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171.
Vanadium recovery from oil fly ash by leaching, precipitation and solvent extraction processes 总被引:2,自引:0,他引:2
Navarro R Guzman J Saucedo I Revilla J Guibal E 《Waste management (New York, N.Y.)》2007,27(3):425-438
In order to reduce the environmental impact due to land disposal of oil fly ash from power plants and to valorize this waste material, the removal of vanadium was investigated using leaching processes (acidic and alkaline treatments), followed by a second step of metal recovery from leachates involving either solvent extraction or selective precipitation. Despite a lower leaching efficiency (compared to sulfuric acid), sodium hydroxide was selected for vanadium leaching since it is more selective for vanadium (versus other transition metals). Precipitation was preferred to solvent extraction for the second step in the treatment since: (a) it is more selective; enabling complete recovery of vanadate from the leachate in the form of pure ammonium vanadate; and (b) stripping of the loaded organic phase (in the solvent extraction process) was not efficient. Precipitation was performed in a two-step procedure: (a) aluminum was first precipitated at pH 8; (b) then ammonium chloride was added at pH 5 to bring about vanadium precipitation. 相似文献
172.
In The Netherlands, construction and demolition (C&D) waste is already to a large extent being reused, especially the stony fraction, which is crushed and reused as a road base material. In order to increase the percentage of reuse of the total C&D waste flow to even higher levels, a new concept has been developed. In this concept, called 'Closed Cycle Construction', the processed materials are being reused at a higher quality level and the quantity of waste that has to be disposed of is minimised. For concrete and masonry, the new concept implies that the material cycle will be completely closed, and the original constituents (clay bricks, gravel, sand, cement stone) are recovered in thermal processes. The mixed C&D waste streams are separated and decontaminated. For this purpose several dry separation techniques are being developed. The quality of the stony fraction is improved so much, that this fraction can be reused as an aggregate in concrete. The new concept has several benefits from a sustainability point of view, namely less energy consumption, less carbon dioxide emission, less waste production and less land use (for excavation and disposal sites). One of the most remarkable benefits of the new concept is that the thermal process steps are fuelled with the combustible fraction of the C&D waste itself. Economically the new process is more or less comparable with the current way of processing C&D waste. On the basis of the positive results of a feasibility study, currently a pilot and demonstration project is being carried out. The aim is to optimise the different process steps of the Closed Cycle Construction process on a laboratory scale, and then to verify them on a large scale. The results of the project are promising, so far. 相似文献
173.
Chloramphenicol (CA) is a largely used antibiotic and it is an inhibitor of protein synthesis that also induces ROS production. In this work there were investigated activities and expressions in the Adriatic bivalve Chamelea gallina of some antioxidant and detoxification proteins like superoxide dismutase (Mn-SOD, Cu/Zn-SOD), catalase (CAT) and Cytochrome P450 (CYP1A). Clams exposed to 5mgl(-1) of chloramphenicol were sampled 2, 4 and 8 days after treatment (CA2, CA4 and CA8). SODs, CAT, and CYP1A activity and/or expression were detected in pooled digestive glands by Western blotting and by spectrophotometrical analysis. Enzymes activities increase during the entire antibiotic exposure. With respect to the control Cu/Zn-SOD expression increases, while Mn-SOD expression decreases significantly after 4 days. Two CYP1A immunopositive-proteins (57.7 and 59.8kDa) were detected. The lower band significantly decreases in CA8, the upper one also in CA4 condition. High levels of Mn-SOD, CAT activity and Cu/Zn-SOD expression, indicate intense ROS production while Mn-SOD expression inhibition might be ascribable to mitochondrial alterations due to CA and indirectly to ROS. CYP1A1 action determines H(2)O(2) production that would contribute to a CYP1A1 gene promoter down regulation, a response to oxidative stress with the antioxidant enzymes activation as a final result. This study highlights the close association, in C. gallina, in presence of chloramphenicol, between SOD/CAT and CYP system, and it appear particularly interesting to the lack of similar researches on mollusc species. 相似文献
174.
Aishah S. A. K. Sharifah Hanafiah Zainal Abidin Mohamad R. Sulaiman Kheng H. Khoo Hairi Ali 《Journal of Material Cycles and Waste Management》2008,10(2):116-123
Malaysia is in dire need of alternatives to landfilling for solid waste management. Recently, landfills have faced the problems
of overfilling, overflowing of leachates leading to pollution of water resources, and uncontrolled dust emissions adversely
affecting the local environment. With the rising cost of urbanization coupled with the high rate of waste generation, one
possible method of waste treatment that is receiving particular attention by the government is incineration. Incineration
of solid waste is rather new in Malaysia, with limited usage in handling small sources of waste generation such as the municipal
solid waste (MSW) of resort islands; however, its potential in ameliorating the problems associated with solid waste treatment
may make it an attractive alternative to landfill. This article presents the results of test runs conducted to investigate
the performance of a locally designed and manufactured rotary kiln incinerator (RKI). The test runs were conducted using MSW
collected from the Shah Alam municipality. The combustion efficiency was analyzed by looking at the temperature profiles and
chemical species concentrations. To complement the combustion characteristics measurements, predictions of the air flow in
the incinerator during the process were also investigated. The overall performance of the RKI suggests that it is suitable
for treating MSW. 相似文献
175.
