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681.
Contribution to biomonitoring of some trace metals by deciduous tree leaves in urban areas 总被引:1,自引:0,他引:1
Tomasević M Vukmirović Z Rajsić S Tasić M Stevanović B 《Environmental monitoring and assessment》2008,137(1-3):393-401
Leaves of the deciduous tree species, horse chestnut (Aesculus hippocastanum L.) and Turkish hazel (Corylus colurna L.) were used as accumulative biomonitors of trace metal pollution in the urban area of Belgrade. Using differential pulse
anodic stripping voltametry, trace metal concentrations (Pb, Cu, Zn, Cd) were determined at the single leaf level (ten leaves
per species, per month), during two successive years with markedly different atmospheric level of trace metals. Increased
trace metal concentrations in the leaves of A. hippocastanum reflected elevated atmospheric trace metal pollution, whereas C. colurna L. did not respond accordingly. The contents of Pb and Zn in soil over the same period also followed this trend. Anatomical
analyses, in young as well as in old leaves of both species, indicated typical foliar injuries of plants exposed to stressful
air conditions. Water relations that correspond to leaf age may have contributed to the considerable trace metal accumulation
in leaves. 相似文献
682.
Grčić Ivana Marčec Jan Radetić Lucija Radovan Ana-Maria Melnjak Ivana Jajčinović Igor Brnardić Ivan 《Environmental science and pollution research international》2021,28(15):18354-18367
Environmental Science and Pollution Research - In this work, we present the application of solar photocatalysis for air purification including toxic substances such as ammonia and methane normally... 相似文献
683.
Gulchohra Aliyeva Carrie Amber Sinnott-Clark Ondřej Audy Lenka Škrdlíková Petr Kukučka Jana Klánová Crispin Halsall 《Environmental science and pollution research international》2018,25(32):31863-31873
PBDEs were measured in air and soil across Azerbaijan to establish contemporary concentrations at 13 urban and rural sites. Polyurethane foam passive air samplers (PUF-PAS) were deployed for a period of a month with surface soil samples collected at the same sites. Unlike organochlorine pesticides previously surveyed by our group, PBDE concentrations in both contemporary air and soil were low in comparison to recent European and Asian studies. For example, mean ∑9PBDE concentrations in air and soil were 7.13 ± 1.66 pg m?3 and 168 ± 57 pg g?1, respectively. The fully brominated BDE-209 was the most abundant congener observed in soil (174.8 ± 58.5 pg g?1), comprising ~ 96% of ∑10PBDE. However, the PAS-derived air concentrations for highly brominated congeners must be viewed with caution as there is uncertainty over the uptake rates of particle-bound chemicals using these devices. Some of the highest concentrations in air were observed at sites with the highest wind speeds and at several remote locations in the north of the country and this requires further research. Levels of BDE-47 and 99 (the two most abundant congeners in the widely used penta-formulation) were lower than levels reported elsewhere suggesting limited use/import of the penta-BDE formulation in Azerbaijan. 相似文献
684.
Application of a scenario-based modeling system to evaluate the air quality impacts of future growth
Jülide Kahyaoğlu-Koračin Scott D. Bassett David A. Mouat Alan W. Gertler 《Atmospheric environment (Oxford, England : 1994)》2009,43(5):1021-1028
The structure and design of future urban development can have significant adverse effects on air pollutant emissions as well as other environmental factors. When considering the future impact of growth on mobile source emissions, we generally model the increase in vehicle kilometers traveled (VKT) as a function of population growth. However, diverse and poorly planned urban development (i.e., urban sprawl) can force higher rates of motor vehicle use and in return increase levels of pollutant emissions than alternative land-use scenarios. The objective of this study is to develop and implement an air quality assessment tool that takes into account the influence of alternative growth and development scenarios on air quality.The use of scenario-based techniques in land use planning has been around since the late 1940s and been tested in many different applications to aid in decision-making. In this study, we introduce the development of an advanced interactive scenario-based land use and atmospheric chemistry modeling system coupled with a GIS (Geographical Information System) framework. The modeling system is designed to be modular and includes land use/land cover information, transportation, meteorological, emissions, and photochemical modeling components. The methods and modularity of the developed system allow its application to both broad areas and applications.To investigate the impact of possible land use change and urbanization, we evaluated a set of alternative future patterns of land use developed for a study area in Southwest California. Four land use and two population variants (increases of 500k and 1M) were considered. Overall, a Regional Low-Density Future was seen to have the highest pollutant emissions, largest increase in VKT, and the greatest impact on air quality. On the other hand, a Three-Centers Future appeared to be the most beneficial alternative future land-use scenario in terms of air quality. For all cases, the increase in population was the main factor leading to the change on predicted pollutant levels. 相似文献
685.
