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261.
Soil contamination is notoriously difficult to treat because the contaminants are often tightly bound to the soil particles. Conventional remediation technologies are becoming less popular due to the high treatment costs. This paper gives a comprehensive overview and evaluation of an emerging promising alternative, surfactant foam technology. Different from other approaches, surfactant foam technology may be designed either to remove contaminants or/and simultaneously act as an augmentation for the existing technologies such as pump-and-treat systems and bioremediation processes to improve the contaminant removal efficiency and cost effectiveness. Encouraging results were achieved from laboratory and field demonstrations. However, as an innovative technology, there are many factors to be investigated with the future development. Special attention is paid to the selection of the most appropriate foaming surfactant and surfactant concentration, which are critical to the success of the implementation of the remediation process and have significant effects on the treatment costs. Moreover, development of predictive mathematical models in for future research is helpful to optimize the remediation process. 相似文献
262.
Thirty-two brownfield sites from the city of Wolverhampton were selected from those with a former industrial use, wasteland
or areas adjacent to industrial processes. Samples (<2 mm powdered soil fraction) were analysed, using inductively coupled
plasma–atomic emission spectrometry (ICP–AES) for 20 elements. Loss on ignition and pH were also determined. A five-step chemical
sequential extraction technique was carried out. Single leach extraction with 0.12 M hydrochloric acid of Pb, Cu and Zn in
soil was determined as a first approximation of the bioavailability in the human stomach. Some of the sites were found to
have high concentrations of the potentially toxic elements Pb, Zn, Cu and Ni. The partitioning of metals showed a high variability,
however a number of trends were determined. The majority of Zn was partitioned into the least chemically stable phases (steps
1, 2 and 3). The majority of Cu was associated with the organic phase (step 4) and the majority of Ni was fractionated into
the residue phase (step 5). The majority of Pb was associated with the residue fraction (step 5) followed by Fe–Mn oxide fraction
(step 3). The variability reflects the heterogeneous and complex nature of metal speciation in urban soils with varied historic
histories. There was a strong inverse linear relationship between the metals Ni, Zn and Pb in the readily exchangeable phase
(step 1) and soil pH, significant at P < 0.01 level. There was a significant increase (P < 0.05) in the partitioning of Cu, Ni and Zn into step 4 (the organic phase) in soils with a higher organic carbon content
(estimated by loss on ignition). Copper was highly partitioned into step 4 as it has a strong association with organics in
soil but this phase was not important for the partitioning of Ni or Zn. The fractionation of Ni, Cu and Zn increased significantly
in step 3 when the total metal concentration increases (P < 0.01). The Fe–Mn oxide fraction becomes more important in soils elevated in these metals, possibly due to the scavenging
of metals by oxides. Cu and Pb extracted by HCl was statistically similar to the sum of the metals in steps 1 to 4 (P < 0.01) and HCl available Zn was statistically similar to the sum of Zn in steps 1 to 3 (P < 0.01). Step 4 (the organic phase) was not an important phase for Zn, so it was concluded that any Cu, Zn and Pb present
in soil in a nonresidue phase would be potentially available for uptake into the human system once soil has been ingested. 相似文献
263.
Seasonal source identification and source-specific health risk assessment of pollutants in road dust
Wang Jingshu Huang Jinhui Jeanne Mulligan Catherine 《Environmental science and pollution research international》2022,29(7):10063-10076
Environmental Science and Pollution Research - Humans who are exposed to metals in road dust may have potential health risks through touching, ingesting, and inhaling the suspended road dust. There... 相似文献
264.
Roman M. Wittig Catherine Crockford Robert M. Seyfarth Dorothy L. Cheney 《Behavioral ecology and sociobiology》2007,61(6):899-909
Theory predicts that females in species with matrilineal dominance hierarchies should use nepotistic support systems to maintain
their family’s rank. Female Old World monkeys, however, form alliances against other females at surprisingly low rates. Nonetheless,
in many species, females utter threat vocalizations when observing others’ disputes, suggesting that these vocalizations may
function as ‘vocal alliances’. We describe a playback experiment testing the efficacy of vocal alliances in free-ranging female
baboons. Subjects were played the same female’s threat-grunts under three separate conditions: after being threatened by the
signaller’s close relative to mimic kin support, after being threatened by a female maternally unrelated to the signaller
to mimic non-kin support, and after a friendly interaction with the signaller’s close relative as a control. Subjects responded
more strongly to the playback and avoided the signaller and her matrilineal relatives for a longer period of time in kin support
trials than in either non-kin support or no aggression trials. In contrast, there was no difference in subjects’ behaviour
between non-kin support and no aggression trials. These results corroborate observational data showing that vocal support
occurs at a higher rate than physical support in female baboons, and that kin are more likely to provide vocal support than
non-kin. We conclude that vocal support plays a similar role as physical support in the alliances of female baboons. 相似文献
265.
