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31.
In 1998, the Agrio and Guadiamar rivers underwent an enormous environmental disaster caused by the rupture of the Aznalcóllar
tailings dam and the release of 6 hm3 of pyrite sludge and acidic water. Both rivers run over recent alluvial materials which form a small-sized aquifer which
is however important because underground water feeds the flow of the rivers. This work analyzes the state of groundwater 10 years
after the spill. Before the dam failure, this aquifer was already contaminated in the zone nearest to the mine, to which the
impact of the spill was added. Contamination levels in the alluvial aquifer of the Agrio River have decreased remarkably.
However, they are still important, with acidic pH values and high concentrations of toxic elements (maximum values of 16 mg/L
of Zn and 15 mg/L of Al). There are also important levels of contamination in the Guadiamar alluvial area closest to the mine,
as well as in specific zones located further south. The concentration of toxic elements is mainly controlled by pH. The evolution
of contaminant levels show a sharp decrease after the first years following the spill, followed by a subsequent stabilization.
It is necessary to take measures for the recovery of the aquifer because, otherwise, groundwater will continue contributing
contaminants into the Agrio and Guadiamar rivers. 相似文献
32.
José Carlos de Moura Xavier Irany de Andrade Azevedo Wilson Cabral de Sousa Junior Augusto Nishikawa 《Environmental monitoring and assessment》2013,185(2):1463-1471
Atmospheric pollutant monitoring constitutes a primordial activity in public policies concerning air quality. In São Paulo State, Brazil, the São Paulo State Environment Company (CETESB) maintains an automatic network which continuously monitors CO, SO2, NO x , O3, and particulate matter concentrations in the air. The monitoring process accuracy is a fundamental condition for the actions to be taken by CETESB. As one of the support systems, a preventive maintenance program for the different analyzers used is part of the data quality strategy. Knowledge of the behavior of analyzer failure times could help optimize the program. To achieve this goal, the failure times of an ozone analyzer—considered a repairable system—were modeled by means of the nonhomogeneous Poisson process. The rate of occurrence of failures (ROCOF) was estimated for the intervals 0–70,800 h and 0–88,320 h, in which six and seven failures were observed, respectively. The results showed that the ROCOF estimate is influenced by the choice of the observation period, t 0?=?70,800 h and t 7?=?88,320 h in the cases analyzed. Identification of preventive maintenance actions, mainly when parts replacement occurs in the last interval of observation, is highlighted, justifying the alteration in the behavior of the inter-arrival times. The performance of a follow-up on each analyzer is recommended in order to record the impact of the performed preventive maintenance program on the enhancement of its useful life. 相似文献
33.
Thais Cristina de Oliveira Souza Rafael Coll Delgado Iris Cristiane Magistrali Gilsonley Lopes dos Santos Daniel Costa de Carvalho Paulo Eduardo Teodoro Carlos Antônio da Silva Júnior Rodrigo Hotzz Caúla 《Environmental monitoring and assessment》2018,190(11):688
This study aimed to analyze the spectral trend of vegetation with rainfall in El Niño-Southern Oscillation events (ENSO) in the Atlantic Forest, Brazil. Monthly rainfall data were collected from 85 conventional meteorological stations (EMC), data from the Enhanced Vegetation Index 2 (EVI2) and ENSO events (El Niño, La Niña, and Neutral) in the period from 2001 to 2013. Afterwards, state cluster analysis was performed using the results of non-parametric tests. The Mann-Kendall (MK) non-parametric test did not identify a trend pattern in rainfall distribution in the Atlantic Forest. The results for EVI2 by state and region showed that the trend is decreasing in the Northeast Region, except for the states of Alagoas and Pernambuco. Southeast region showed an increasing trend of EVI2 (except for Rio de Janeiro and São Paulo), while the South region showed a decreasing trend. In the Midwest, the trend was significantly decreasing. In the prognosis elaborated for the future, the regions with significant declines of the vegetation were the Northeast and Midwest. This study shows that the Atlantic Forest in some regions of Brazil has been suffering from the growing urbanization process and there is a trend of soil degradation. 相似文献
34.
