Analysing Seasonal Differences between a Soil Water Balance Model and in Situ Soil Moisture Measurementsat Nine Locations Across Europe

We compared soil moisture from the soil water balance model for European Water Accounting (swbEWA) with in situ observations from nine locations in three European climatic zones (continental, Mediterranean and maritime temperate), for different periods between 2003 and 2011. Despite the simplicity of the swbEWA model, the patterns of temporal changes in soil moisture content are well represented at all locations. Annual averages show that the model overestimates the soil moisture content, and that overestimations are the smallest when measurements are obtained from more than one depth. These results suggest that the relationship between simulated and observed soil moisture also depends on the number of measurements and the depth over which they are taken. In the continental climate, where snow cover and frozen soil influence soil moisture, we observe higher root mean square error values in winter months. However, in the Mediterranean and maritime temperate climates, we do not observe clear common seasonal patterns in the soil moisture profile, which makes it difficult to relate the model’s accuracy to climate. With the percentage of correctness and probability of detection measures, we tested the model performance in simulating dry versus non-dry events. The percentage of the correctly classified dry and non-dry events is higher than 84 % at all locations, whereas the probability to detect dry events is significantly lower, exceeding 50 % at only four out of nine stations. The frequency distribution of consecutive days with dry soil (CDDS) confirms the model performance: higher number of short dry periods (with less than 20 days of soil moisture near wilting point) are reproduced and observed in continental climates, whereas long dry periods (longer than 50 days) are noted in the Mediterranean climate. Overall, the statistical measures suggest that the model produces the highest accuracy in summer months at the stations in continental climates, whereas in the Mediterranean climate, the accuracy is slightly higher in the colder seasons.     

Metal concentrations in water,sediment and three fish species from the Danube River,Serbia: a cause for environmental concern

Environmental Science and Pollution Research - The aim of this study was to investigate the presence of metal contamination in water, sediments and three different fish species. All samples were...     

The potential impact of geological environment on health status of residents of the Slovak Republic

In order to assess the potential impact of the geological environment on the health of the population of the Slovak Republic, the geological environment was divided into eight major units: Paleozoic, Crystalline, Carbonatic Mesozoic and basal Paleogene, Carbonatic-silicate Mesozoic and Paleogene, Paleogene Flysch, Neovolcanics, Neogene and Quaternary sediments. Based on these geological units, the databases of environmental indicators (chemical elements/parameters in groundwater and soils) and health indicators (concerning health status and demographic development of the population) were compiled. The geological environment of the Neogene volcanics (andesites and basalts) has been clearly documented as having the least favourable impact on the health of Slovak population, while Paleogene Flysch geological environment (sandstones, shales, claystones) has the most favourable impact. The most significant differences between these two geological environments were observed, especially for the following health indicators: SMRI6364 (cerebral infarction and strokes) more than 70 %, SMRK (digestive system) 55 %, REI (circulatory system) and REE (endocrine and metabolic system) almost 40 % and REC (malignant neoplasms) more than 30 %. These results can likely be associated with deficit contents of Ca and Mg in groundwater from the Neogene volcanics that are only about half the level of Ca and Mg in groundwater of the Paleogene sediments.     

Relation Between Edaphic Factors and Vegetation Development on Copper Mine Wastes: A Case Study From Bor (Serbia,SE Europe)

