Assessment of the maximum possible liquid superheat during flashing leak flow

During the discharge of flashing liquids through leaks due to abrupt depressurization a transient thermodynamic non-equilibrium in the form of a boiling delay in the superheated liquid flow can occur. As a consequence the actual mass flow quality is smaller than calculated under the assumption of an immediate adjustment of the thermodynamic equilibrium between the phases. For the prediction of the leak mass flow for a given pressure difference the magnitude of this self-adjusting mass flow quality is needed.

Most of the models cited in the literature include only the equilibrium mass quality as limiting quantity and ignore further effects as that of the depressurization velocity or the mean nucleus distance. For the assessment of the maximum possible liquid superheat during flashing only the conduction heat transfer from a stagnant liquid to the bubble surface is used to describe the bubble growth.

The sub-model for the bubble growth due to expansion and mass transfer necessary for the global prediction of the transient thermodynamic non-equilibrium in flashing liquids was validated using bubble radii measured by Hooper et al. [Bubble growth and pressure relationship in the flashing of superheated water. Technical publication 6904, Mechanical Engineering Department, University of Toronto, 1969] for the case of a sudden depressurization of initially saturated water. On this basis the calculated time-dependent temperature field, the actual mass quality, the mean liquid temperature and, in comparison to the corresponding values based on the assumption of immediate thermodynamic equilibrium, the maximum possible liquid superheat are predicted.     

Synthesis of poly(hydroxyalkanoate) from hydrolyzed linseed oil

Pseudomonas putida was grown on a mixture of long-chain fatty acids obtained by hydrolysis of linseed oil. A poly(3-hydroxyalkanoate) containing 51.2% of unsaturated monomers was obtained. A considerable percentage (13.6%) was constituted by C₁₄ and C₁₆ monomers containing three double-bonds in the side chains. The polymer showed a high tendency to crosslink when it was kept in presence of air. In the crosslinked polymer no polyunsaturated monomers could be detected.     

Laboratory scale studies on gaseous emissions generated by the incineration of an artificial automotive shredder residue presenting a critical composition

Car manufacturers must eliminate automotive shredder residues (ASR). Two ways of incineration are of interest: at 850°C in municipal waste incinerators or at higher temperatures, above 1100°C in cement plants. These processes reduce the mass and the volume of waste to be disposed of in landfills and energy recovery might be possible. Regulations govern the emission of gaseous effluents to control environmental risk. To determine gaseous effluents from a pilot sacle or an industrial incineration plant, an artificial ASR was made by mixing three representative organic polymers present in the real ASR, namely polyvinylchloride, polyurethane and rubber. This mixture was incinerated at 850 and 1100°C in laboratory experiments and the analyses of the principal gaseous effluents such as carbon oxides, nitrogen oxides, volatile organic compounds, hydrochloric and hydrocyanic acids and sulphur compounds are presented and discussed. Lastly, in order to simulate artificial ASR behaviour, the composition of the combustion gases at equilibrium was calculated using a Gibbs energy minimisation code.     

The impact of impression‐management tactics on supervisor ratings of organizational citizenship behavior

Previous research indicates that the use of impression management is related to supervisor ratings of employee likeability and job performance. It has been argued, though, that employees might also use impression management so that their superiors will see them as ‘good soldiers’ who engage in high levels of organizational citizenship behaviors (OCBs). This study investigates the ways in which three types of impression management—namely, job‐focused, self‐focused, and supervisor‐focused tactics of impression management—influence supervisor ratings of OCB. Using a sample of 122 supervisor‐subordinate dyads, the findings indicate that supervisor‐focused tactics of impression management are positively related to OCB ratings, while job‐focused tactics are negatively related to such evaluations. Additionally, citizenship behaviors are positively related to supervisor liking of the employee and overall ratings of job performance. Finally, the results suggest that OCB ratings mediate the relationship between supervisor‐focused tactics of impression management and supervisor evaluations of employee likeability. Some implications of this study and directions for future research are also addressed. Copyright © 2006 John Wiley & Sons, Ltd.     

Emotional social support and job burnout among high‐school teachers: is it all due to dispositional affectivity?