Bigorgne E Foucaud L Lapied E Labille J Botta C Sirguey C Falla J Rose J Joner EJ Rodius F Nahmani J 《Environmental pollution (Barking, Essex : 1987)》2011,159(10):2698-2705
The increasing production of nanomaterials will in turn increase the release of nanosized byproducts to the environment. The aim of this study was to evaluate the behaviour, uptake and ecotoxicity of TiO2 byproducts in the earthworm Eisenia fetida. Worms were exposed to suspensions containing 0.1, 1 and 10 mg/L of byproducts for 24 h. Size of TiO2 byproducts showed aggregation of particles up to 700 μm with laser diffraction. Only worms exposed at 10 mg/L showed bioaccumulation of titanium (ICP-AES), increasing expression of metallothionein and superoxide dismutase mRNA (Real-time PCR) and induction of apoptotic activity (Apostain and TUNEL). TiO2 byproducts did not induce cytotoxicity on cœlomocytes, but a significant decrease of phagocytosis was observed starting from 0.1 mg/L. In conclusion, bioaccumulation of byproducts and their production of reactive oxygen species could be responsible for the alteration of the antioxidant system in worms. 相似文献
266.
We assessed the relationship between the quality (i.e., job characteristics, role stressors, and interpersonal relationships) and quantity of part-time employment, and work-related attitudes and aspirations among 349 students. Neither the linear nor the quadratic components of employment quantity predicted any of the outcome variables. Motivation to do good work was predicted both by role stressors and by family achievement orientation. Career maturity was predicted by role stressors at work, and cynicism by role stressors and satisfaction with interpersonal relationships. In contrast, job involvement was significantly related to family achievement orientation but not to any perceived job factors. These findings question the assumption that only intensive work during high school exerts negative effects for teenagers, and support the importance of employment quality for teenagers as well as adults. © 1998 John Wiley & Sons, Ltd. 相似文献
267.
Jondreville C Bouveret C Lesueur-Jannoyer M Rychen G Feidt C 《Environmental science and pollution research international》2013,20(1):292-299
The former use of chlordecone (CLD) in the French West Indies has resulted in long-term pollution of soils and of food chains. CLD may be transferred into eggs of hens reared outdoors, through polluted soil ingestion. Tropical volcanic soils display variable capacities of pollutant retention: CLD is less available and more persistent in andosol than in nitisol. The impact of soil type on CLD bioavailability to hens was tested through a relative bioavailability study. The deposition of CLD in egg yolk and in abdominal fat was measured in 42 individually housed laying hens fed with diets containing graded levels of CLD from polluted andosol, nitisol, or spiked oil during 23 days. Within each ingested matrix, the concentration of CLD in yolk and in abdominal fat linearly increased with the amount of ingested CLD (P < 0.001). However, the response to andosol diets and to nitisol diets was not different from the response to oil diets (P > 0.1), indicating that CLD was equally bioavailable to laying hens, irrespective of the matrix. This suggests that the hen's gastrointestinal tract efficiently extracts CLD from the two tropical volcanic soils, regardless of their retention capacity. Thus, hens reared on polluted soils with CLD may lay contaminated eggs. 相似文献
268.
Christopher J. O'Bryan Stephen T. Garnett Julia E. Fa Ian Leiper Jose A. Rehbein Álvaro Fernández-Llamazares Micha V. Jackson Harry D. Jonas Eduardo S. Brondizio Neil D. Burgess Catherine J. Robinson Kerstin K. Zander Zsolt Molnár Oscar Venter James E. M. Watson 《Conservation biology》2021,35(3):1002-1008
Indigenous Peoples’ lands cover over one-quarter of Earth's surface, a significant proportion of which is still free from industrial-level human impacts. As a result, Indigenous Peoples and their lands are crucial for the long-term persistence of Earth's biodiversity and ecosystem services. Yet, information on species composition on these lands globally remains largely unknown. We conducted the first comprehensive analysis of terrestrial mammal composition across mapped Indigenous lands based on data on area of habitat (AOH) for 4460 mammal species assessed by the International Union for Conservation of Nature. We overlaid each species’ AOH on a current map of Indigenous lands and found that 2695 species (60% of assessed mammals) had ≥10% of their ranges on Indigenous Peoples’ lands and 1009 species (23%) had >50% of their ranges on these lands. For threatened species, 473 (47%) occurred on Indigenous lands with 26% having >50% of their habitat on these lands. We also found that 935 mammal species (131 categorized as threatened) had ≥ 10% of their range on Indigenous Peoples’ lands that had low human pressure. Our results show how important Indigenous Peoples’ lands are to the successful implementation of conservation and sustainable development agendas worldwide. 相似文献
269.
270.