火电厂烟气排放连续监测系统的检测

针对烟气排放连续监测系统（CEMS）现场检测中发现的许多问题进行了探讨。并提出建议,认为完善和规范标准体系、加强监督管理是解决当前问题的主要途径。     

降尘监测点位优化应用研究

以上海市长兴岛的环境空气降尘点位为例,采用聚类分析法对点位进行优化分析,快速完成点位的分类;再引入主成分分析法进行分析,不仅验证了聚类分析结果,并可根据原信息量需要保留的比例,来合理确定优选的类别数,使得优化调整的过程更为科学,结果也更为可信。     

Effect of amorphous silica and silica sand on removal of chromium(VI) by zero-valent iron

The effect of two surfaces (amorphous silica and silica sand) on the reduction of chromium(VI) by zero-valent iron (Fe(0)) was investigated using batch reactors. The amendment of both surfaces significantly increased the rate and extent of Cr(VI) removal. The rate enhancement by amended surfaces is presumed to result from scavenging of Fe(0)-Cr(VI) reaction products by the provided surfaces, which minimized surface deactivation of Fe(0). The rate enhancing effect was greater for silica compared to sand, and the difference is attributed to silica's higher surface area, greater affinity for reaction products and pH buffering effect. For a given mass of Fe(0), the reactivity and longevity of Fe(0) to treat Cr(VI) increased with increasing dose of silica. Elemental analyses of the reacted iron and silica revealed that chromium removed from the solution was associated with both surfaces, with its mass distribution being approximately 1:1 per mass of iron and silica. The overall result suggests reductive precipitation was a predominant Cr(VI) removal pathway, which involves initial reduction of Cr(VI) to Cr(III), followed by formation of Cr(III)/Fe(III) hydroxides precipitates.     

Mechanism of decolorization and degradation of CI Direct Red 23 by ozonation combined with sonolysis

The decolorization and degradation of CI Direct Red 23, which is suspected to be carcinogenic, were investigated using ozonation combined with sonolysis. The results showed that the combination of ozonation and sonolysis was a highly effective way to remove color from waste water. The operational parameters, namely concentration of the dye, pH, ozone dose and ultrasonic density, were investigated during the process. The decolorization of the dye followed pseudo-first-order kinetics. Increasing the initial concentration of Direct Red 23 led to a decreasing rate constant. The optimum pH for the reaction was 8.0, and both lower and higher pH decreased the removal rate. The effect of the ozone dose on the dye decolorization was much greater than that of the sonolysis density. Intermediates such as naphthalene-2-sulfonic acid, 1-naphthol, urea and acetamide were detected by gas chromatography coupled with mass spectrometry in the absence of pH buffer, while nitrate and sulfate ions and formic, acetic and oxalic acids were detected by ion chromatography. A tentative degradation pathway was proposed without any further quantitative analyses. During the degradation, all nitrogen atoms and phenyl groups of Direct Red 23 were degraded into urea, nitrate ion, nitrogen and formic, acetic and oxalic acids, etc.     

Response of microcystis to copper stress: do phenotypes of microcystis make a difference in stress tolerance?

To elucidate the role of phenotype in stress-tolerant bloom-forming cyanobacterium Microcystis, two phenotypes of M. aeruginosa - unicellular and colonial strains were selected to investigate how they responded to copper stress. Flow cytometry (FCM) examination indicated that the percents of viable cells in unicellular and colonial Microcystis were 1.92-2.83% and 72.3-97.51%, respectively, under 0.25 mgl(-1) copper sulfate treatment for 24h. Upon exposure to 0.25 mgl(-1) copper sulfate, the activities of antioxidative enzyme, such as superoxide dismutase (SOD) and catalase (CAT), were significantly increased in colonial Microcystis compared to unicellular Microcystis. Meanwhile, the values of the photosynthetic parameters (F(v)/F(m), ETR(max), and oxygen evolution rate) decreased more rapidly in unicellular Microcystis than in colonial Microcystis. The results indicate that colonial Microcystis has a higher endurance to copper than unicellular Microcystis. This suggests that the efficient treatment concentration of copper sulfate as algaecides will be dependent on the phenotypes of Microcystis.     

Numerical simulations of heat and moisture transport in thermal protective clothing under flash fire conditions.

A numerical model of heat and moisture transport in thermal protective clothing during exposure to a flash fire was introduced. The model was developed with the assumption that textiles are treated as porous media. The numerical model predictions were compared with experimental data from different fabric systems and configurations. Additionally, with the introduction of a skin model, the parameters that affect the performance of thermal protective clothing were investigated.     

火灾事故发展趋势预测方法的应用研究

介绍了三种火灾事故发展趋势预测方法：灰色理论预测法、指数平滑法和马尔科夫预测法。结合贵州省1997至2006年火灾四项指标统计数据,探讨了三种预测方法对不同波动幅度数据序列的适用性;给出了贵州省未来两年火灾的发展趋势,可为当地制定正确地防止火灾发生的决策提供重要的参考依据。此外,还对每种方法在预测过程中值得注意的问题进行了讨论。     

农村生活污水治理措施

介绍了适合于国内农村生活污水治理的一些技术与措施。沼气技术是当前处理农村生活污水的较佳选择。