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Environmental Science and Pollution Research - Upon screening for novel and potential biocompounds with larvicidal activities, we successfully isolated hamisonine (HMSN) a limonoid compound from...  相似文献   
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The rising global population is inducing a fast increase in the amount of municipal waste and, in turn, issues of rising cost and environmental pollution. Therefore, alternative treatments such as waste-to-energy should be developed in the context of the circular economy. Here, we review the conversion of municipal solid waste into energy using thermochemical methods such as gasification, combustion, pyrolysis and torrefaction. Energy yield depends on operating conditions and feedstock composition. For instance, torrefaction of municipal waste at 200 °C generates a heating value of 33.01 MJ/kg, while the co-pyrolysis of cereals and peanut waste yields a heating value of 31.44 MJ/kg at 540 °C. Gasification at 800 °C shows higher carbon conversion for plastics, of 94.48%, than for waste wood and grass pellets, of 70–75%. Integrating two or more thermochemical treatments is actually gaining high momentum due to higher energy yield. We also review reforming catalysts to enhance dihydrogen production, such as nickel on support materials such as CaTiO3, SrTiO3, BaTiO3, Al2O3, TiO3, MgO, ZrO2. Techno-economic analysis, sensitivity analysis and life cycle assessment are discussed.

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A significant concern of our fuel-dependent era is the unceasing exhaustion of petroleum fuel supplies. In parallel to this, environmental issues such as the greenhouse effect, change in global climate, and increasing global temperature must be addressed on a priority basis. Biobutanol, which has fuel characteristics comparable to gasoline, has attracted global attention as a viable green fuel alternative among the many biofuel alternatives. Renewable biomass could be used for the sustainable production of biobutanol by the acetone-butanol-ethanol (ABE) pathway. Non-extinguishable resources, such as algal and lignocellulosic biomass, and starch are some of the most commonly used feedstock for fermentative production of biobutanol, and each has its particular set of advantages. Clostridium, a gram-positive endospore-forming bacterium that can produce a range of compounds, along with n-butanol is traditionally known for its biobutanol production capabilities. Clostridium fermentation produces biobased n-butanol through ABE fermentation. However, low butanol titer, a lack of suitable feedstock, and product inhibition are the primary difficulties in biobutanol synthesis. Critical issues that are essential for sustainable production of biobutanol include (i) developing high butanol titer producing strains utilizing genetic and metabolic engineering approaches, (ii) renewable biomass that could be used for biobutanol production at a larger scale, and (iii) addressing the limits of traditional batch fermentation by integrated bioprocessing technologies with effective product recovery procedures that have increased the efficiency of biobutanol synthesis. Our paper reviews the current progress in all three aspects of butanol production and presents recent data on current practices in fermentative biobutanol production technology.

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Environmental Science and Pollution Research - Human utilization of natural resources acts as a main driver in altering the ecosystem service and functions. Apart from indirect influence, these...  相似文献   
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Studies on ultrasound-assisted processes are gaining importance due to its effectiveness and facilitating green method in processing. Degreasing of skin/hide prior to tanning process is an important unit operation. Presence of large amounts of natural fat at the interior of skin/hide matrix makes degreasing process a challenging one. Conventionally, organic solvent and/or detergent based degreasing process are employed leading to environmental problems. In the present paper, the use of power ultrasound in aqueous degreasing process has been studied and compared with different degreasing systems. Glutaraldehyde pre-tanning has also been employed for carrying out the degreasing process at ultrasonic bath temperature. The results indicate that there is a significant increase in the degreasing efficiency due to the application of ultrasound. About 2-fold increase in fat removal has been observed due to the use of ultrasound as compared to control under the given process conditions. Comparing the degreasing efficiencies of the solvent with aqueous based ultrasonic processes, about 80% of the solvent degreasing efficiency could be obtained for aqueous degreasing process. This novel ultrasonic process helps in making aqueous degreasing process a viable option, which is eco-friendly even dispensing with temperature control measures.  相似文献   
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Cell-free DNA (cfDNA) testing is increasingly being used to screen pregnant women for fetal aneuploidies. This technology may also identify fetal sex and can be used to screen for sex chromosome aneuploidies (SCAs). Physicians offering this screening will need to be prepared to offer comprehensive prenatal counseling about these disorders to an increasing number of patients. The purpose of this article is to consider the source of information to use for counseling, factors in parental decision-making, and the performance characteristics of cfDNA testing in screening for SCAs. Discordance between ultrasound examination and cfDNA results regarding fetal sex is also discussed. © 2015 John Wiley & Sons, Ltd.  相似文献   
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Arylsulfatase activity in marine sediments   总被引:1,自引:0,他引:1  
Arylsulfatase activity and arylsulfatase-producing bacteria were estimated in sediment samples collected from 3 different biotopes: marine, estuarine, and mangrove. No direct relationship could be established between activity and the number of bacteria at any station. In general, clayey sediments always harboured more arylsulfatase producers than sandy sediments, irrespective of salinity variations. Of the 3 biotopes investigated, the mangrove area exhibited maximum activity. The enzyme showed two pH optima, one at 6.2, the other at 9.0. The optimum substrate concentration was 12x10-4M. Higher substrate concentrations tended to inhibit arylsulfatase activity. The recovery of added phenolphthalein was maximum only at pH 6.2; KCN, Na2So4, and KH2Po4 inhibited enzyme activity by 65.5, 46.8 and 37.5%, respectively. More than one type of arylsulfatase may be present in marine sediments; further studies on the role of arylsulfatases are required, since arylsulfatases have been reported to bear on the formation and hardening of exoskeletons in marine forms.  相似文献   
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