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731.
E. Smith R. Gordon C. Bourque A. Campbell S. Génermont P. Rochette M. Mkhabela 《Journal of environmental management》2009
A need exists to improve the utilization of manure nutrients by minimizing NH3 emissions from land application of manure. Management strategies to reduce NH3 emissions are available; however, few have been validated under Canadian conditions. A well tested and accurate simulation model, however, can help overcome this challenge by determining appropriate management strategies for a given set of field conditions. 相似文献
732.
There is growing concern that recreational shoreline angling activity may negatively impact littoral and riparian habitats
independent of any direct or indirect influences of fish harvest or fishing mortality through mechanisms such as disturbance
(e.g., trampling, erosion) and pollution (e.g., littering). We sampled a suite of aquatic and terrestrial variables (i.e.,
water quality, aquatic and terrestrial macrophytes, soil compaction, anthropogenic refuse) at 14 high shoreline angling-activity
sites (identified by way of interviews with conservation officers and angling clubs) within an urban area (Ottawa, Canada).
For each high angling-activity site, a nearby corresponding low angling-activity site was sampled for comparison. We found
that the percentage of barren area and soil compaction were greater in areas of high angling activity compared with areas
that experienced relatively low angling activity. In addition, terrestrial and aquatic macrophyte density, height, and diversity
were lower at high angling-activity sites. Angling- and non-angling-related litter was present in large quantities at each
of the high angling-activity sites, and comparatively little litter was found at low angling-activity sites. Collectively,
these findings indicate that shoreline angling does alter the riparian environment, contributing to pollution and environmental
degradation in areas of high angling intensity. With growing interest in providing urban angling opportunities and in response
to increasing interest in developing protected areas and parks, a better understanding of the ecologic impacts of shoreline
angling is necessary to address multiuser conflicts, to develop angler outreach and educational materials, and to optimize
management of angling effort to maintain ecologic integrity of riparian and aquatic ecosystems. 相似文献
733.
Hydrogeomorphic (HGM) functional assessment models were used to assess whether function in created wetlands of two ages (1 year
old and >12 years old) was equivalent to that of natural (reference) mainstem floodplain wetlands. Reference wetlands scored
higher than both created age classes for providing energy dissipation and short-term surface water storage. Reference wetlands scored higher in maintaining native plant community and structure than 1-year-old sites, and 12-year-old wetlands scored higher than reference sites for providing vertebrate habitat structure. Analysis of individual model variables showed that reference wetlands had greater vegetative biomass and higher soil organic
matter content than both created wetland age classes. Created wetlands were farther from natural wetlands and had smaller
mean forest patch sizes within a 1-km-radius circle around the site than did the reference sites, indicating less hydrologic
connectivity. Created wetlands also had less microtopographic variation than reference wetlands. The 1-year-old created sites
were placed in landscape settings with greater land use diversity and road density than reference sites. The 12-year-old sites
had a higher gradient and a higher percentage of their surrounding area in urban land use. These results show that the created
wetlands were significantly structurally different (if not functionally so) from reference wetlands even after 12 years. The
most profound differences were in hydrology and the characteristics of the surrounding landscape. More attention needs to
be focused on placing created wetlands in appropriate settings to encourage proper hydrodynamics, eliminate habitat fragmentation,
and minimize the effects of stressors to the site. 相似文献
734.
Use of Descriptors of Ecosystem Functioning for Monitoring a National Park Network: A Remote Sensing Approach 总被引:1,自引:0,他引:1
Baseline assessments and monitoring of protected areas are essential for making management decisions, evaluating the effectiveness
of management practices, and tracking the effects of global changes. For these purposes, the analysis of functional attributes
of ecosystems (i.e., different aspects of the exchange of matter and energy) has advantages over the traditional use of structural
attributes, like a quicker response to disturbances and the fact that they are easily monitored through remote sensing. In
this study, we described the spatiotemporal patterns of different aspects of the ecosystem functioning of the Spanish national
parks and their response to environmental changes between 1982 and 2006. To do so, we used the NOAA/AVHRR-GIMMS dataset of
the Normalized Difference Vegetation Index (NDVI), a linear estimator of the fraction of photosynthetic active radiation intercepted
by vegetation, which is the main control of carbon gains. Nearly all parks have significantly changed during the last 25 years:
The radiation interception has increased, the contrast between the growing and nongrowing seasons has diminished, and the
dates of maximum and minimum interception have advanced. Some parks concentrated more changes than others and the degree of
change varied depending on their different environmental conditions, management, and conservation histories. Our approach
identified reference conditions and temporal changes for different aspects of ecosystem functioning, which can be used for
management purposes of protected areas in response to global changes. 相似文献
735.
