特殊工况下船舶生活污水处理的试验研究

采用厌氧复合床反应器与接触氧化、接触沉淀相结合的工艺,针对实船条件下可能出现的重启动、倾斜、海水及淡水海水交替冲洗厕所和水力负荷增加等情况,进行了特殊工况下船舶生活污水处理的试验研究。结果表明,该组合工艺在设计条件下（HRT为5h）重启动速度较快,可用于海水冲厕所产生的高盐度污水处理,耐受淡水海水交替变化的盐度冲击负荷变化能力较强,具有一定的水力负荷增加潜力,并且不受倾斜影响。     

草皮缓冲带对洱海流域面源污染的削减效果

在前期植物调查和资料调研的基础上,构建了以百慕大、结缕草、混播草草皮为陆生植物的缓冲带,以洱海流域面源污染水样为这些植被缓冲带的进水,进行削减效果的现场中试实验。结果表明,裸露地表对径流SS几乎没有削减效果,而草皮缓冲带能有效截留径流SS,去除率大小顺序为混播草缓冲带> 结缕草缓冲带> 百慕大缓冲带;草皮缓冲带渗流水中的TN、TP的去除率均在60%以上,而径流水中TN、TP的去除率在40%以上;总体而言,草皮缓冲带对面源污染的削减效果沿程增强,且前段去除效果较强,后段去除效果减弱,其中混播草缓冲带的削减效果最好,百慕大缓冲带的削减效果相对较差;通过计算,当SS去除率为70%时,混播草缓冲带的最佳宽度仅为13.4 m,比百慕大缓冲带缩短了5.2 m。     

碳基材料对污水厂尾水和太湖水体中CDOM的吸附特征

采用颗粒活性炭、粉末活性炭和碳纳米管3种典型碳基材料来吸附太湖水和污水厂尾水中的有机物,考察碳基材料对水中有色可溶性有机物(CDOM)的吸附特征。基于荧光光谱和平行因子分析(PARAFAC),提取出C1(腐殖酸类)、C2(色氨酸类蛋白)和C3(酪氨酸类蛋白)3个PARAFAC荧光组分。粉末活性炭和碳纳米管具有发达的中孔孔隙结构,对水中大分子有机物具有较高的吸附容量,颗粒活性炭微孔结构发达反而不利于吸附水中腐殖酸等大分子有机物。粉末活性炭对水中有机物具有最高的吸附速率,对太湖水中荧光组分C1、C2和C3 的吸附速率分别为0.278、0.358和0.359 min-1,颗粒活性炭的吸附速率明显低于粉末活性炭和碳纳米管。研究结果揭示了水中复杂混合有机物的吸附特征,为吸附工艺参数的优化提供技术参考。     

Phthalic acid esters (PAEs) in workplace and house dust from Vietnam: concentrations,profiles, emission sources,and exposure risk

Environmental Science and Pollution Research - The occurrence of nine phthalic acid esters (PAEs) were determined in indoor dust samples collected from vehicle repair shops, waste processing...     

Chlorination of dibenzofuran and dibenzo-p-dioxin vapor by copper (II) chloride

Dibenzofuran (DF) is formed from phenol and benzene in combustion gas exhaust streams prior to particle collection equipment. Subsequent chlorination at lower temperatures on particle surfaces is a potential source of chlorinated dibenzofuran (CDF). Gas streams containing 8% O₂ and approximately 0.1% DF vapor were passed through particle beds containing copper (II) chloride (0.5% Cu, mass) at temperatures ranging from 200 to 400 °C to investigate the potential for CDF formation during particle collection. Experiment duration was sufficient to provide an excess amount of DF (DF/Cu=3). The efficiency of DF chlorination by CuCl₂ and the distribution of CDF products were measured, with effects of temperature, gas velocity, and experiment duration assessed. Results of a more limited investigation of dibenzo-p-dioxin (DD) chlorination by CuCl₂ to form chlorinated DD (CDD) products are also presented.The efficiency of DF/DD chlorination by CuCl₂ was high, both in terms of CuCl₂ utilization and DF/DD conversion. Total yields of Cl on CDF/CDD products of up to 0.5 mole Cl per mole CuCl₂ were observed between 200 and 300 °C; this suggests that nearly 100% CuCl₂ was utilized, assuming a conversion of two moles of CuCl₂ to CuCl per mole Cl added to DD/DF. In a short duration experiment (DF/Cu=0.3), nearly 100% DF adsorption and conversion to CDF was achieved. The degree of CDF chlorination was strongly dependent on gas velocity. At high gas velocity, corresponding to a gas–particle contact time of 0.3 s, mono-CDF (MCDF) yield was largest, with yields decreasing with increasing CDF chlorination. At low gas velocity, corresponding to a gas–particle contact time of 5 s, octa-CDF yield was largest. DF/DD chlorination was strongly favored at lateral sites, with the predominant CDF/CDD isomers within each homologue group those containing Cl substituents at only the 2,3,7,8 positions. At the higher temperatures and lower gas velocities studied, however, broader isomer distributions, particularly of the less CDD/CDF products, were observed, likely due to preferential destruction of the 2,3,7,8 congeners.     