Mihail Ionescu S. Sinharoy Zoran S. Petrović 《Journal of Polymers and the Environment》2009,17(2):123-130
The synthesis of telechelic polyacetals with terminal hydroxyl groups (polyacetal polyols), by the reaction of triethylene
glycol divinyl ether with dipropylene glycol in the presence of trimethylolpropane or other triols or diols as starters, in
acidic catalysis, has been studied. The synthesized liquid polyacetal triols and polyacetal diols were characterized by hydroxyl
number, viscosity, acidity, number average molecular weight (Mn), weight average molecular weight (Mw), molecular weight distribution (Mw/Mn), FT-IR spectra. The obtained polyacetals were transformed in cast elastomers by the reaction with the isocyanate Mondur
CD (modified diphenyl methane diisocyanate) with properties very close to the elastic polyurethanes obtained by using conventional
polyether triols, copolymers propylene oxide–ethylene oxide. The polyacetal polyols are suitable for the synthesis of elastic
polyurethanes (polyurethane elastomers, flexible polyurethane foams). Polyacetals are well known biodegradable polymers. Therefore,
the polyurethanes based on polyacetal polyols are expected to be biodegradable. 相似文献
686.
We assessed human impacts on ecosystems by calculating the proportion of aboveground net primary production appropriated by
humans (aHANPP) in the territory of the Czech Republic. The human appropriation of aboveground net primary production reached
21.5 Tg C per year in 2006 or 56% of the annual potential natural productivity. Harvested productivity equivalent aNPPH is contributing to the overall appropriation of photosynthetic production by 80%. Considerable productivity losses have been
induced by agricultural land conversion and urbanization. While artificial surfaces are responsible for the appropriation
of whole ecosystem production, productivity of urban green areas and managed forests can even exceed natural productivity
levels. In the period 1990–2000, the aHANPP dropped by 7%, but the indicator shows an increase by over 2% in the period 2000–2006.
The indicator of human appropriation of net primary production enables translation of land cover changes into measures of
ecosystem services affected by human activities. We found aHANPP to be a suitable indicator of human impacts on ecosystems,
as it detects trends and enables spatial mapping of human impacts. 相似文献
687.
Klobučar GI Stambuk A Srut M Husnjak I Merkaš M Traven L Cvetković Z 《Environmental pollution (Barking, Essex : 1987)》2011,159(4):841-849
There is a growing interest for the application of biomakers to field-collected earthworms. Therefore we have evaluated the usability of native populations of endogeic, widely distributed earthworm Aporrectodea caliginosa in the assessment of soil genotoxicity using the Comet assay. Validation of the Comet assay on earthworm coelomocytes has been established using commercially available Eisenia fetida exposed to copper, cadmium, and pentachlorophenol, along with A. caliginosa exposed to copper in a filter paper contact test. Neutral red retention time (NRRT) assay was conducted on copper exposed and field-collected earthworms. Significant DNA and lysosomal damage was measured using Comet and NRRT assays in native populations of A. caliginosa sampled from the polluted soils in the urban area in comparison to the earthworms from the reference site. The results of this study confirm the employment of A. caliginosa as a suitable species for the in situ soil toxicity and genotoxicity field surveys. 相似文献
688.