Vanessa Santana Vieira Santos Karen Magalhães Arantes Ester Luiza Gonçalves Carlos Fernando Campos Edimar Olegário de Campos Júnior Antônio Marcos Machado de Oliveira Boscolli Barbosa Pereira 《Environmental monitoring and assessment》2018,190(5):303
Phyllanthus niruri is a plant that is used to prevent calcium oxalate crystallisation and to block the stone formation in urolithiasis. Contaminants in the environment can be readily taken up by medicinal plants due to their ability to absorb chemicals into their tissues. If contaminated plants are ingested, they have the potential to negatively affect human and environmental health. The aim of this study was to assess contamination in the soil and the medicinal plant P. niruri by cadmium (Cd) in ceramic industrial areas of Monte Carmelo, Brazil. Soil samples and plant samples (divided in root, shoot and leaves) were collected from a contaminated monitoring site and from a rural area (which was used as a reference site for comparative purposes). The Cd concentrations of the samples were analysed with an atomic absorption spectrometer. P. niruri was found to be sensitive to soil contamination by Cd that was attributed to ceramic industrial emissions. The results revealed that Cd bioaccumulation in the roots and shoots of P. niruri was associated with a significant increase (p?<?0.05) in the concentration of active lignan compounds (phyllanthin and hypophyllanthin) in the leaves. The identification of high concentrations of Cd and active lignan compounds suggests a risk of contamination of the site and the risk of a high dose of Cd to people exposed at the site. 相似文献
35.
Lorena A. Latini María M. Indaco María B. Aguiar Liliana B. Monza María E. Parolo Carlos F. Melideo 《Journal of environmental science and health. Part. B》2018,53(7):469-475
Chlorpyrifos (O, O-diethyl O-3,5,6-trichloropyridin-2-yl phosphorothioate) and carbaryl (1-naphthyl methylcarbamate) are often applied concurrently as insecticides in food production. The aim of this study was to research their migration behavior in a real environment. We researched the leaching of both pesticides by setting up field lysimeters on a farm with the typical soil used in fruit production today. In order to analyze the variables involved in this process, we performed complementary adsorption studies, we performed complementary adsorption studies using batches and undisturbed soil laboratory columns for both compounds. The results for pesticide transport through the lysimeters showed that less than 1% of chlorpyrifos was recovered in the leachates, while almost 17% was recovered for carbaryl. Having completed the experiment in undisturbed laboratory columns, soil analysis showed that chlorpyrifos mainly remained in the first 5 cm, while carbaryl moved down to the lower sections. These results can be explained in view of the sorption coefficient values (KD) obtained in horizons A and B for chlorpyrifos (393 and 184 L kg?1) and carbaryl (3.1 and 4.2 L kg?1), respectively. By integrating the results obtained in the different approaches, we were able to characterize the percolation modes of these pesticides in the soil matrix, thus contributing to the sustainable use of resources. 相似文献
36.
D. S. Cardillo Carlos Busso Mariela Ambrosino Leticia Ithurrart Yanina Torres Rosana Palomo 《Russian Journal of Ecology》2018,49(5):413-421
The objectives of this study were to determine the percentage of root colonization by arbuscular mycorrhizal (AM) fungi at various levels of plant species richness and developmental morphology stages in various perennial grass, and herbaceous and woody dicots species using experimental plots during 2013 and 2014. An auger was used to obtain six replicate root + soil samples at each sampling time on each of the study parameters. Roots were washed free of soil, and percentage AM was determined. The shrub Larrea divaricata was the species which showed the lowest percentage of colonization by AM at the vegetative developmental morphology stage at the monocultures and six-species-mixtures on the experimental plots. Dicots, but not grass, species showed a greater percentage colonization by AM fungi at the greatest (i.e., six-species-mixtures) than lowest (i.e., monocultures) species richness. Although at different degrees of species richness and developmental morphology stages, the perennial grasses Nassella longiglumis and N. tenuis, the herbaceous dicot Atriplex semibaccata, and the shrubs L. divaricata and Schinus fasciculatus showed a greater (p < 0.050) percentage colonization by AM fungi during the second than the first study year. Even though it was species- and sampling time-dependent, percentage colonization by AM fungi increased as species richness also increased most of the times. Our results demonstrated that the plant species differences in percentage colonization by AM fungi in the experimental plots were species richness-, developmental morphology stage-, and sampling-time dependents. 相似文献
37.
