Cleaner production in Danish fish processing – experiences,status and possible future strategies

Danish fish processing industry has been one of the pioneers regarding implementation of cleaner production and environmental management systems. This article describes the experiences with cleaner production (CP) among leading Danish industries producing pickled herring and canned mackerel. The article emphasizes two case studies of ‘first mover’ companies, but data from other ‘proactive’ companies are also included.The article provides an overview of different types of CP solutions, improvement potentials, synergistic effects and possible trade-offs. The development of the applied solutions from the late 1980s until today are analysed and recommendations to future strategies at company level and policy level are provided.It is concluded that significant environmental improvements have been obtained for the analysed companies – especially concerning reductions in water consumption, wastewater emissions, and utilisation of fish ‘waste’ for valuable by-products. Still, more focus could be placed on the reduction of energy consumption, change of packaging types, and environmental impacts in other stages of the products life cycle.Authorities and companies have mainly focused on on-site reductions of wastewater emissions, but life cycle assessments show that more attention should be given to the reductions of environmental impacts in other parts of the product chain, e.g. fishing operations and transport as well.     

Distribution,fate and persistence of organochlorine compounds formed during production of bleached pulp

The processes governing distribution of a xenobiotic compound discharged initially into the environment are discussed, and attention is drawn to (a) binding to organic matter in the sediment phase which affects both persistence and toxicity to biota and (b) the role of atmospheric transport for compounds of low water solubility and high vapour pressure. Important limitations in the use of sum parameters such as EOCI are pointed out. The important distinction between biodegradation and biotransformation is pointed out, and significant experimental determinants noted. Pathways for the aerobic metabolism of chlorophenolic compounds are discussed, and attention is drawn to the role of O‐methylation as an environmentally significant alternative to biodegradation. Evidence for the biodegradation of chlorinated aliphatic acids and hydrocarbons under both aerobic and anaerobic conditions is presented. Anaerobic metabolism of chlorophenolic compounds is discussed with respect to (a) de‐O‐methylation of chloroguaiacols, (b) dechlorination of chlorocatechols and (c) reduction of chlorovanillins. It is emphasized that current evidence provides a complex metabolic picture, and that only partial dechlorination may occur. Brief attention is given to the important issue of the persistence of chlorolignin, and attention drawn to technical issues which render this problem difficult of access by traditional procedures. Biohalogenation—particularly by fungi—is noted, though its quantitative contribution cannot be estimated at the moment. A number of important unresolved issues are underscored: (a) the problem of determining rates of microbial reactions which may be translated to environmental situations, (b) the cardinal role not only of the number of chlorine atoms in an aromatic compound but also the substitution pattern and (c) limitations in current understanding of the role of anaerobic bacteria in bringing about biodegradation and biotransformation.     

Evolution of Cardium (Cerastoderma) edule,C. lamarcki and C. glaucum: studies of DNA-variation

Genetic relations between populations of Cardium (Cerastoderma) edule (L.) and C. lamarcki (Reeve) from Danish waters and C. glaucum (Bruguiére) from the Mediterranean Sea were studied using DNA analysis. Repetitive sequences of nuclear DNA were compared by Southern blotting of enzyme digested DNA fragments, separated on agarose gel by electrophoresis. Fragments were visualized by autoradiography using ³²P labelled probes. These were nick translated, randomly sheared fragments of the whole chromosomal genomes of two species of distant taxa — Mytilus edulis and Mya arenaria, respectively. The number of detected DNA bands was 18 for C. edule, 32 for C. lamarcki, and 24 for C. glaucum. Measurements of genetic distances, based on comparisons of these repetitive sequences using a simple dissimilarity coefficients, show the greatest distance, i.e., 0.84 between C. edule and C. lamarcki, 0.69 between C. edule and C. glaucum, and the smallest, 0.52 between C. lamarcki and C. glaucum. Comparisons of the three Cardium types, using gene spliced and cloned C. edule nuclear DNA (nDNA) fragments as probes, accorded with these findings. Also, analysis of mitochondrial DNA (mtDNA) from eggs and hepatopancreas, although not in itself conclusive, accorded with the results of the analyses of nDNA. MtDNA was measured by electron micrograph to 15 000 base pairs (bp), and sizes of restriction enzyme digested fragments were compared by gel electrophoresis. The results of the comparisons based on repetitive sequences supported by the two other studies suggest that C. edule resembles the ancestral form more than the two others, and that C. lamarcki is the most different and recently evolved form. This hypothesis is discussed in relation to the geographical distribution of the species complex.     

