The Metallic Composition of Aerosols at Three Monitoring Sites in Korea During Winter 2002

In the present study, the distribution patterns of various metals were analyzed and compared using PM samples collected concurrently from three monitoring sites located in Korea (Seoul, Busan, and Jeju island) in December 2002. As these sites can represent metal pollution with different degrees of anthropogenic activities, their concentration levels were distinguished in a systematic manner in the order of Jeju, Busan, and Seoul. By comparing the present data sets with those measured previously from other locations in Korea and around the world, we attempted to diagnose the general status of elemental pollution on the Korean peninsula. Through an application of different statistical approaches, the major processes controlling elemental levels were assessed for each of the three study sites. The results indicated the importance of both crustal and anthropogenic sources in all sites with their relative roles varying significantly from each other. The results of the metal analysis data, when examined in relation to back trajectory analysis, confirmed that their concentration changes are affected quite sensitively with air mass movement patterns. The overall results of this study consistently indicated the contribution of a strong anthropogenic source area (e.g., China) to the observed metal concentration levels in the study area, but the strengths of such signals vary considerably across the Korean peninsula.     

Co-pyrolysis of swine manure with agricultural plastic waste: Laboratory-scale study

Manure-derived biochar is the solid product resulting from pyrolysis of animal manures. It has considerable potential both to improve soil quality with high levels of nutrients and to reduce contaminants in water and soil. However, the combustible gas produced from manure pyrolysis generally does not provide enough energy to sustain the pyrolysis process. Supplementing this process may be achieved with spent agricultural plastic films; these feedstocks have large amounts of available energy. Plastic films are often used in soil fumigation. They are usually disposed in landfills, which is wasteful, expensive, and environmentally unsustainable. The objective of this work was to investigate both the energetics of co-pyrolyzing swine solids with spent plastic mulch films (SPM) and the characteristics of its gas, liquid, and solid byproducts. The heating value of the product gas from co-pyrolysis was found to be much higher than that of natural gas; furthermore, the gas had no detectable toxic fumigants. Energetically, sustaining pyrolysis of the swine solids through the energy of the product gas could be achieved by co-pyrolyzing dewatered swine solids (25% m/m) with just 10% SPM. If more than 10% SPM is used, the co-pyrolysis would generate surplus energy which could be used for power generation. Biochars produced from co-pyrolyzing SPM and swine solid were similar to swine solid alone based on the surface area and the ¹H NMR spectra. The results of this study demonstrated the potential of using pyrolysis technology to manage two prominent agricultural waste streams (SPM and swine solids) while producing value-added biochar and a power source that could be used for local farm operations.     

Mercury flows in a zinc smelting facility in South Korea

To prepare for the international mercury convention, the characteristics of mercury emissions from a zinc smelting facility in South Korea have been reviewed and a material flow analysis (MFA) has been conducted in this research. As inputs into the mercury MFA study, zinc ores and sulfuric acid were examined, whereas wastewater sludge, effluence water, spent catalyst, and emissions from the casting and roasting processes were examined as outputs. Mercury concentrations extracted from end products like zinc ingots, cadmium ingots, and sulfuric acid were then analyzed. Our results showed that the wastewater sludge discharged from the zinc smelting process had a relatively higher concentration of mercury, indicating that the concentration of mercury was further enriched in the wastewater sludge. The wastes discharged through the zinc smelting process should be thoroughly controlled, as results of the MFA showed that approximately 89 % of the mercury contained in the original input was later found in the waste. According to this study, the higher the concentration of mercury within zinc ores at the input stage, the higher is the mercury concentration found in the wastewater sludge at the output stage.     

Numerical study of heat transfer characteristics of char from waste tire pyrolysis

To investigate heat transfer of char from waste tire pyrolysis, the cooling of char was simulated by the computational fluid dynamics. To scrutinize the heat transfer characteristics, bed height, temperature of cooling wall, and mixing time were selected as calculation parameters. From the results, increasing the char bed height from 0.005 to 0.02 m, the total heat transfer is decreased as from 45.5 to 26.5 J. As the char bed height is further increased from 0.02 to 0.06 m, the total heat transfer is decreased from 26.5 to 9.1 J. The char bed height affects the total heat transfer significantly. The total heat transfer decreases from 15.9 to 14.0 J as the temperature of cooling wall increases from 273.15 to 323.15 K. The total heat transfer mildly depends on the temperature of cooling wall. The particle mixing time increases from 10 to 120 s and the total heat transfer decreases from 28.6 to 22.6 J. It is noted that the particle contact is enhanced between char particles as well as the particles and cooling wall as the particle mixing time decreases. Consequently, heat transfer is augmented.     

Hydro-thermal reaction according to the CaO/SiO2 mole-ratio in silico-manganese slag

Journal of Material Cycles and Waste Management - SiMn slag is a by-product of the production of ferroalloy, and has a chemical composition that could be used as a cement admixture. It is not...     

