This study describes a novel electrochemical method to determine the herbicide trifluralin in samples of water, fruit juice, and vegetable extracts in the presence of surfactants, using a glassy carbon electrode (GCE). In acidic media, trifluralin was irreversible on the glassy carbon electrode surface at ?0.5 V vs. Ag/AgCl. Surfactant presence on the electrode–solution interface modified current intensities and shifted the reduction peak potential of trifluralin. Different types of surfactant and their concentrations were investigated. The anionic surfactant significantly enhanced the peak current intensity of trifluralin. Under optimal analytical conditions, an analytical curve was obtained in the concentration range of 0.48–32.20 µM. The limits of detection and quantification were estimated at 0.031 and 0.104 µM, respectively. The method was successfully applied to quantify trifluralin in samples of water, orange and tomato juice, and green pepper, carrot, and onion extracts, with recovery rates of 97.9–102.1%. The results were in good agreement with those obtained using high-performance liquid chromatography, indicating that the proposed electrochemical method can be employed to quantify trifluralin in various types foods, with sensitivity, specificity, selectivity and reproducibility. 相似文献
Environmental Science and Pollution Research - In the current study, water quality of five river sites in Parana River basin (Brazil), utilized for public water supply, was assessed through a set... 相似文献
Environmental Science and Pollution Research - This study investigates the dynamic linkage among foreign direct investment, energy consumption, and environmental pollution of China spanning from... 相似文献
Environmental Science and Pollution Research - This study employs super-efficiency DEA model with desirable inputs and an undesirable output in calculating environmental efficiency values in... 相似文献
The impact of the sulfur (S) content in lubricating oil was evaluated for four ultra-low-emission vehicles and two super-ultra-low-emission vehicles, all with low mileage. The S content in the lube oils ranged from 0.01 to 0.76%, while the S content of the gasoline was fixed at 0.2 ppmw. Vehicles were configured with aged catalysts and tested over the Federal Test Procedure, at idle and at 50-mph cruise conditions. In all testing modes, variations in the S level of the lubricant did not significantly affect the regulated gas-phase tailpipe emissions. In addition to the regulated gas-phase emissions, a key element of the research was measuring the engine-out sulfur dioxide (SO2) in near-real-time. This research used a new methodology based on a differential optical absorption spectrometer (DOAS) to measure SO2 from the lubricants used in this study. With the DOAS, the contribution of SO2 emissions for the highest-S lubricant was found to range from less than 1 to 6 ppm on a gasoline S equivalent basis over the range of vehicles and test cycles used. The development and operation of the DOAS is discussed in this paper. 相似文献
The two UV screens 3-benzylidene-camphor (3-BC) and 3-(4'-methylbenzylidene)-camphor (4-MBC) were tested regarding their toxicity and estrogenic activity. The Yeast Estrogen Screen (YES) and two sediment assays with the freshwater invertebrates Lumbriculus variegatus and Potamopyrgus antipodarum were performed. In the YES, both substances activated the human estrogen receptor alpha with EC50 values of 44.2 microM for 3-BC and 44.3 microM for 4-MBC, whereby 4-MBC attained only 8% of the maximal response of 17beta-estradiol. For P. antipodarum embryo production increased after exposure to both substances (EC50 of 4.60 microM 4-MBC=1.17 mg kg(-1)dw) while mortality increased at high concentrations. The reproduction of L. variegatus was decreased by 3-BC with an EC50 of 5.95 microM (=1.43 mg kg(-1)dw) and also by 4-MBC, where no EC50 could be calculated. While reproduction decreased, the worms' weight increased after exposure to 3-BC with an EC50 of 26.9 microM (=6.46 mg kg(-1) dw), hence the total biomass remained unaffected. 相似文献
The recent increase in European temperatures led to a strong enhancement in the occurrence of extremely warm events, with relevant consequences for environment and everyday life. Here, we investigate the evolution of very intense warm and cold events in a south-western European zone during 1961–2007 at a seasonal level. Special attention is given to summertime when warming is the most pronounced. Using a previously developed theoretical model, we discuss how the average properties and long-term trends observed in probability density functions of daily temperatures can explain changes in the frequency of severe, isolated events. In this perspective, the recent intensification of extremely warm events, especially experienced by the Mediterranean zone, is proved to be well consistent with a pure shift of seasonal mean temperatures. On the other hand, any change in the second and higher distributional moments of daily temperatures is ruled out by the data, whereas the average values of these properties, that is, variability and asymmetry, do play a role by shaping the temporal behavior of very intense events. 相似文献
