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41.
42.
Chelator-mediated Fenton reactions (CMFRs) were used to decolorize a biodegradable-resistant polymeric dye (Poly R-478). Screening of different iron chelators was performed on Fe(3+)-reduction activity. All chelators showed Fe(3+)-reduction activity over a wide range of pH (2-7) and each mol of catecholate chelators (3,4-dihydroxiphenilacetic acid--DOPAC and 2,3-dihydroxibenzoic acid--DHBA) reduced about 5-6 moles of Fe(3+) whereas hydroxamate chelators (acetohydroxamic acid-AHA and desferrioxamine B-DFB) reduced Fe(3+) stoichiometrically. The most effective decolorization of Poly R-478 was achieved by CMFR using catecholate chelators. In addition, a 2(4) factorial design was performed with the aim of evaluating the effects of the variables considered in this study (pH, [DOPAC], [Fe(3+)] and [H(2)O(2)]) and optimizing the dye decolorization, using response surface methodology. Statistical analysis of results showed that, in the range studied, except for Fe(3+), all variables have a significant effect on dye decolorization. A second-order model is proposed to represent the Poly R-478 decolorization. At optimum conditions, complete decolorization of the dye (degradation of the chromophoric group) and also complete chemical degradation of the dye was observed. 相似文献
43.
Use of ecosystem information to improve soil organic carbon mapping of a Mediterranean island 总被引:1,自引:0,他引:1
Detailed maps of soil C are needed to guide sustainable soil uses and management decisions. The quality of soil C maps of Italian Mediterranean areas may be improved and the sampling density reduced using secondary data related to the nature of the ecosystem. The current study was conducted to determine: (i) the improvements obtainable in mapping soil C over a Mediterranean island by using ecosystem features and (ii) the effect of different sampling densities on the map accuracy. This work relied on field sampling (n=164) of soil properties measured over the island of Pianosa (Central Italy). Statistical analysis assessing the relationship between soil properties and ecosystem features revealed that the conceptual model of ecosystems defined on the basis of environmental features such as vegetation cover, land use, and soil type was mainly related to the variation of soil organic carbon (OC) content and to the type of Mediterranean environment. The distribution of ecosystems was used to improve the accuracy of soil OC maps obtainable by a simple interpolation approach (ordinary kriging). Substantial improvement was obtained by: (i) stratification into ecosystem types and (ii) applying locally calibrated regressions to satellite imagery that introduced both inter-ecosystem and intra-ecosystem information linked to vegetation features. This study showed that interpolation methods using information on ecosystem distribution can produce accurate maps of soil OC in Mediterranean environments, mostly because of the linkage between soil OC and vegetation types, which are spatially fragmented and heterogeneous. 相似文献
44.
de Araújo Gusmão Carolina Palharim Priscila Hasse Ramos Bruno Teixeira Antonio Carlos Silva Costa 《Environmental science and pollution research international》2022,29(28):42215-42230
Environmental Science and Pollution Research - Catalyst samples based on SiO2-supported TiO2 were prepared with the incorporation of Ag (metal), S (nonmetal), and ZnO@S (semiconductor and... 相似文献
45.
The European Water framework directive (WFD) is probably the most important environmental management directive that has been enacted over the last decade in the European Union. The directive aims at achieving an overall good ecological status in all European water bodies. In this article, we discuss the implementation steps of the WFD and their implications for environmental engineering practice while focusing on rivers as the main receiving waters. Arising challenges for engineers and scientists are seen in the quantitative assessment of water quality, where standardized systems are needed to estimate the biological status. This is equally of concern in engineering planning, where the prediction of ecological impacts is required. Studies dealing with both classification and prediction of the ecological water quality are reviewed. Further, the combined emission–water quality approach is discussed. Common understanding of this combined approach is to apply the most stringent of either water quality or emission standard to a certain case. In contrast, for example, the Austrian water act enables the application of only the water quality based approach - at least on a temporary basis. 相似文献
46.
210Pb geochronology and trace metal fluxes (Cd, Cu and Pb) in the Gulf of Tehuantepec, South Pacific of Mexico 总被引:1,自引:0,他引:1
Ruiz-Fernández AC Páez-Osuna F Machain-Castillo ML Arellano-Torres E 《Journal of environmental radioactivity》2004,76(1-2):161-175
Distributions of Al, Cd, Cu, Fe, Li, Mn and Pb were analyzed in a sediment core collected in the Gulf of Tehuantepec, an important fisheries region located in the South Pacific of Mexico, where data on metal accumulation and accretion rates were previously almost nonexistent. Depth profiles of metal concentrations were converted to time-based profiles by using a 210Pb-derived vertical accretion rate, estimated to be 0.05 cm year(-1) on the average. Sediments were dated up to 8 cm depth, corresponding to a layer of ca. 140 years old. The historical changes of metal accumulation along the sediment core have shown a moderate enrichment of Cd, Cu and Pb concentrations at present, of about threefold the corresponding background concentrations. Chronological trace metal records showed that metal fluxes have increased over the last 20 years, reaching the maximum values at present of 2.5, 22.5 and 45.8 (microg cm(-2) year(-1)) for Cd, Pb and Cu, respectively. These increments in metal fluxes are likely influenced by the development of anthropogenic land-based activities since over this period of time oil production activities in the region have had a significant development. 相似文献
47.
