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241.
Tungsten trioxide thin films on transparent substrates (glass and F:SnO(2) or ITO-coated glass) were prepared by layer-by-layer brush painting and spin-coating using organic precursors. Well-crystallized WO(3) with monoclinic structure was formed on all substrates after annealing at 500 degrees C or above. The dense semiconducting films are specular and transparent outside the band-gap. Their photoactivity in junctions with aqueous electrolytes extends up to 470 nm, with incident photon to current conversion efficiencies around 0.9 at 313 nm and up to 0.1 at 436 nm. Films of 10 cm x 10 cm were used for the study of solute degradation reactions in a thin-film reactor under backside illumination. Dilute aqueous solutions of model substances for contaminants like oxalic acid were decomposed under continuous flow using broadband UVA illumination and electrical bias. Operation under solar illumination was also feasible. The advantage over operation without bias (conventional photocatalysis) prevailed for all decomposition reactions studied. 相似文献
242.
The role of American leadership in the UN climate negotiations that produced the 2015 Paris Agreement is examined. First, United States (US) climate goals are identified. Then, utilizing unique survey data collected at eight UN climate summits between 2008 and 2015, the extent to which the US was recognized as a leader by potential followers is investigated. Finally, the extent to which US goals are reflected in negotiation outcomes is evaluated. Recognition of the US as a leader varied over time, peaking at the UN climate meetings in Copenhagen and Paris, reflecting US leadership in shaping the outcomes of both meetings. Although the results reveal a divided leadership landscape in which the US must compete for leadership with other actors, such as the European Union and China, US leadership was crucial to the successful adoption of the Paris Agreement. 相似文献
243.
Stefanie Walter Michael Brüggemann Sven Engesser 《Environmental Communication: A Journal of Nature and Culture》2018,12(2):204-217
Although there is a broad consensus among scientists and journalists about the existence of anthropogenic climate change as a global problem, some segments of the population remain doubtful about the human impact on it. The internet provides citizens with opportunities to publicly voice their doubts and user comment sections of online media are a popular form of user-generated content. This study identifies factors that foster comments that are sceptical or supportive of basic assumptions of anthropogenic climate change, drawing on online news in the US, the UK, Germany, India, and Switzerland. The results show that users adapt to the dominant opinion within the respective media outlet: user comment sections serve as echo chambers rather than as corrective mechanisms. Climate change denial is more visible in user comment sections in countries where the climate change debate reflects the scientific consensus on climate change and user comments create niches of denial. 相似文献
244.
Dorothee Arlt Imke Hoppe Josephine B. Schmitt Fenja De Silva-Schmidt Michael Brüggemann 《Environmental Communication: A Journal of Nature and Culture》2018,12(1):84-98
Various scholars underscore the importance of public engagement with climate change to successfully respond to the challenges of global warming. However, although online media provide various new opportunities to actively engage in climate discourse so far very little is known about the drivers of this form of engagement. Against this background, this study tested a theoretical model on the effects of media and interpersonal communication on participation in climate discourse online using data from a representative online survey of German citizens (n?=?1392) carried out while COP21. Overall, the results show that receiving information on climate change from social media (social networks, Twitter, blogs), active information seeking online and interpersonal conversations about COP21 strongly encourage participation in climate discourse online. Moreover, results provide relevant insights on the role of interest in climate politics, personal issue relevance and climate scepticism as preconditions of communication effects. 相似文献
245.
