全文获取类型
收费全文 | 9849篇 |
免费 | 2篇 |
国内免费 | 1篇 |
专业分类
安全科学 | 4篇 |
废物处理 | 768篇 |
环保管理 | 1223篇 |
综合类 | 989篇 |
基础理论 | 3161篇 |
污染及防治 | 1779篇 |
评价与监测 | 1022篇 |
社会与环境 | 905篇 |
灾害及防治 | 1篇 |
出版年
2023年 | 1篇 |
2022年 | 2篇 |
2021年 | 3篇 |
2020年 | 2篇 |
2019年 | 4篇 |
2018年 | 1476篇 |
2017年 | 1373篇 |
2016年 | 1201篇 |
2015年 | 133篇 |
2014年 | 26篇 |
2013年 | 23篇 |
2012年 | 472篇 |
2011年 | 1351篇 |
2010年 | 698篇 |
2009年 | 610篇 |
2008年 | 888篇 |
2007年 | 1237篇 |
2006年 | 12篇 |
2005年 | 27篇 |
2004年 | 43篇 |
2003年 | 68篇 |
2002年 | 101篇 |
2001年 | 16篇 |
2000年 | 12篇 |
1999年 | 6篇 |
1998年 | 11篇 |
1997年 | 6篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1994年 | 5篇 |
1993年 | 2篇 |
1991年 | 1篇 |
1984年 | 11篇 |
1983年 | 8篇 |
1981年 | 1篇 |
1969年 | 1篇 |
1966年 | 1篇 |
1963年 | 1篇 |
1961年 | 1篇 |
1959年 | 3篇 |
1958年 | 1篇 |
1957年 | 1篇 |
1955年 | 2篇 |
1953年 | 1篇 |
1952年 | 1篇 |
1949年 | 1篇 |
1935年 | 2篇 |
排序方式: 共有9852条查询结果,搜索用时 31 毫秒
981.
Mehmet Sinan Bilgili Gamze Varank Elif Sekman Selin Top Didem Özçimen Remziye Yazıcı 《Environmental Modeling and Assessment》2012,17(3):289-300
Since phenols and phenolic compounds in many industrial wastewaters are toxic organic contaminants for humans and aquatic
life, to remove these compounds via the most efficient way is very important for environmental remediation treatment. In this
context, almost all of the isotherm models (Freundlich, Langmuir, Temkin, Redlich–Peterson, Sips, and Khan) for adsorption
in the literature were applied to explain the adsorption mechanism of 4-chlorophenol on activated carbon in this study. Also
theoretical modeling data were obtained using model equations; interpolation and analysis of variance were made to compare
data by using statistics software. In addition, the thermodynamic and kinetic studies for adsorption mechanism were included
in the article. The adsorption of 4-chlorophenol on activated carbon fits well to the pseudo-first-order kinetic model than
the pseudo-second-order, intraparticular diffusion and Bangham models. It is also indicated that 4-chlorophenol adsorption
by granular activated carbon would be attributed to a type of transition between physical and chemical adsorption rather than
a pure physical or chemical adsorption process. As a result, an environmental remediation problem and the adsorption mechanism
on activated carbon that can be regarded as a solution to this problem are described and explained using the mathematical
models and calculations in this study. 相似文献
982.
Ali Naderi Beni Michael Kühn Robert Meyer Christoph Clauser 《Environmental Modeling and Assessment》2012,17(4):337-351
We study opportunities for CO2 sequestration in geological formations of the state North Rhine Westphalia in Germany. Simulations are performed for evaluating a potential site within the Bunter sandstone formation near the town of Minden in a depth?of around 3,000 m using the numerical simulator TOUGHREACT. Our focus is on three CO2 storage mechanisms: (1) hydrodynamic trapping, (2) dissolution trapping, and (3) mineral trapping. The results show that due to buoyancy the injected CO2 phase initially migrates towards the top of the reservoir and is hydrodynamically trapped beneath the confining layer of the cap rock. Then, the CO2 spreads laterally and dissolves partially in the formation water. The dissolution of CO2 results in an increase of the density of the brine causing a downward migration until it settles after 10,000 years at the bottom of the reservoir. The simulations indicate that after 10,000 years, 15% (17 Mt) from a total of 114 Mt injected CO2 are trapped hydrodynamically, 20% (23 Mt) are trapped by dissolution, and 65% (74 Mt) are fixed in newly formed carbonates such as dawsonite, ankerite, and siderite. Within our study pressure increases near the injection well by a factor of 1.1 which is lower than the upper limit usually accepted in gas storage operations. The mineral reactions cause a net decrease of porosity and in turn a decrease of permeability down to 9% of the initial value in parts of the reservoir. 相似文献
983.