Analysis and structure prediction of chlorinated polycyclic aromatic hydrocarbons released from combustion of polyvinylchloride

Chlorinated polycyclic aromatic hydrocarbons (Cl-PAHs) released from combustion of polyvinylchloride (PVC) at different furnace temperatures were investigated. A laboratory-scale tube-type furnace with electric heating was utilized to control combustion conditions. Glass fabric filters and adsorbents were used to collect the combustion emissions. Following Soxhlet extraction, concentration and column chromatography purification, isomers separation, selective detection and identification of Cl-PAHs were performed on GC/MS system on the basis of retention data and mass spectra. Their quantification was accomplished by using external standard calibration technique. About 18 Cl-PAHs were determined, most of which were monochlorinated derivatives of naphthalene, biphenyl, fluorene, phenanthrene, anthracene, fluoranthene and pyrene. Only two dichlorophenanthrenes or anthracenes were identified. The possible positions of chlorine atoms attached to the aromatic rings are predicted by quantitative structure-property relationship. The levels of these compounds were in the range of 0.30-29.08 microg/g PVC. The relationship between the formation of Cl-PAHs and PAHs was discussed.     

古尔班通古特沙漠边缘生态环境建设策略

沙漠古已有之,近期由于开发的需要,人为造成的沙漠扩张明显超过历史时期,沙漠化与人类干扰的加剧有直接关系。在荒漠区的开发及其生态环境建设过程中,应深入了解荒漠区的环境现状,充分利用该区的自然环境条件,改造沙漠,实施保护、利用与建设相结合的方针,以荒漠植被自然侵移规律为依据,依靠自然降水,以最大限度人工发展可供饲用的灌林,实现荒漠生态环境建设的目的     

Spatial Organization Mechanism of Aircraft Manufacturing

Unquestionably, aircraft industry plays an important part in both economy and security of a nation. However, few of articles have dealt with the spatial development of this industry sector. The purpose of this article is to analyze the dynamics of agglomeration and diffusion of aircraft industry.In a historical view, with some spatial analysis methods, this research discusses the characteristics and patterns of aircraft industry's spatial organization and evolution, globally, nationally and regionally respectively. We find out there is a 'Matthew effect' in aircraft industry of the world, and the spatial evolution of the industry is consistent with the nation's industrialization process. Then, it concludes that the main agglomeration forces consist of capital, talents, technology and cluster's advantages, and the main diffusion forces include comparative advantages, cost and risk sharing, emerging markets, development policy for backward regions and military requirements. All the factors can be divided into market forces making the spatial development of aircraft industry normal and non-market forces making that irregular. In particular, lessons from the USA and France are expected to be conducive to the rise of China's aircraft industry in the future.     

低温条件下生态槽深度处理农村生活污水的日变化特性

针对农村生活污水处理设施出水水质偏高污染环境的现状,构建了以水生植物为主体的生态槽深度处理农村生活污水,研究了低温条件下生态槽深度处理生活污水过程中DO、pH、COD、NH4+-N、TP等指标的日变化特性。结果表明,生活污水COD为37.67～60.23 mg/L、NH4+-N为13.66～16.76 mg/L、TP为1.32～1.78 mg/L、水温为9～11℃,HRT为5 d时,生态槽出水COD、NH4+-N和TP平均为21.07 mg/L、0.99 mg/L和0.19 mg/L,均可达《地表水环境质量标准》(GB3838-2002)之Ⅳ类水标准。各级生态槽内DO浓度夜间低于昼间。夜间植物对NH4+-N和TP具有较强的吸收作用,平均去除率分别达94.83%和89.87%;而TN去除效果稍差,平均去除率为59.9%。     

CeO_x/AC催化剂NH_3选择性催化还原NO

以用不同浓度的HNO3预处理后的椰壳活性炭为载体,负载铈制备SCR催化剂。利用比表面积分析仪（BET）、X射线衍射（XRD）、扫描电镜（SEM）和催化剂活性实验,探讨了不同变量如金属离子的分布、焙烧温度和载体属性对催化活性的影响。结果表明,HNO3处理后,经500℃焙烧金属铈负载量为7%的催化剂表现出优良的催化性能。在90℃时,NO转化率在90%以上,随温度升高,达到接近100%的NO转化率。