A. Massling M. Stock B. Wehner Z.J. Wu M. Hu E. Brüggemann T. Gnauk H. Herrmann A. Wiedensohler 《Atmospheric environment (Oxford, England : 1994)》2009,43(8):1578-1589
Physical and chemical properties of submicrometer aerosol particles were measured in summer 2004 (June/July) and winter 2005 (January/February) in Beijing, Peoples Republic of China, using a Twin-Differential Mobility Particle Sizer (T-DMPS), a Hygroscopicity-Tandem Differential Mobility Analyzer (H-TDMA), and a Micro Orifice Uniform Deposit Impactor (MOUDI). Particle number–size distributions were measured in the diameter range Dp = 3–800 nm and hygroscopic properties were determined at initial dry particle diameters of Dpj (j = 30, 50, 80, 150, 250, and 350 nm) at a relative humidity (RH) of 90%. Hygroscopic properties were compared with chemical analyses of aerosol samples taken with the MOUDI. Based on the hygroscopicity data, the total hygroscopic particle volume was modeled, including dependence on dry particle size, season and level of pollution using a simple approach.Overall, the chemical analysis showed ammonium sulfate to be the major inorganic component of the urban submicrometer aerosol in Beijing along with relatively high fractions of elemental carbon (10–25%) and organic matter (15–60%) depending on particle size and season.The hygroscopic growth distributions (H-TDMA) subdivided the aerosol population into three different groups of particles with varying growth factors depending on dry particle size, namely nearly hydrophobic (growth factor = 0.96–1.07), less hygroscopic (1.06–1.29) and more hygroscopic (1.26–1.62).Hydrophobic particle fractions indicating freshly emitted soot/carbonaceous particles varied between 10 and 32% depending on dry particle size and season. During heavily polluted times, a decreasing number of hydrophobic particle fractions indicated that the urban submicrometer aerosol in Beijing was highly influenced by more aged aerosol transported from the industrial regions around Beijing containing sulfate as a major component.Based on model calculations, the urban submicrometer aerosol in Beijing showed strong compositional variations. The calculated total hygroscopic volume fractions varied between 16 and 65% depending on size, level of pollution and season. 相似文献
246.
E. Brüggemann H. Gerwig Th. Gnauk K. Müller H. Herrmann 《Atmospheric environment (Oxford, England : 1994)》2009,43(15):2456-2463
The size-segregated chemical composition of atmospheric aerosol particles (aerodynamic diameter Dpaer = 0.05–10 μm) was studied to reveal differences between seasons (winter/summer), air mass origins (East/West/North), and days of the week (weekday/Sunday). The goal was to identify the different particle emission sources for the first time at a kerbside in the city of Dresden, Germany.Ultra-fine particles (Dpaer = 0.05–0.14 μm, 12% of PM10) consisted of approximately 80% OM (organic matter) and EC (elemental carbon), while fine particles (Dpaer = 0.14–1.2 μm) comprised about 55% ionic compounds with 44% OM and EC. The coarse fraction (Dpaer = 1.2–10 μm) consisted of approximately 65% ions/OM/EC and 20% metal oxides.Pb, Zn, and Cu showed crustal enrichment factors (CEFSi) > 100 for all particle sizes indicating strong anthropogenic influence. The Zn source was coal burning rather than traffic emissions. Doubled concentrations in winter were likely caused by coal combustion (Pb) and biomass burning (K), but also by a lower mixing layer height. Air masses from the East caused higher Pb and K concentrations. The origin of air masses had almost no influence on Cu, Cr, Fe, Mn, Zn and Ca, Si, Ti, indicating local sources such as traffic and heating. Possible actions against particle emissions are discussed. 相似文献
247.