Sotiria Anastasiou Georgios K. Sylaios Vassilios A. Tsihrintzis 《Environmental monitoring and assessment》2015,187(6):392
The present study investigates the use of combined methods of optical and acoustic sensors, in collaboration with direct in situ measurements, for the calibration and validation of a model transforming acoustic backscatter intensity series into suspended particulate matter (SPM) concentration datasets. The model follows previously elaborated techniques, placing particular attention to the parameterization of the acoustic absorption index as a function of water physical properties. Results were obtained from the annual deployment (during 2007–2008) of an upward-facing acoustic Doppler current profiler (ADCP) (307 kHz), equipped with a Wave Array, and an optical backscatter sensor (OBS), at the bottom of Thassos Passage near Nestos River plume (Thracian Sea, Northern Greece). The OBS was calibrated through linear regression, using 2007 and 2012 field sampling data, exhibiting an error of 13–14 % due to chlorophyll presence. The ADCP signal was calibrated through simultaneous measurements of backscatter intensity and turbidity profiles. Harmonic analysis on the model-produced SPM concentrations explained the tidal influence on their variability, especially during the summer. Empirical orthogonal functions analysis revealed the impact of waves and wave-induced currents on SPM variability. Finally, Nestos River sediment load was found uncorrelated to the SPM change in Thassos Passage, due to the dispersal and sediment deposition near the river mouth. 相似文献
984.
Ruzica Micic Snezana Mitic Biljana Arsic Anja Jokic Milan Mitic Danijela Kostic Aleksandra Pavlovic Milan Cekerevac Ljiljana Nikolic-Bujanovic Zaklina Spalevic 《Environmental monitoring and assessment》2015,187(6):389
Zinc, copper, iron, chromium and cobalt are essential elements for human health, showing toxicity only in high concentrations, while lead and cadmium are extremely toxic even as traces. Therefore, it is important to monitor the contents of toxic metals in vegetables. Large number of vegetables is grown and used in nutrition, in Kosovo. The concentrations of selected elements in vegetables (radish, onion, garlic and spinach) from Kosovo were determined using ICP-OES method. Oral intake of metals and health risk index were calculated. Statistical analysis indicated numerous positive correlations between concentrations of selected elements in vegetables. As a result of principal component analysis, 15 new variables were obtained which were characterized by eigenvalues. The sequence of health quotients for the heavy metals followed the decreasing order Zn?=?Mn?>?Pb?>?Cu?>?Ni?>?Fe?>?Cd?>?Co?>?Cr. The health quotients for all investigated heavy metals were below 1 (one), which is considered safe. The vegetables from Kosovo are mainly safe for use in everyday diet. 相似文献
985.
Thomas Minning Darren A. Lytle Maily Pham Keith Kelty 《Environmental monitoring and assessment》2015,187(6):383
Distinguishing between soluble and particulate lead in drinking water is useful in understanding the mechanism of lead release and identifying remedial action. Typically, particulate lead is defined as the amount of lead removed by a 0.45-μm filter. Unfortunately, there is little guidance regarding selection of filter membrane material and little consideration to the possibility of the sorption of dissolved lead to the filter. The objective of this work was to examine the tendency of 0.45-μm syringe filter materials to adsorb lead. Tests were performed with water containing 40 and 24 μg/L soluble lead at pH 7 buffered with 50 mg C/L dissolved inorganic concentration (DIC). The amounts of lead sorbed greatly varied by filter, and only two filter types, polypropylene and mixed cellulose esters, performed well and are recommended. Great care must be taken in choosing a filter when filtering soluble lead and interpreting filter results. 相似文献
986.
V. Vijayasree Hebsy Bai S. Naseema Beevi Thomas Biju Mathew Thomas George George Xavier 《Environmental monitoring and assessment》2015,187(5):299
Dissipation and decontamination of chlorantraniliprole (Coragen 18.5 SC) in brinjal and okra fruits were studied following field application at single and double doses of 30 and 60 g ai ha?1, and the residues of the insecticide was estimated using LC-MS/MS. Initial residues of chlorantraniliprole at single and double doses on the fruits of brinjal were 0.72 and 1.48 mg kg?1, while on okra fruits, the residues were 0.48 and 0.91 mg kg?1, respectively. The residues reached below detectable level of 0.01 mg kg?1 on the 10th day. Half-life of chlorantraniliprole at 30 and 60 g ai ha?1 on brinjal was 1.58 and 1.80 days with the calculated waiting period of 0.69 and 2.38 days, whereas on okra, the values were 1.60 and 1.70 and 0 and 1.20 days, respectively. The extent of removal of chlorantraniliprole using simple decontaminating techniques at 2 h and 3 days after spraying was 40.99–91.37 % and 29.85–89.12 %, respectively, from brinjal fruits and 47.78–86.10 % and 41.77–86.48 %, respectively, from okra fruits. 相似文献
987.
