
choristoderes already had a Pan-Laurasian distribution in the Jurassic. 相似文献
299.
Henner Hollert Susanne Heise Steffen Keiter Peter Heininger Ulrich F?rstner 《Umweltwissenschaften und Schadstoff-Forschung》2006,18(2):148
Tagungsankündigungen
Sedimenttoxizit?t — ein inhaltlicher Schwerpunkt beim SETAC Europe 16th Annual Meeting World Forum Convention Center in Den Haag, Niederlangden, 7–11 Mai 2006 相似文献300.
This article presents the results of laboratory tests on the combined effect of whole-body vibration (WBV) and hand-arm vibration (HAV). The reactions of subjects exposed to various combinations of vibration were recorded. The vibrotactile perception threshold (VPT) test identified changes caused by exposure to vibration. Ten male subjects met the criteria of the study. There were 4 series of tests: a reference test and tests after exposure to HAV, WBV, and after simultaneous exposure to HAV and WBV. An analysis of the results (6000 ascending and descending VPTs) showed that the changes in VPTs were greatest after simultaneous exposure to both kinds of vibration. The increase in VPT, for all stimulus frequencies, was then higher than after exposure to HAV or WBV only. 相似文献