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151.
María Luisa González De Canales Milagrosa Oliva Carmen Garrido 《Journal of environmental science and health. Part. B》2013,48(2):95-105
The purpose of the present study was to research the sublethal and/or lethal effects produced by the exposure of fish and shellfish to the γ isomer of lindane, γ-hexachlorocyclohexane (γ-HCH). The teleostean fish Sparus aurata and the shellfish Crassostrea angulata and Scrobicularia plana, were exposed to 16 μ g/L of lindane for 15 days. Samples of different fish (liver, kidney and gills) and shellfish (gills, gut, digestive gland and mantle) tissues were extracted and processed for histopathological observations. Although mortality was not detected during the bioassay, sublethal effects (histopathological alterations) were observed. Vacuolization in the liver cells and lamellar fusion in gills from exposed fish were observed. Disorganization of normal gill structure, epithelial desquamation with the disappearance of apical ciliature in intestine, and inflammatory response in mantle from exposed shellfish were also observed. Thus, it can be concluded that the lindane concentration employed in the present research did not produce lethal effects in the exposed organisms but it caused sublethal effects. Lindane has time-dependent multiple toxic effects in S. aurata, C. angulata and S. plana, which were more severe at the end of the experimental time. The toxicological implications arising from these results are subjects for further multiconcentration tests dealing with lethal responses (mortality) or with sublethal responses (cellular/molecular biomarkers) of the aforementioned species. 相似文献
152.
E. Manuela Garrido Marcos Santos Paulo Silva Fernando Cagide Jorge Garrido Fernanda Borges 《Journal of environmental science and health. Part. B》2013,48(9):869-875
The chlorophenoxy herbicide MCPA (4-chloro-2-methylphenoxyacetic acid), widely used for the control of broad-leaf weeds primarily in cereal and grass seed crops, still remains one of the most often used herbicides in Portugal. As the formation of inclusion complexes with cyclodextrins can improve its solubility properties, the interaction between the herbicide MCPA and β-cyclodextrin was investigated. The stability constants describing the extent of formation of the complexes have been determined by phase-solubility studies. Different analytical techniques [ultraviolet-visible spectroscopy (UV-Vis), differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR), proton nuclear magnetic resonance spectroscopy (1H NMR)] were employed for a thorough investigation of the structural characteristics of the obtained complexes, which exhibited distinct features and properties from both “guest” and “host” molecules. FTIR and 1H NMR data obtained for the MCPA/β-CD complexes gave information about the interaction between MCPA and the nonpolar cyclodextrin cavity. The dramatic change observed in band frequency and proton displacements of OCH2 group and H6 aromatic proton confirmed the inclusion of MCPA in β-CD. The formation of an inclusion complex between MCPA and β-CD increased the aqueous solubility of this herbicide which could be a particularly advantageous property for some specific applications, namely to improve commercial formulation and for environmental protection. 相似文献
153.
Antonella Maccotta Claudio De Pasquale Antonio Caruso Claudia Cosentino Giuseppe Alonzo Pellegrino Conte 《Environmental science and pollution research international》2013,20(7):4847-4858
The present study deals with the reconstruction of the environmental evolution of a Trapani saltmarsh (southwestern Sicily, Italy) by combining different analytical approaches such as metal content evaluation, low-field nuclear magnetic resonance (NMR) relaxometry, and benthic foraminifera identification. A 41 cm core was collected in the sediments of a Trapani saltmarsh (southwestern Sicily, Italy) at a water depth of about 50 cm. Different time intervals were recognized, each characterized by peculiar features that testify different environmental conditions. In particular, the bottom layers of the sediment core (41–28 cm) comprised the lowest amount of mud fraction, only some selected metals, and the lowest foraminiferal density. Here, co-occurrence of abundant microcrystals of gypsum and Ammonia tepida is indicative of hyper-saline conditions. In the sediments from 28 to 6 cm, mud fraction and number of metal elements resulted higher due to the increase of the anthropogenic pressure. The sediments in the last time interval, corresponding to the environmental recovery of the saltmarsh, showed an increase of foraminiferal density, a decrease of the mud fraction, and a trend in the metal concentration attributable to the protection policy applied since 1990. NMR relaxometry parameters highlighted the changes of sediment chemical–physical heterogeneity going from the bottom to the top of the core. These heterogeneities have been related to the different intervals recognized as aforementioned. The present study highlights how the anthropogenic pressure modifies the environmental conditions of a transitional ecosystem like saltmarshes. 相似文献
154.
155.