The relationship between edaphic characteristics and vegetation growing on mine wastes in the Bor region (East Serbia, SE Europe) was studied using multivariate statistical analysis. The influence of edaphic factors on the composition of plant life-forms was also investigated, since it could reflect strategies for the avoidance of or tolerance to disturbances of ecosystems. The goal was to provide potential models for the restoration and management of this and similar mine waste areas. The results of this study imply that soil textures, nitrogen contents, reclamation technology and the presence of hydrothermally altered andesite as the type of bedrock significantly influenced plant colonization and vegetation composition of the Bor mine wastes. These edaphic factors explained 30.3 % of the total variation in the vegetation data set. It was also revealed that the pattern of plant life-forms found on the considered site groups corresponded to the soil texture. Based on their relative abundance on the investigated sites and relationships with soil properties it is concluded that therophytes and geophytes are unsuccessful primary colonizers of the Bor mine wastes. Hemicryptophytes of psammophytic character were the most successful primary colonizers and therefore potential candidates for anthropogenically-assisted natural recovery. This study suggested that an assessment of edaphic factors should be widely used in the characterization of mine wastes prior to reclamation. Estimation of their role in the development of existing mine vegetation should predate reclamation procedures. Thus, approaches based on adequate plant life-forms should have a more prominent role in future mine reclamation schemes.     

Sources of organochlorine pesticides in air in an urban Mediterranean environment: volatilisation from soil

Organochlorine pesticide (OCP) cycling was studied in the area of Banja Luka, Bosnia and Herzegovina, over 3 days in summer with high temporal (4 h-means) and spatial (3 sites distanced 3-6 km) resolutions. Elevated levels of DDX compounds (i.e. o,p'- and p,p'-isomers of DDT, DDE and DDD, 44-74 pg m(-3) at the urban sites and 27 pg m(-3) as a background level), HCH (α-, β- and γ-isomers, 52-70 vs. 147 pg m(-3)), HCB (34-48 vs. <0.1 pg m(-3)) and pentachlorobenzene (6.8-9.9 vs. 6.0 pg m(-3)) were found. The variation of OCP levels at the two urban sites was not in phase, except for most DDX compounds. This was related to background levels, which for HCH were higher than in the urban area. Vertical profiles between samples collected from 1.1 and 2.3 m (part of the time 0.6 and 2.3 m) above a soil, which was only moderately contaminated by OCPs (0.12 ng g(-1) HCH, 0.11 ng g(-1) DDX, 0.44 ng g(-1) HCB) were analysed. Volatilisation from the ground caused negative vertical concentration gradients of HCH isomers (day and night), but not for HCB (except for 1 day-time sample) and DDX compounds (except p,p'-DDD, day-time, sporadically). The concentration in air and the vertical concentration gradient of the HCH isomers varied with air temperature (day-time maxima), while the variation of the HCB concentration was inversely related to air temperature and was determined by mixing (night-time maxima). α- and β-HCH were volatilised from soil throughout the three days, even during periods of cooling. Fugacity calculations, based on the absorption in soil organic matter as the process determining retention in soil, underestimated the volatilisation of β-HCH and p,p'-DDD. It is concluded that the representativeness of point measurements of OCPs in urban areas is limited by the spatial variability of soil contamination.     

Pollution of soils with organophosphorus flame retardants and plasticizers

The detection of the three organophosphate esters TCEP, TCPP and TBEP in soil samples indicates that pollution of soils from diffuse atmospheric sources has to be considered in risk assessments.     

Investigation of bioremediation potential of zymogenous bacteria and fungi for crude oil degradation

Bioremediation potential of bacteria and fungi isolated from sludge samples has been investigated (Danube alluvium, Pančevo, Serbia). Total isolated microorganisms were divided into three parts. One part was added with actidione antifungicide. The second part was added with streptomycin antibiotic. The third part was without additives. Paraffinic type of crude oil was a substrate for assessment of bioremediation potential. The simulated oil biodegradation lasted 30, 60 and 90 days. Parallel with that, the experiments with blind trial were conducted. Extracts were isolated from the samples with chloroform in a separate funnel. They were assayed for the group composition (alkanes, aromatics, alcohols and fatty acids) by column chromatography. Alkane fraction was analysed by gas chromatography—mass spectrometry (GC–MS). The most intense oil degradation was achieved in the experiments with bacteria, somewhat weaker with consortium of fungi and bacteria, and the weakest bioremediation potential in these experiments was shown by fungi.