The authors investigated whether the relationship between the contents of emotional social support and job burnout among high‐school teachers is spurious because of the role of dispositional positive and negative affectivity. A national sample of 339 teachers was surveyed via a web‐based procedure. Hierarchical regression analyses did not support spuriousness; emotional social support was uniquely predictive of three dimensions of burnout controlling for affectivity. As positive emotional social support increased, emotional exhaustion and cynicism decreased, and professional efficacy increased. As negative emotional social support increased, emotional exhaustion and cynicism also increased. Commonality analyses based on the present data and data reported by K. L. Zellars and P. L. Perrewé (2001; Journal of Applied Psychology, 86, 459–467) provided additional support for the unique role of emotional social support on burnout, but these analyses suggest a greater role of affectivity than emotional social support. These findings have implications for research on burnout as well as the prevention of burnout among teachers. Copyright © 2006 John Wiley & Sons, Ltd.     

Locus of control at work: a meta‐analysis

This study meta‐analyzed the relationships between locus of control (LOC) and a wide range of work outcomes. We categorized these outcomes according to three theoretical perspectives: LOC and well‐being, LOC and motivation, and LOC and behavioral orientation. Hypotheses reflecting these three perspectives were proposed and tested. It was found that internal locus was positively associated with favorable work outcomes, such as positive task and social experiences, and greater job motivation. Our findings are discussed in relation to research on core self‐evaluation and the Big Five personality traits. Copyright © 2006 John Wiley & Sons, Ltd.     

On the response of 500 gal propane tanks to a 25% engulfing fire

This paper presents detailed data on the thermal response of two 500 gal ASME code propane tanks that were 25% engulfed in a hydrocarbon fire. These tests were done as part of an overall test programme to study thermal protection systems for propane-filled railway tank-cars.

The fire was generated using an array of 25 liquid propane-fuelled burners. This provided a luminous fire that engulfed 25% of the tank surface on one side. The intent of these tests was to model a severe partially engulfing fire situation.

The paper presents data on the tank wall and lading temperatures and tank internal pressure. In the first test the wind reduced the fire heating and resulted in a late failure of the tank at 46 min. This tank failed catastrophically with a powerful boiling liquid expanding vapour explosion (BLEVE). In the other test, the fire heating was very severe and steady and this tank failed very quickly in 8 min as a finite rupture with massive two-phase jet release. The reasons for these different outcomes are discussed. The different failures provide a range of realistic outcomes for the subject tank and fire condition.     

On the thermal rupture of 1.9 m propane pressure vessels with defects in their thermal protection system

This paper describes the results from a series of fire tests that were carried out to measure the effect of defects in thermal protection systems on fire engulfed propane pressure vessels.

In North America thermal protection is used to protect dangerous goods rail tank-cars from accidental fire impingement. They are designed so that a tank-car will not rupture for 100 min in a defined engulfing fire, or 30 min in a defined torching fire. One common system includes a 13 mm blanket of high-temperature ceramic fibre thermal insulation covered with a 3 mm steel jacket. Recent inspections have shown that some tanks have significant defects in these thermal protection systems. This work was done to establish what levels of defect are acceptable from a safety standpoint.

The tests were conducted using 1890 l (500 US gallon) ASME code propane pressure vessels (commonly called tanks in the propane industry). The defects tested covered 8% and 15% of the tank surface. The tanks were 25% engulfed in a fire that simulated a hydrocarbon pool fire with an effective blackbody temperature of 870 °C.

The fire testing showed that even relatively small defects can result in tank rupture if the defect area is engulfed in a severe fire, and the defect area is not wetted by liquid from the inside. A wall failure prediction technique based on uniaxial high-temperature stress rupture test data has been developed and agrees well with the observed failure times.     

Current status and research on E-waste issues in Asia

Rapid economic growth in Asia and the increasing transboundary movement of secondary resources will increasingly require both 3R endeavors (reduce, reuse, recycle) in each country and appropriate control of international material cycles. Recently, managing electrical and electronic waste (E-waste) has become an important target for domestic and international material cycles from the viewpoints of environmental preservation and resource utilization efficiency. To understand the current status of E-waste issues in the context of international material cycles and to discuss the future tasks related to achieving 3R in the region, we organized the National Institute for Environmental Studies (NIES) E-waste Workshop in December 2004. This article reviews past studies on E-waste and briefly describes the topics presented and discussions held at the workshop. The topics at the workshop included E-waste generation, recycling systems, international trade, and environmental impacts. In addition, we discussed various issues such as terminology, current environmental concerns, and possible solutions. Transboundary shipments of E-waste should be conducted taking into consideration the concept of sustainable development. The direction of future research and possible collaborations are also discussed.