The dynamic and residues of florasulam and flumetsulam in corn field ecosystem were investigated using quick, easy, cheap, effective, rugged, and safe (QuEChERS) procedure with high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS). The limits of quantification (LOQs) of the proposed method ranged from 0.005 to 0.01 mg/kg. Mean recoveries and relative standard deviations (RSDs) of the two compounds in all samples at three spiking levels ranged 94–110 % and 2.0–9.2 %, respectively. Florasulam and flumetsulam degradation followed first-order kinetics with half-lives 1.7–2.9 and 3.3–8.7 days in soil and 1.3–1.8 and 0.9–1.7 days in plant, respectively. The residues in all the samples were found to be less than the LOQs at preharvest intervals of 53 and 78 days. The results suggest that the combined use of florasulam and flumetsulam on corn is considered to be safe under the recommended conditions and can be utilized for establishing the maximum residue limit (MRL) of florasulam in corn in China. 相似文献
988.
Claudia Pahl-Wostl Christoph Schlumpf Martin Büssenschütt Andreas Schönborn Jan Burse 《Integrated Assessment》2000,1(4):267-280
Within the CLEAR project a new approach to integrated assessment modelling has been developed for the participatory integrated
assessment of regional climate change involving citizens' focus groups. The climate change decision problem was structured
by focusing separately on climate impacts and mitigation options. The attempt was made to link the different scales of the
problem from the individual to the global level. The abstract topic of climate change was related to options on the level
of a citizen's individual lifestyle. The option of a low energy society was emphasised in order to embed the climate change
decision problem in a wider range of societal concerns. Special emphasis was given to the characterisation and communication
of uncertainties. The chosen approach allows different kinds of uncertainties in one framework to be addressed. The paper
concludes with a summary of the experience made, and recommendations for the use of models in participatory integrated assessments.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
989.
Past changes and possible future variations in the nature of extreme precipitation and flood events in Central Europe and
the Alpine region are examined from a physical standpoint. An overview is given of the following key contributory physical
processes: (1) the variability of the large-scale atmospheric flow and the associated changes of the North-Atlantic storm
track; (2) the feedback process between climate warming and the water cycle, and in particular the potential for more frequent
heavy precipitation events; and (3) the catchment-scale hydrological processes associated with variations in major river flooding
events and that are related to land-use changes, river training measures, and shifts in the proportion of rain to snowfall.
In this context an account is provided of the possible future forecasting and warning methodologies based upon high-resolution
weather prediction and runoff models. Also consideration is given to the detectability of past (future) changes in observed
(modeled) extreme events. It is shown that their rarity and natural fluctuation largely impedes a detection of systematic
variations. These effects restrict trend analysis of such events to return periods of below a few months. An illustration
using daily precipitation from the Swiss Alps does yield evidence for pronounced trends of intense precipitation events (return
period 30 days), while trends of stronger event classes are not detectable (but nevertheless can not be excluded). The small
detection probability for extreme events limits possible mitigation of future damage costs through an abatement of climate
change alone, and points to the desirability of developing improved early forecasting/warning systems as an additional no-regret
strategy.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
990.
Maria P. Papadopoulou Emmanouil A. Varouchakis George P. Karatzas 《Environmental Modeling and Assessment》2010,15(5):319-328
Karst aquifers are characterized by spatial heterogeneity due to the presence of highly permeable channels and conduits in
low-permeable fractured rocks (matrix block). Recent studies have reported a close relationship between surface and subsurface
water in karstic regions due to the water flow through a complicated network of paths formed by fracture intersections. Subsurface
flow in karstified aquifers ranges between conduit flow, in large passages with relatively high flow velocities, and diffuse
flow, in the matrix block where Darcy’s law is still valid. In this paper, we present the simulation of a complex karstified
aquifer system in Crete, Greece, where the presence of main faults drastically affects the regional flow. A discrete fracture
approach in conjunction with an equivalent porous medium approach was adopted to simulate the mixed flow in the area of interest.
The simulation results have shown that the length and the orientation of the dominant faults, primarily during the rainy season,
affect the flow field. 相似文献