Reiner Schroll Sabine Grundmann Ulrike Dörfler Bernhard Ruth Jean Charles Munch 《Water, Air, & Soil Pollution: Focus》2008,8(2):209-216
Several lysimeter scenarios and approaches exist to study the fate of agro-chemicals or contaminants from deposition in soil
columns. In many systems just transport and leaching of the parent compound is followed, in some systems the leaching and
transport of the metabolites is investigated as well. In more sophisticated lysimeter systems the volatilization and also
the mineralization of the applied chemicals can be additionally monitored. Depending on the lysimeter system used and on the
fact whether the applied chemicals are 14C-labeled or not, different results and various interpretations of the results might be achieved. Different lysimeter systems
are described in this paper and a real dataset of a specific lysimeter experiment was transferred and evaluated in a virtual
approach in the different lysimeter systems in order to show the advantages and disadvantages of the various systems. 相似文献
176.
MULTI INCREMENT® and discrete sampling strategies were used to estimate the average concentration and the three‐dimensional distribution of TCE in a 3,300‐m3 zone composed of two decision units (e.g., area of concern, population, exposure unit). Authors of this article and a private contractor (Stanley Consultants Inc.), respectively, implemented these two sampling strategies independently. Compared to discrete sampling, the MULTI INCREMENT sampling strategy identified more locations where percent‐level concentrations of TCE have migrated, is more economical, and provided greater data quality. © 2008 Wiley Periodicals, Inc. 相似文献
177.
LEAP是由斯德哥尔摩环境研究所(SEI)波士顿中心领导的一项合作项目,旨在为一体化的能源环境分析建立一套新的分析软件和数据库.LEAP2000项目的产品应尽早获得以广为传播. 相似文献
178.
The fractal branching of an arborescent sponge 总被引:4,自引:0,他引:4
Edward R. Abraham 《Marine Biology》2001,138(3):503-510
The fractal properties of specimens of a planar branching sponge Raspailia inaequalis (Porifera, Demospongiae) were determined by analysing digitised photographs. The specimens, collected from a single site
in northeastern New Zealand, had a wide range of morphology. Three different fractal methods were used: box counting; a method
that gives the scaling of branch length with distance from the base of the fan; and an allometric analysis of the dependence
of frontal area on specimen size. All three approaches gave a similar value for the fractal dimension. The conjecture that
the specimens have a fractal branching structure is consistent with the results of a Horton analysis of their branching pattern.
There is a significant relationship between fractal dimension and number of fingers, which implies that a simple count of
the number of fingers is as useful for discriminating between individuals as the more complex fractal analysis. Using this
relation, sponges from a site with less water movement are inferred to have a lower fractal dimension. This result is in agreement
with the predictions of the Kaandorp model of sponge growth.
Received: 13 March 2000 / Accepted: 11 October 2000 相似文献
179.
Information concerning the way juvenile crabs choose their diet from a variety of prey types can be useful for a better understanding of community dynamics, as well as for the adequate management of natural resources. Prey size and species selection by juvenile Carcinus maenas (15-35 mm carapace width, CW) and Cancer pagurus (20-40 mm CW) feeding on four bivalves of contrasting shell morphology were investigated. When offered a wide size range of Mytilus edulis, Ostrea edulis, Crassostrea gigas, and Cerastoderma edule presented individually, crabs generally showed evidence of size-selective predation. Cancer pagurus selected larger mussels relative to the size of their chelae (relative prey size, RPS) than did Carcinus maenas of similar and even larger carapace width. However, the RPS of selected O. edulis and Cerastoderma edule were similar for all crabs, suggesting that certain prey features constitute effective barriers even to the powerful chelae of Cancer pagurus. When offered a wide size range of mussels and oysters simultaneously, all crabs consistently selected mussels. When offered O. edulis and Crassostrea gigas, crabs consumed both these oyster species in similar numbers. Carcinus maenas consumed similar numbers of mussels and cockles; Cancer pagurus, however, showed no preference for either prey in the smaller size classes but selected more mussels than cockles as prey increased in size. Although previous studies report that adult Carcinus maenas select prey species according to their profitability (amount of food ingested per unit of handling time, milligrams per second), consumption rates of the size classes of prey selected by juvenile shore crabs did not always parallel prey value. Although variations in crab strength can account for many of the differences between the foraging strategy of juvenile and adult C. maenas, our results suggest that juvenile crabs are less species selective than adults as a result of the restrictions imposed on small individuals that have limited access to larger prey. 相似文献
180.
M. Zimmer J. P. Danko S. C. Pennings A. R. Danford A. Ziegler R. F. Uglow T. H. Carefoot 《Marine Biology》2001,138(5):955-963
Three isopod species (Crustacea: Isopoda), commonly found in the intertidal and supratidal zones of the North American Pacific
coast, were studied with respect to symbiotic microbiota in their midgut glands (hepatopancreas). Ligia pallasii (Oniscidea: Ligiidae) contained high numbers of microbial symbionts in its hepatopancreatic caeca. Numbers of endosymbionts
were strongly reduced by ingestion of antibiotics. By contrast, the hepatopancreas of Idotea wosnesenskii (Valvifera: Idoteidae) and Gnorimosphaeroma oregonense (Sphaeromatidea: Sphaeromatidae) did not contain any microbiota. Results of feeding experiments suggest that microbial endosymbionts
contribute to digestive processes in L. pallasii, the most terrestrial of the three isopods that we studied. The acquisition of digestion-enhancing endosymbionts may have
been an important evolutionary step allowing isopods to colonize terrestrial habitats where relatively indigestible leaf litter
is the primary food source. By contrast, the ability to digest phenolic compounds was most developed in one of the more marine
species, suggesting that this trait may have evolved independently in isopod species that consume a phenolic-rich diet, whether
in marine habitats or on land.
Received: 28 August 2000 / Accepted: 8 December 2000 相似文献