Yung-Ping Tseng Gerard T. Kyle C. Scott Shafer Alan R. Graefe Timothy A. Bradle Michael A. Schuett 《Environmental management》2009,43(3):496-507
Along with the growing boating population and the number of boats in use on limited inland waterways, boater expectations
of setting density, safety perceptions, and the associated impacts on their experience (e.g., satisfaction) are becoming increasingly
important. The primary purpose of this article was to explore a recreational boating crowding–satisfaction model derived from
previous work using safety and enjoyment as mediating variables. We also tested our crowding–satisfaction model among day
and overnight users. Our analysis revealed no significant difference between day and overnight users for any of the relationships
tested in our model. Our final model indicated as respondents’ expectations for seeing people increased along with their feelings
of being crowded, they were more inclined to consider the conditions on the lake as being unsafe. They were also more inclined
to indicate that the number of people they had seen on the lake detracted from their boating experience. Respondents’ satisfaction
was tied to their perceptions of crowding. Mediating variables illustrated that the relationship was conditioned by perceptions
of safety and enjoyment. Analysis of the indirect effect observed in our study illustrate that when the number of people seen
on the lake exceed respondents’ expectations, their perceptions of safety and enjoyment both decline, resulting in lower satisfaction.
These findings have implications for managing recreational boating use on inland lake systems. Given the role played by expectations
in our model, efforts to communicate with boaters about conditions on these waterways is important for helping them plan their
boating experience and avoid situations they consider unsafe or unsatisfactory. 相似文献
736.
A compilation has been undertaken of data which can be used to derive animal product transfer coefficients for radionuclides, including an extensive review of Russian language information. The resultant database has been used to provide recommended transfer coefficient values for a range of radionuclides to (i) cow, sheep and goat milk, (ii) meat (muscle) of cattle, sheep, goats, pigs and poultry and (iii) eggs. The values are used in a new IAEA handbook on transfer parameters which replaces that referred to as ‘TRS 364’. The paper outlines the approaches and procedures used to identify and collate data, and assumptions used. There are notable differences between the TRS 364 ‘expected’ values and the recommended values in the revised Handbook from the new database. Of the recommended values, three milk values are at least an order of magnitude higher than the TRS 364 values (Cr, Pu (cow) Pu (sheep)) and one milk value is lower (Ni (cow)). For meat, four values (Am, Cd, Sb (beef) I (pork)) are at least an order of magnitude higher than the TRS 364 values and eight values are at least an order of magnitude lower (Ru, Pu (beef), Ru, Sr, Zn (sheep), Ru, Sr (pork), Mn (poultry)). Many data gaps remain. 相似文献
737.
Mohammednoor Altarawneh Daniel Carrizo Artur Ziolkowski Eric M. Kennedy Bogdan Z. Dlugogorski John C. Mackie 《Chemosphere》2009,74(11):1435-1443
This article reports the computational and experimental results of the thermal decomposition of permethrin, a potential source of dibenzo-p-dioxins (PCDD) and polychlorinated dibenzofurans (PCDF). We have performed a quantum chemical analysis by applying density functional theory to obtain the decomposition pathways of permethrin and the formation mechanism of dibenzofuran. We have conducted the pyrolysis experiments in a tubular reactor and identified the pyrolysis products to demonstrate the agreement between the experimental measurements and quantum chemical calculations. The initiation of the decomposition of permethrin involves principally the aromatisation of permethrin into 3-phenoxyphenylacetic acid, 2-methylphenyl ester (J) and concomitant loss of 2HCl. This rearrangement is followed by the rupture of the O–CH2 linkage in J, with a rate constant derived from the quantum chemical results of 1 × 1015 exp(−68 kcal/mol/RT) s−1 for temperatures between 700 and 1300 K. This is confirmed by finding that the rate constant for unimolecular rearrangement of permethrin into J is 1.2 × 1012 exp(−53 kcal/mol/RT) s−1 over the same range of temperatures and exceeds the direct fission rate constant at all temperatures up to 850 ± 120 °C as well as by the experimental detection of J prior to the detection of the initial products incorporating diphenyl ether, 1-methyl-3-phenoxybenzene, 3-phenoxybenzaldehyde and 1-chloromethyl-3-phenoxybenzene. As the temperature increases, we observe a rise in secondary products formed directly or indirectly (via phenol/phenoxy) including aromatics (naphthalene), biphenyls (biphenyl, 4-methyl-1,1′-biphenyl) and dibenzofuran (DF). In particular, we discover by means of quantum chemistry a direct route from 2-phenoxyphenoxy to naphthalene. We detect no polychlorinated dibenzo-p-dioxins and dibenzofurans. Unlike the case of oxidative pyrolysis [Tame, N.W., Dlugogorski, B.Z., Kennedy, E.M., 2007b. Formation of dioxins in fires of arsenic-free treated wood: Role of organic preservatives. Environ. Sci. Technol. 41, 6425–6432] where significant yields of both PCDD and PCDF were obtained, under non-oxidative conditions the thermal decomposition of permethrin does not form appreciable amounts of PCDD or PCDF and the presence of oxygen (and/or a sizable radical pool) appears necessary for the formation of dibenzo-p-dioxin itself or PCDD/F from phenol/phenoxy. 相似文献
738.