Renata B. S. Oliveira Riccardo Mugnai Carolina M. Castro Darcilio F. Baptista 《Environmental monitoring and assessment》2011,175(1-4):75-85
The purpose of this study was to establish a subsampling procedure for benthic macroinvertebrates to aid in the development of a multimetric index to assess the biological condition of streams. Data from six streams that are considered minimally impaired were used. Subsampling was done using a device divided into 24 quadrats. The sediment from each quadrat was sorted, and all organisms were removed and identified. Richness metrics were the most affected by subsample size. Relative-abundance metrics were the most stable, proving that the sample was well distributed throughout the tray and abundance proportions were maintained. The results showed that the macroinvertebrate assemblage present in the six quadrats was similar to that present in the full sample. These analyses indicated that six quadrats, randomly designated, with a minimum of 200 collected specimens could be used in place of the full sample. In routine water management, managing time and costs are a major challenge; therefore, this type of simplification is absolutely necessary to ensure that a biomonitoring tool is useful for practical applications. 相似文献
48.
Carolina Gonzalez-Merchan Sylvie Barraud Jean-Philippe Bedell 《Environmental science and pollution research international》2014,21(8):5419-5426
The paper presents the role of spontaneous vegetation on the hydraulic performance of an infiltration basin. The objective of the research was more particularly to study this role of different types of spontaneous vegetation found in situ in an infiltration basin near Lyon. The saturated hydraulic conductivity of three areas covered by Phalaris arundinacea, Polygonum mite, Rumex crispus and similar non-vegetated zones was compared. Eight field campaigns were carried out from July 2010 to May 2011 in order to compare the performance of each type of vegetation and its evolution over time. The results suggest a positive impact of vegetation on hydraulic performance in particular in summer during the growth of the plants. The hydraulic conductivity in this period was twice to four times higher than in bare areas or in vegetated zones during the plant rest periods. Some species were also found more appropriate to limit clogging (Phalaris arundinacea) likely due to its specific structure and growth process. 相似文献
49.
Carolina Gonzalez Merchan Yves Perrodin Sylvie Barraud Christel Sébastian Céline Becouze-Lareure Christine Bazin Gislain Lipeme Kouyi 《Environmental science and pollution research international》2014,21(8):5357-5366
Detention basins are valuable facilities for urban storm water management, from both the standpoint of flood control and the trapping of pollutants. Studies performed on storm water have shown that suspended solids often constitute the main vector of pollutants (heavy metals, polycyclic aromatic hydrocarbon (PAH), etc.). In order to characterise the ecotoxicity of urban sediments from storm water detention basins, the sediments accumulated over a 6-year period were sampled at five different points through the surface of a large detention basin localised in the east of Lyon, France. A specific ecotoxicological test battery was implemented on the solid phase (raw sediment) and the liquid phase (interstitial water of sediments). The results of the study validated the method formulated for the ecotoxicological characterization of urban sediments. They show that the ecotoxicological effect of the sediments over the basin is heterogeneous and greater in areas often flooded. They also show the relationship between, on one hand, the physical and chemical characteristics of the sediments and, on the other hand, their ecotoxicity. Lastly, they contribute to a better understanding of the dynamics of the pollution close to the bottom of detention basins, which can be useful for improving their design. The results of this research raise particularly the issue of using oil separators on the surface of detention basins. 相似文献
50.
Copper (Cu) and diazinon are two widely distributed pollutants; they coexist in agro-ecosystems and cause toxicity to wild biota. This study proposes to analyse the joint toxicity of binary mixtures of Cu and diazinon on the early development of the South American toad, Rhinella arenarum by means of a standardised test. Cu was always more toxic than diazinon. Cu was more embryotoxic while the pesticide was more toxic during the larval exposure than during the embryonic period. The different Cu/diazinon mixtures proportions assayed were significantly less toxic than expected by additive effects. Thus, an antagonistic interaction pattern was observed. This pattern was independent of the assayed proportion, the exposure times and the exposure developmental periods. In the risk assessment analysis to establish water quality criteria, the joint toxicity should be considered at different ratios, exposure time and life period for a certain species, in order to preserve wild species. 相似文献