Performance of an electrochemical COD (chemical oxygen demand) sensor with an electrode-surface grinding unit

An electrochemical COD (chemical oxygen demand) sensor using an electrode-surface grinding unit was investigated. The electrolyzing (oxidizing) action of copper on an organic species was used as the basis of the COD measuring sensor. Using a simple three-electrode cell and a surface grinding unit, the organic species is activated by the catalytic action of copper and oxidized at a working electrode, poised at a positive potential. When synthetic wastewater was fed into the system, the measured Coulombic yields were found to be dependent on the COD of the synthetic wastewater. A linear correlation between the Coulombic yields and the COD of the synthetic wastewater was established (10-1000 mg L(-1)) when the electrode-surface grinding procedure was activated briefly at 8 h intervals. When various kinds of wastewater samples obtained from various sewage treatment plants were measured, linear correlations (r(2)> or = 0.92) between the measured EOD (electrochemical oxygen demand) value and COD of the samples were observed. At a practical wastewater treatment plant, the measurement system was successfully operated with high accuracy and good stability over 3 months. These experimental results show that the application of the measurement system would be a rapid and practical method for the determination of COD in water industries.     

Optimal Design of a Multi-Pollutant Air Quality Monitoring Network in a Metropolitan Region Using Kaohsiung, Taiwan as an Example

An air quality monitoring network (AQMN) usually performs the basic function of assessment of regional air quality and demonstration of compliance with ambient air quality standards in an urban area. Different pollutants, however, may present different characteristic variabilities due to their specific emission patterns, rates of diffusion, and transport and transformation behaviors. But the costs of siting in a pollutant-specific monitoring network would be higher than that for a common network with respect to several pollutants monitored simultaneously. This paper presents a survey of multi-pollutant design principles and optimal searches for siting patterns of an AQMN using both simulation and optimization models as a combined tool. While conservative, quasi-stable, and reactive pollutants are considered in the design principles, cost, coverage effectiveness, and spatial correlation characteristics are included in the multi-criteria decision making process. For illustrative purpose, a series of technical settings and two types of objectives were examined in the case study for the city of Kaohsiung in Taiwan.     

Development of Customized Fire Behavior Fuel Models for Boreal Forests of Northeastern China

Knowledge of forest fuels and their potential fire behavior across a landscape is essential in fire management. Four customized fire behavior fuel models that differed significantly in fuels characteristics and environmental conditions were identified using hierarchical cluster analysis based on fuels data collected across a boreal forest landscape in northeastern China. Fuel model I represented the dense and heavily branched Pinus pumila shrubland which has significant fine live woody fuels. These forests occur mainly at higher mountain elevations. Fuel model II is applicable to forests dominated by Betula platyphylla and Populus davidiana occurring in native forests on hill slopes or at low mountain elevations. This fuel model was differentiated from other fuel models by higher herbaceous cover and lower fine live woody loading. The primary coniferous forests dominated by Larix gmelini and Pinus sylvestris L. var. mongolica were classified as fuel model III and fuel model IV. Those fuel models differed from one another in average cover and height of understory shrub and herbaceous layers as well as in aspect. The potential fire behavior for each fuel model was simulated with the BehavePlus5.0 fire behavior prediction system. The simulation results indicated that the Pinus pumila shrubland fuels had the most severe fire behavior for the 97th percentile weather condition, and had the least severe fire behavior under 90th percentile weather condition. Fuel model II presented the least severe fire potential across weather conditions. Fuel model IV resulted in greater fire severity than Fuel model III across the two weather scenarios that were examined.     

A resilience-based approach for comparing expert preferences across two large-scale coastal management programs

This report proposes a method for assessing resilience-building components in coastal social–ecological systems. Using the proposed model, the preferences of experts in Masan Bay (South Korea) and Puget Sound (USA) are compared. A total of 30 management objectives were determined and used to build a hierarchic tree designed using the principles of the Analytic Hierarchy Process (AHP). Surveys were performed with 35 Puget Sound experts using face-to-face interviews and with 28 Masan Bay experts by mail. The results demonstrate that the legal objective, which enables legislation, was the highest preferred component in both regions. The knowledge translation variable was also given a high preference score in both regions. An analysis of variance (ANOVA) showed that the Puget Sound experts significantly favored attention to education, habitat restoration and species protection objectives in comparison to the Masan Bay experts. The Masan Bay experts placed greater emphasis on legislation and the type of institutional design than did the Puget Sound experts. Using cluster analysis, four distinct groups of respondents were independently identified in Puget Sound and three groups were identified in Masan Bay. One unique subgroup in the Puget Sound experts group, which was characterized by its high preferences for habitat restoration and species protection, was not observed in Masan Bay. Demographic variables (length of career and role in coastal issue) failed to account for the differences in groupings and preferences in either region, except for the variable ‘favoring information source’ in the Puget Sound group. This finding implies that the demographic information was not related to differences in group opinions in both regions. The analysis framework presented here was effective in identifying expert preferences regarding the overall structure and emphasis in coastal management programs. Thus, this framework can be applied towards coastal policy development.