Kačániová M Juráček M Chlebo R Kňazovická V Kadasi-Horáková M Kunová S Lejková J Haščík P Mareček J Simko M 《Journal of environmental science and health. Part. B》2011,46(7):623-629
Contamination by microscopic fungi and mycotoxins in different bee pollen samples, which were stored under three different ways of storing as freezing, drying and UV radiation, was investigated. During spring 2009, 45 samples of bee-collected pollen were gathered from beekeepers who placed their bee colonies on monocultures of sunflower, rape and poppy fields within their flying distance. Bee pollen was collected from bees' legs by special devices placed at the entrance to hives. Samples were examined for the concentration and identification of microscopic fungi able to grow on Malt and Czapek-Dox agar and mycotoxins content [deoxynivalenol (DON), T-2 toxin (T-2), zearalenone (ZON) and total aflatoxins (AFL), fumonisins (FUM), ochratoxins (OTA)] by direct competitive enzyme-linked immunosorbent assays (ELISA). The total number of microscopic fungi in this study ranged from 2.98 ± 0.02 in frozen sunflower bee pollen to 4.06 ± 0.10 log cfu.g(-1) in sunflower bee pollen after UV radiation. In this study, 449 isolates belonging to 21 fungal species representing 9 genera were found in 45 samples of bee pollen. The total isolates were detected in frozen poppy pollen 29, rape pollen 40, sunflower pollen 80, in dried poppy pollen 12, rape pollen 36, sunflower 78, in poppy pollen after UV radiation treatment 54, rape 59 and sunflower 58. The most frequent isolates of microscopic fungi found in bee pollen samples of all prevalent species were Mucor mucedo (49 isolates), Alternaria alternata (40 isolates), Mucor hiemalis (40 isolates), Aspergillus fumigatus (33 isolates) and Cladosporium cladosporioides (31 isolates). The most frequently found isolates were detected in sunflower bee pollen frozen (80 isolates) and the lowest number of isolates was observed in poppy bee pollen dried (12 isolates). The most prevalent mycotoxin of poppy bee pollen was ZON (361.55 ± 0.26 μg.kg(-1)), in rape bee pollen T-2 toxin (265.40 ± 0.18 μg.kg(-1)) and in sunflower bee pollen T-2 toxin (364.72 ± 0.13 μg.kg(-1)) in all cases in frozen samples. 相似文献
689.
This study aimed at investigating the cellular distribution of Hg in the lichens Cladonia arbuscula subsp. mitis and Peltigera rufescens treated with Hg2+ and at testing if Hg treatment affects selected physiological parameters. In both species, increasing Hg accumulation under increasing Hg supply in the treatment solutions was found. P. rufescens showed a higher intracellular accumulation. Photosynthetic parameters were negatively affected in both species, as indicated by the decrease in photosynthetic pigments content, photosynthetic efficiency and chlorophyll integrity. Cell membranes of both species endured damage as indicated by the increase in the concentration of products of lipid peroxidation and decrease in ergosterol content. Nevertheless, differences between the two species were found, suggesting a differential sensitivity to Hg. 相似文献
690.
Köck-Schulmeyer M Ginebreda A Postigo C López-Serna R Pérez S Brix R Llorca M de Alda ML Petrović M Munné A Tirapu L Barceló D 《Chemosphere》2011,82(5):670-678
The presence of sewage-borne micro contaminants in environmental waters is directly related to the discharge of treated effluents from wastewater treatment plants (WWTP) and the flow rate of the receiving river waters. Mediterranean rivers, in particular, are characterized by important fluctuations in the flow rates and heavy pollution pressures resulting from extensive urban, industrial and agricultural activities. This translates into contamination levels in these rivers often higher than those in other larger European basins. The present work provides an overview of the occurrence of five groups of organic contaminants (131 compounds) namely pharmaceuticals, illicit drugs, polar pesticides, estrogens, alkylphenols and related ethoxylates in WWTP tertiary treatment effluents. Data gathered during a period of water reuse carried out in the lower stretch of the Llobregat river (NE Spain), in the surroundings of the town of Barcelona as a consequence of the severe drought that took place along the years 2007-2008 are presented as illustrative example. In general, measured concentrations of the target compounds were in the low to mid ng L−1 range. The total concentration of each compound class downstream to the discharge point was similar or slightly higher than that found upstream. Regarding the loads calculated for each compound, the relative contribution from the river upstream and the tertiary effluent were highly compound depending with no apparent trend. However, estimation of the overall bulk loads for each compound class determined in the Llobregat river showed the following rank order: pharmaceuticals > alkylphenols > pesticides > illicit drugs ? estrogens. 相似文献