Jasim?ImranEmail authorView authors OrcID profile Sadia?M.?Khan Carlos?Pirmez Gary?Parker 《Environmental Fluid Mechanics》2017,17(1):159-186
The scaling problem associated with the modeling of turbidity currents has been recognized but is yet to be explored systematically. This paper presents an analysis of the dimensionless governing equations of turbidity currents to investigate the scale effect. Three types of flow conditions are considered: (i) conservative density current; (ii) purely depositional turbidity current; and (iii) mixed erosional/depositional turbidity current. Two controlling dimensionless numbers, the Froude number and the Reynolds number, appear in the non-dimensional governing equations. When densimetric Froude similarity is satisfied, the analysis shows that the results would be scale-invariant for conservative density current under the rough turbulent condition. In the case of purely depositional flows, truly scale-invariant results cannot be obtained, as the Reynolds-mediated scale effects appear in the bottom boundary conditions of the flow velocity and sediment fall velocity. However, the scale effect would be relatively modest. The Reynolds effect becomes more significant for erosional or mixed erosional/depositional turbidity currents as Reynolds-mediated scale effects also appear in the sediment entrainment relation. Numerical simulations have been conducted at three different scales by considering densimetric Froude scaling alone as well as combined densimetric Froude and Reynolds similarity. Simulation results confirm that although the scaling of densimetric Froude number alone can produce scale-invariable results for conservative density currents, variations occur in the case of turbidity currents. The results become scale invariant when densimetric Froude and Reynolds similarities are satisfied simultaneously. 相似文献
38.
Design of water quality monitoring networks with two information scenarios in tropical Andean basins
Juan Carlos Bastidas Jorge Julián Vélez Jeannette Zambrano Adela Londoño 《Environmental science and pollution research international》2017,24(25):20134-20148
Design and redesign of water quality monitoring networks were evaluated for two similarly sized watersheds in the tropical Andes via optimization techniques using geographic information system technology (GIS) and a matter-element analysis of 5-day biological oxygen demand (BOD5) and total suspended solids (TSS). This resulted in a flexible, objectively based design for a 1128-km2 watershed without prior water quality data (La Miel River), and a network redesign of a 1052-km2 watershed with historical water quality monitoring (Chinchiná River). Monitoring design for the undocumented basin incorporated mathematical expressions for physical, anthropological, and historical factors—and was based on clear objectives for diagnosis and intervention of water pollution. Network redesign identified network redundancy, which resulted in a 64% reduction in the number of water quality monitoring stations along the channel, and a 78% reduction of stations throughout the basin. Most tropical drainage basins throughout the world have little to no prior water quality data. But even in well-studied drainage basins like the Chinchiná River, which is among the most thoroughly studied basins in Colombia, redesign of historical and existing monitoring networks will become a standard tool to advance the restoration of polluted surface waters, not only in Colombia, but also throughout the world. 相似文献
39.
Mayra Cecilia Rodriguez-Hernandez Carlos E. Flores-Chaparro Jose Rene Rangel-Mendez 《Environmental science and pollution research international》2017,24(26):20922-20933
The effect of dissolved organic matter (DOM) and oil on the removal of the water-soluble compounds benzene, toluene, ethylbenzene, and xylene isomers (BTEX) by two low-cost biosorbents Macrocystis pyrifera and Ulva expansa) was evaluated. DOM decreased the adsorption capacity of toluene, ethylbenzene, and xylenes of the two biosorbents. In contrast, the removal of benzene increased under the same conditions in single and multi-solute systems: this effect was dominant in U. expansa biomass treatments. In the presence of DOM and oil in solutions, the removal of BTEX notoriously increased, being oil that contributed the most. Solubility and hydrophobicity of pollutants played a key role in the adsorption process. The attractions between BTEX molecules and biosorbents were governed by π–π and hydrophobic interactions. Affinities of biosorbents for BTEX were mainly in the order of X > E > T > B. The Langmuir and Sips equations adjusted the adsorption isotherms for BTEX biosorption in deionized and natural water samples, but in the case of oily systems, the Freundlich equation seemed to have a better fit. The biosorption processes followed a pseudo-second-order rate in all the cases. 相似文献
40.
Laura Blanco Daphne Hermosilla Carlos Negro Nathalie Swinnen David Prieto Ángeles Blanco 《Environmental science and pollution research international》2017,24(20):16631-16638
To reduce fresh water consumption in a polyvinyl chloride (PVC) plant, the effluent from a biological treatment must be demineralized to be re-used in the resin polymerization process. Demineralization is a critical process, since the quality and the stability of the PVC resins are highly influenced by the water quality used in the process. The main target values for water parameters are the following: conductivity <10 μScm?1, TOC < 10 mg L?1, and Al < 0.1 mg L?1. To achieve this quality, several reverse osmosis membranes from different materials and suppliers were tested and compared in the demineralization treatment. Polyamide membranes showed higher salt rejection compared to cellulose acetate membranes yielding both types similar flux and permeability. Two-pass reverse osmosis treatment was necessary to reach conductivities lower than 10 μS cm?1. On the other hand, a good quality effluent for reuse was obtained by combining RO and ionic exchange resins. Results showed that good quality PVC resins in terms of color, granulometry, porosity, and bulk density were obtained when demineralized water from two-pass reverse osmosis was used as fresh water, proving the feasibility of the effluent reuse in the PVC industry. 相似文献