Irreversible binding of o,p'-DDD in interrenal cells of Atlantic cod (Gadus morhua)

Precision-cut tissue slices of the anterior kidney from Atlantic cod (Gadus morhua) were prepared with a Krumdieck tissue slicer and exposed to 2-(2-chlorophenyl)-2-(4-chloro-(14C)phenyl)-1,1-dichlorethane (o,p(')-[14C]DDD) in vitro. Microautoradiography revealed irreversible o,p(')-DDD-derived binding confined to the glucocorticoid producing interrenal cells (adrenocortical analogues). This cell-selective binding was confirmed by means of autoradiography at different levels of resolution on Atlantic cod administered o,p(')-[14C]DDD intragastrically. The results provide evidence for a site-specific metabolic activation and irreversible binding of o,p(')-DDD in the interrenal cells, which, in turn, may modify glucocorticoid homeostasis.     

大型动物的种群恢复:大象种群增长的生态学效应

博茨瓦纳北部及其毗邻地区分布着世界上最大的非洲象种群(Loxodonta africana),而在100年前,由于过度捕猎,大象的种群数量极为稀少.     

Testing the Norwegian phosphorus index at the field and subcatchment scale

Simple risk assessment tools for agricultural phosphorus (P) losses, like the P index, have been developed in the U.S.A. and in some European countries. Despite its popularity, there have been surprisingly few studies, which try to test the index close to the field scale. For Norway, the P index approach comprises the risk related to both the source of P (soil P status, amount of fertilizer and manure as well as method of application, plant P release by freezing and P balance) and the risk related to transport of P (erosion, flooding, surface runoff, contributing distance, modified connectivity, soil profile, subsurface drainage). In this paper, we have applied the Norwegian P index to farmer fields within a small agricultural catchment, the Skuterud catchment (450 ha), in southeastern Norway. The Norwegian P index was tested for two agricultural fields (0.3–0.4 ha) and nine subcatchments (6–65 ha). Total P concentrations in runoff from the 11 study areas were measured during the year from May 2001 to April 2002. Results from the testing showed that the Norwegian P index described 66% of the variation in measured relative total P concentration for fields and subcatchments included in this study. Additionally, the P index was able to detect fields and subcatchments with the highest measured P concentrations. Results also showed that the source factor contributed most to the variation between fields and hence were important for the identification of high-risk areas in Skuterud catchment. It was found that the soil P status described 66% of the variation in the source factor. Among the transport variables, it was found that both erosion risk and contributing distance had an important influence on the transport factor. Overall, the study illustrated the potential of the P index to detect areas with the highest risk of P loss.     

Regional eco-efficiency indicators – a participatory approach

Eco-efficiency emerged in the 1990s as a measure of “the efficiency with which ecological resources are used to meet human needs.” Eco-efficiency indicators as tools for regional sustainability policy were demonstrated in a Life-Environment project, ECOREG, in the Finnish region of Kymenlaakso. A participatory approach was utilised to produce indicators that are relevant for regional decision-makers and that will actually be used. The approach established a system through which decision-makers are able to monitor changes using several economic-environmental ratio indicators, and at the same time obtain information on the social progress taking place in the region. In the future, there will be a need for an ongoing dialogue among the different actors in the region in order to ensure that the indicators are indeed used to promote sustainable development.