The herbicide paraquat induces alterations in the elemental and biochemical composition of non-target microalgal species 总被引:1,自引:0,他引:1
Huge quantities of pesticides are dispersed in the environment, affecting non-target organisms. Since paraquat affects the photosynthetic process, the biochemical composition of affected species should be altered. The effect of paraquat on Chlamydomonas moewusii, a freshwater non-target species, was studied. After 48 h of herbicide exposure, growth rate, dry weight, and chlorophyll a and protein content were affected by paraquat concentrations above 0.05 μM. C/N ratio was also affected due to a decrease in nitrogen content in the dry biomass, while the carbon content remained constant for all paraquat concentrations assayed. Enzymes involved in nitrogen assimilation were affected by paraquat, being nitrate reductase activity more sensitive to paraquat than nitrite reductase. Based on the results obtained in the present study, paraquat exerts adverse effects upon a common freshwater green microalga, thus the application of this herbicide for weed control must be carried out very carefully, so that any disturbance affecting algae will have severe repercussions on higher trophic levels and on the elemental biogeochemical cycles. 相似文献
739.
Influence of titanium dioxide nanoparticles on speciation and bioavailability of arsenite 总被引:2,自引:0,他引:2
Sun H Zhang X Zhang Z Chen Y Crittenden JC 《Environmental pollution (Barking, Essex : 1987)》2009,157(4):1165-1170
In this study, the influence of the co-existence of TiO2 nanoparticles on the speciation of arsenite [As(III)] was studied by observing its adsorption and valence changing. Moreover, the influence of TiO2 nanoparticles on the bioavailability of As(III) was examined by bioaccumulation test using carp (Cyprinus carpio). The results showed that TiO2 nanoparticles have a significant adsorption capacity for As (III). Equilibrium was established within 30 min, with about 30% of the initial As (III) being adsorbed onto TiO2 nanoparticles. Most of aqueous As (III) was oxidized to As(V) in the presence of TiO2 nanoparticles under sunlight. The carp accumulated considerably more As in the presence of TiO2 nanoparticles than in the absence of TiO2 nanoparticles, and after 25-day exposure, As concentration in carp increased by 44%. Accumulation of As in viscera, gills and muscle of the carp was significantly enhanced by the presence of TiO2 nanoparticles. 相似文献
740.
Sorption of alkylphenols on Ebro River sediments: comparing isotherms with field observations in river water and sediments 总被引:1,自引:0,他引:1
Navarro A Endo S Gocht T Barth JA Lacorte S Barceló D Grathwohl P 《Environmental pollution (Barking, Essex : 1987)》2009,157(2):698-703
This study reports sorption isotherms of the endocrine disruptors nonylphenol (NP) and octylphenol (OP) in three sediment samples from the Ebro River basin (NE Spain), with organic carbon fractions (fOC) ranging from 0.0035 to 0.082 gOC g−1. All isotherms were fitted to the Freundlich model with slightly nonlinear exponents ranging from 0.80 to 0.94. The solubility of the compounds as well as the organic carbon (OC) content had the strongest influences on the sorption behavior of these compounds. Comparison of the laboratory-spiked samples with the native contamination of NP of 45 water and concurrent sediment samples resulted in reasonable matches between both data sets, even though the lowest concentrations in the field were not completely reached in laboratory tests. This good agreement indicates that sorption laboratory data can be extrapolated to environmental levels and therefore the distribution of nonylphenol between sediments and water can be predicted with a precision of one order of magnitude. Furthermore, laboratory experiments with simultaneous loading of NP and OP revealed negligible competition for sorption sites at low concentrations. 相似文献