A southern Italian area that is characterized by large outcrops of rocks that are rich in titanium oxide (TiO2) phases were investigated to determine the mineralogical risk induced by the natural dispersion of TiO2 minerals. Rock, sediment and surface water samples were collected to determine the physicochemical and mineralogical factors (i.e., size distribution, morphology and alteration) indicative of potential TiO2 toxicity. X-ray diffraction data suggested that titanium oxides were present as rutile and anatase. Scanning electron microscopy images showed elongated TiO2 morphologies; fibres were found as either isolated or embedded/enclosed in flake-like phyllosilicates. The concentration of fibres in stream water ranged from 1.7 to 4.6 million fibres per litre. The highest fibre amounts in the sediments were in the <8-µm fraction, while single fibres were primarily concentrated in the <2-µm fraction. The results indicate that titanium oxide minerals represent a natural source of environmental risk and that the geomineralogical characterization of rich TiO2 areas is indispensable for understanding their geoavailability, dispersion and distribution.
- DOI: http://dx.doi.org/10.1065/espr2006.01.009
Background, Aims and Scope Most existing models used to describe the fate of chemicals in surface water and sediment generally consider a 'static scenario',
in which a contaminant is discharged at a constant rate and environmental input parameters do not change during the simulation
time. This approach is not suitable in environmental scenarios characterized by daily or periodic changes of several input
parameters. The aim of this study is to estimate approximate emissions of DDT lo Lake Maggiore using a new surface water model,
(DynA Model) that describes the fate of a chemical in a dynamic scenario.
Methods The model is developed on the grounds of an existing and validated model (QWASI). A numerical solution was adopted to build
the fully dynamic version of the model.
Results and Discussion The model was applied to Lake Maggiore emitting DDT at a constant rate until steady-state was reached. Emissions were stopped
and later sporadic 'pulse' emissions were added. This was done to calculate the amount of DDT needed to simulate concentrations
close to those measured in water and sediments. This allowed the evaluation of the order of magnitude of emissions. An uncertainty
analysis for sediment resuspension was also performed, given the lack of measured resuspension rates.
Conclusion The model showed the time response of the Lake Maggiore system to varying emission scenarios and provided what are regarded
as reasonable estimates of DDT emissions. The model demonstrated the importance of sediment-water exchange.
Recommendation and Outlook In order to better calculate DDT concentrations the model should be run with different discharge scenarios to clarify the
time trends of concentrations, possibly with the use of different sets of measured data (such as biota and sediment deposition/resuspension
rates). 相似文献
Hydropower developments along the main stem of the Mekong River and its tributaries cause transboundary effects within the Mekong Basin Region, which comprises parts of six countries. On the one hand, the provision of hydropower triggers economic development and helps to meet the rising energy demand of the Mekong riparian countries, especially China, Thailand, and Vietnam. On the other hand, the negative impact of dam construction, mainly altered water flow and sediment load, has severe impacts on the environment and the livelihoods of the rural Mekong population. Several discrepancies exist in the needs, demands, and challenges of upstream versus downstream countries. Against the common apprehension that downstream countries are powerlessly exposed to mainly negative impacts whereas upstream countries unilaterally benefit from hydropower, the authors argue that upstream–downstream relations are not really clear-cut. This conclusion is based on a consideration of the complex power play between Mekong riparians, with a focus on recent power trade interactions. The article investigates the consequences of hydropower dams for the Mekong region as well as the role of supranational players, such as the Mekong River Commission and the Greater Mekong Subregion Initiative, on the hydropower debate. It is not nations that are the winners or losers in the hydropower schemes in the Mekong, but rather parts of the riparian population: a few influential and powerful elites versus the large mass of rural poor. 相似文献