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Density functional theory (DFT) has been used to investigate the reaction pathways with steam reforming of glycerol under cold plasma conditions. Total energies, energy barriers, and reaction enthalpies at 298.15 K have been calculated at the GGA/PW91/DNP level. The calculation shows that, with the presence of steam, the energy barrier of glycerol conversion is reduced and the conversion from glycerol to H2 and CO is promoted under cold plasma conditions. The formation of syngas was through a multi-step pathway via the conversion of OHCH2CHOH, CH2OH, CH2O, HCO,·and CH3, while the recombination of H generated extra H2. The synthesis of hydrocarbons are from the recombination of·CH3,·CH2, and·CH, which could be primarily generated through glycerol dissociation. The structure of glycerol anion was also studied in this work, and it was less stable than the neutral molecule. The route for the formation of OHCH2CHOH·and CH2OH·from glycerol anion is thermodynamically favorable. 相似文献
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Jun-Ji Cao Bai-Qing Xu Jian-Qiao He Xian-Qin Liu Yong-Ming Han Ge-hui Wang Chong-shu Zhu 《Atmospheric environment (Oxford, England : 1994)》2009,43(29):4444-4452
Carbonaceous aerosol concentrations were determined for total suspended particle samples collected from Muztagh Ata Mountain in western China from December 2003 to February 2006. Elemental carbon (EC) varied from 0.004 to 0.174 μg m?3 (average = 0.055 μg m?3) while organic carbon (OC) ranged from 0.12 to 2.17 μg m?3 and carbonate carbon (CC) from below detection to 3.57 μg m?3. Overall, EC was the least abundant fraction of carbonaceous species, and the EC concentrations approached those in some remote polar areas, possibly representing a regional background. Low EC and OC concentrations occurred in winter and spring while high CC in spring and summer was presumably due to dust from the Taklimakan desert, China. OC/EC ratios averaged 10.0, and strong correlations between OC and EC in spring–winter suggest their cycles are coupled, but lower correlations in summer–autumn suggest influences from biogenic OC emissions and secondary OC formation. Trajectory analyses indicate that air transported from outside of China brings ~0.05 μg m?3 EC, ~0.42 μg m?3 OC, and ~0.10 μg m?3 CC to the site, with higher levels coming from inside China. The observed EC was within the range of loadings estimated from a glacial ice core, and implications of EC-induced warming for regional climate and glacial ice dynamics are discussed. 相似文献
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脉冲电晕反应器结构对乙硫醇消除效果的影响 总被引:2,自引:1,他引:1
研究了脉冲电晕等离子体反应器结构的变化对乙硫醇消除效果的影响规律。结果表明,在反应器内设置折流板,可以增加气流的湍动程度,有利于活性粒子与污染物的充分接触,从而提高消除率。高压电极间距对电晕区范围及消毒效果有较大影响,间距较小将导致各电极产生的电场相互干扰明显,消除率减小;而电极间距过大,虽然电极间电场分布相互干扰小,但是反应器内可排布的电极数减少,总电晕区减少,消除率也减小。根据实验结果,电极间距设置为50 mm比较合理。另外,在相同的电场强度和脉冲频率下,毛刺形高压电极比线电极结构能耗低,能量利用率高。 相似文献
26.
Based on the China high resolution emission gridded data (1 km spatial resolution), this article is aimed to create a Chinese city carbon dioxide (CO2) emission data set using consolidated data sources as well as normalized and standardized data processing methods. Standard methods were used to calculate city CO2 emissions, including scope 1 and scope 2. Cities with higher CO2 emissions are mostly in north, northeast, and eastern coastal areas. Cities with lower CO2 emissions are in the western region. Cites with higher CO2 emissions are clustered in the Jing-Jin-Ji Region (such as Beijing, Tianjin, and Tangshan), and the Yangtze River Delta region (such as Shanghai and Suzhou). The city per capita CO2 emission is larger in the north than the south. There are obvious aggregations of cities with high per capita CO2 emission in the north. Four cities among the top 10 per capita emissions (Erdos, Wuhai, Shizuishan, and Yinchuan) cluster in the main coal production areas of northern China. This indicates the significant impact of coal resources endowment on city industry and CO2 emissions. The majority (77%) of cities have annual CO2 emissions below 50 million tons. The mean annual emission, among all cities, is 37 million tons. Emissions from service-based cities, which include the smallest number of cities, are the highest. Industrial cities are the largest category and the emission distribution from these cities is close to the normal distribution. Emissions and degree of dispersion, in the other cities (excluding industrial cities and service-based cities), are in the lowest level. Per capita CO2 emissions in these cities are generally below 20 t/person (89%) with a mean value of 11 t/person. The distribution interval of per capita CO2 emission within industrial cities is the largest among the three city categories. This indicates greater differences among per capita CO2 emissions of industrial cities. The distribution interval of per capita CO2 emission of other cities is the lowest, indicating smaller differences of per capita CO2 emissions among this city category. Three policy suggestions are proposed: first, city CO2 emission inventory data in China should be increased, especially for prefecture level cities. Second, city responsibility for emission reduction, and partitioning the national goal should be established, using a bottom-up approach based on specific CO2 emission levels and potential for emission reductions in each city. Third, comparative and benchmarking research on city CO2 emissions should be conducted, and a Top Runner system of city CO2 emission reduction should be established. 相似文献
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对杭州市环保系统的人才总量、学历结构、专业结构、职称结构和年龄结构等方面作了较详细的分析;针对杭州市环保系统存在的人才总量不足、结构分布不合理和高层次人才匮乏等问题,提出了引进高层次人才、加强教育培训、壮大基层队伍等对策。 相似文献
29.
Tao Tang Kun QianTianyu Shi Fang WangPingliang Li Jianqiang LiYongsong Cao 《Chemosphere》2012,89(11):1419-1425
Quinestrol is synthetic estrogen used in contraceptive and hormone replacement therapy and occasionally for treating breast cancer and prostate cancer. It can make its way into the environment through sewage discharge and waste disposal produced by human excretions. In this study, the photodegradation kinetics of quinestrol in various conditions was investigated by UV and solar irradiation. The affecting factors were studied including concentration of hydrogen peroxide, different water types, and the initial concentrations of quinestrol. Concurrently, the transformation products and presumed pathways of quinestrol in distilled water by UV irradiation were identified and proposed. The results showed that the degradation of quinestrol in both irradiation conditions followed the pseudo-first-order kinetics. More rapid degradation was observed by UV irradiation (k = 0.018 min−1) than solar irradiation (k = 0.004 h−1), and the photodegradation rate of quinestrol depended on the concentration of hydrogen peroxide, the initial concentration of quinestrol and water types. The transformation products of quinestrol in distilled water were identified by gas chromatography/mass spectrometry. When exposed to UV irradiation, quinestrol in aqueous solution was rapidly degraded, giving at least ten photodegradation products. The chemical structures of ten degradation products were identified on the basis of mass spectrum interpretation and literature data. 相似文献
30.
Cao ZJ Lu D Luo LS Deng YX Bian YG Zhang XQ Zhou MH 《Environmental science and pollution research international》2011,19(7):2690-2696