Camilla Andersson Robert Bergström Christer Johansson 《Atmospheric environment (Oxford, England : 1994)》2009,43(22-23):3614-3620
This paper presents the contribution to population exposure (PE) of regional background fine primary (PPM2.5) and secondary inorganic (SIA) particulate matter and its impact on mortality in Europe during 1997–2003 calculated with a chemistry transport model. Contributions to concentrations and PE due to emissions from shipping, Western (WEU), Eastern (EEU), and Northern Europe are compared.WEU contributes about 40% to both PPM2.5 and SIA concentrations, whereas the EEU contribution to PPM2.5 is much higher (43% of total PPM2.5) than to SIA (29% of total SIA). The population weighted average concentration (PWC) of PPM2.5 is a factor of 2.3 higher than average (non-weighted) concentrations, whereas for SIA the PWC is only a factor 1.6 higher. This is due to PPM2.5 concentrations having larger gradients and being relatively high over densely populated areas, whereas SIA is formed outside populated areas. WEU emissions contribute relatively more than EEU to PWC and mortality due to both PPM2.5 and SIA in Europe.The number of premature deaths in Europe is estimated to 301 000 per year due to PPM2.5 exposure and 245 000 due to SIA, despite 3.3 times higher average SIA concentrations. This is due to population weighting and assumed (and uncertain) higher relative risk of mortality for PPM2.5 components (2.8 times higher RR for PPM2.5). This study indicates that it might be more efficient, for the health of the European population, to decrease primary PM emissions (especially in WEU) than to decrease precursors of SIA, but more knowledge on the toxicity of different PM constituents is needed before firm conclusions can be drawn. 相似文献
248.
Chunyan Liu Jirko Holst Zhisheng Yao Nicolas Brüggemann Klaus Butterbach-Bahl Shenghui Han Xingguo Han Bart Tas Andreas Susenbeth Xunhua Zheng 《Atmospheric environment (Oxford, England : 1994)》2009,43(19):3086-3095
We present a methane (CH4) budget for the area of the Baiyinxile Livestock Farm, which comprises approximately 1/3 of the Xilin river catchment in central Inner Mongolia, P.R. China. The budget calculations comprise the contributions of natural sources and sinks as well as sources related to the main land-use in this region (non-nomadic pastoralism) during the growing season (May–September). We identified as important CH4 sources floodplains (mean 1.55 ± 0.97 mg CH4–C m?2 h?1) and domestic ruminants, which are mainly sheep in this area. Within the floodplain significant differences between investigated positions were detected, whereby only positions close-by the river or bayous emitted large amounts of CH4 (mean up to 6.21 ± 1.83 mg CH4–C m?2 h?1). Further CH4 sources were sheepfolds (0.08–0.91 mg CH4–C m?2 h?1) and pasture faeces (1.34 ± 0.22 mg CH4–C g?1 faeces dry weight), but they did not play a significant role for the CH4 budget. In contrast, dung heaps were not a net source of CH4 (0.0 ± 0.2 for an old and 0.0 ± 0.3 μg CH4–C kg?1 h?1 for a new dung heap). Trace gas measurements along two landscape transects (volcano, hill slope) revealed expectedly a mean CH4 uptake (volcano: 76.5 ± 4.3; hill: 28.3 ± 5.3 μg CH4–C m?2 h?1), which is typical for the aerobic soils in this and other steppe ecosystems. The observed fluxes were rarely influenced by topography.The CH4 emissions from the floodplain and the sheep were not compensated by the CH4 oxidation of aerobic steppe soils and thus, this managed semi-arid grassland did not serve as a terrestrial sink, but as a source for this globally important greenhouse gas. The source strength amounted to 1.5–3.6 kg CH4–C ha?1 during the growing season, corresponding to 3.5–8.7 kg C ha?1 yr?1. 相似文献
249.
Durrant CJ Stevens JR Hogstrand C Bury NR 《Environmental pollution (Barking, Essex : 1987)》2011,159(12):3595-3603
The River Hayle in south-west England is impacted with metals and can be divided into three regions depending on the copper and zinc concentrations: a low-metal upper section; a highly-contaminated middle section and a moderately contaminated lower section. Hayle river water is toxic to metal-naive brown trout, but brown trout are found in the upper and lower regions. The study aimed to evaluate the population genetic structure of River Hayle brown trout and to determine if the highly-contaminated section acts as a chemical barrier to migration. Population genetic analysis indicated that metals were not a barrier to gene flow within the river, but there was a high level of differentiation observed between fish sampled at two sites in the upper region, despite being separated by only 1 km. The metal tolerance trait exhibited by this brown trout population may represent an important component of the species genetic diversity in this region. 相似文献