Claudia Cocozza Domenico Vitullo Giuseppe Lima Lucia Maiuro Marco Marchetti Roberto Tognetti 《Environmental science and pollution research international》2014,21(3):1796-1808
The plant–microorganism combinations may contribute to the success of phytoextraction of heavy metal-polluted soil. The purpose of this study was to investigate the effects of cadmium (Cd) soil concentration on selected physiological parameters of the poplar clone “I-214” inoculated at root level with a strain (BT4) of Pseudomonas fluorescens and a commercial product based on microbial consortia (Micosat F Fito®). Plants were subjected to Cd treatment of 40 mg kg?1 in greenhouse. The effects of plant–microbe interactions, plant growth, leaf physiology, and microbial activity were periodically monitored. Metal concentration and translocation factors in plant tissues proved enhanced Cd uptake in roots of plants inoculated with P. fluorescens and transfer to shoots in plants inoculated with Micosat F Fito®, suggesting a promising strategy for using microbes in support of Cd uptake. Plant–microbe integration increased total removal of Cd, without interfering with plant growth, while improving the photosynthetic capacity. Two major mechanisms of metal phytoextraction inducted by microbial inoculation may be suggested: improved Cd accumulation in roots inoculated with P. fluorescens, implying phytostabilization prospective and high Cd transfer to shoots of inoculated plants, outlining enhanced metal translocation. 相似文献
156.
Mirco Hecht Bernadette Oehen Jürg Schulze Peter Brodmann Claudia Bagutti 《Environmental science and pollution research international》2014,21(2):1455-1465
To obtain a reference status prior to cultivation of genetically modified oilseed rape (OSR, Brassica napus L.) in Switzerland, the occurrence of feral OSR was monitored along transportation routes and at processing sites. The focus was set on the detection of (transgenic) OSR along railway lines from the Swiss borders with Italy and France to the respective oilseed processing factories in Southern and Northern Switzerland (Ticino and region of Basel). A monitoring concept was developed to identify sites of largest risk of escape of genetically modified plants into the environment in Switzerland. Transport spillage of OSR seeds from railway goods cars particularly at risk hot spots such as switch yards and (un)loading points but also incidental and continuous spillage were considered. All OSR plants, including their hybridization partners which were collected at the respective monitoring sites were analyzed for the presence of transgenes by real-time PCR. On sampling lengths each of 4.2 and 5.7 km, respectively, 461 and 1,574 plants were sampled in Ticino and the region of Basel. OSR plants were found most frequently along the routes to the oilseed facilities, and in larger amounts on risk hot spots compared to sites of random sampling. At three locations in both monitored regions, transgenic B. napus line GT73 carrying the glyphosate resistance transgenes gox and CP4 epsps were detected (Ticino, 22 plants; in the region of Basel, 159). 相似文献
157.
Claudia Pittiglio Andrew K. Skidmore Hein A. M. J. van Gils Michael K. McCall Herbert H. T. Prins 《Ambio》2014,43(2):149-161
Crop-raiding elephants affect local livelihoods, undermining conservation efforts. Yet, crop-raiding patterns are poorly understood, making prediction and protection difficult. We hypothesized that raiding elephants use corridors between daytime refuges and farmland. Elephant counts, crop-raiding records, household surveys, Bayesian expert system, and least-cost path simulation were used to predict four alternative categories of daily corridors: (1) footpaths, (2) dry river beds, (3) stepping stones along scattered small farms, and (4) trajectories of shortest distance to refuges. The corridor alignments were compared in terms of their minimum cumulative resistance to elephant movement and related to crop-raiding zones quantified by a kernel density function. The “stepping stone” corridors predicted the crop-raiding patterns. Elephant presence was confirmed along these corridors, demonstrating that small farms located between refuges and contiguous farmland increase habitat connectivity for elephant. Our analysis successfully predicted elephant occurrence in farmland where daytime counts failed to detect nocturnal presence. These results have conservation management implications. 相似文献
158.
Claudia Simolo Michele Brunetti Maurizio Maugeri Teresa Nanni 《Regional Environmental Change》2014,14(5):1825-1832
The recent increase in European temperatures led to a strong enhancement in the occurrence of extremely warm events, with relevant consequences for environment and everyday life. Here, we investigate the evolution of very intense warm and cold events in a south-western European zone during 1961–2007 at a seasonal level. Special attention is given to summertime when warming is the most pronounced. Using a previously developed theoretical model, we discuss how the average properties and long-term trends observed in probability density functions of daily temperatures can explain changes in the frequency of severe, isolated events. In this perspective, the recent intensification of extremely warm events, especially experienced by the Mediterranean zone, is proved to be well consistent with a pure shift of seasonal mean temperatures. On the other hand, any change in the second and higher distributional moments of daily temperatures is ruled out by the data, whereas the average values of these properties, that is, variability and asymmetry, do play a role by shaping the temporal behavior of very intense events. 相似文献
159.
Jose Ruben Campos-Gaytan Thomas Kretzschmar Claudia Soledad Herrera-Oliva 《Environmental monitoring and assessment》2014,186(11):7961-7985
Semiarid northwestern Mexico presents a growing water demand produced by agricultural and domestic requirements during the last two decades. The community of Guadalupe Valley and the city of Ensenada rely on groundwater pumping from the local aquifer as its sole source of water supply. This dependency has resulted in an imbalance between groundwater pumpage and natural recharge. A two-dimensional groundwater flow model was applied to the Guadalupe Valley Aquifer, which was calibrated and validated for the period 1984–2005. The model analysis verified that groundwater levels in the region are subject to steep declines due to decades of intensive groundwater exploitation for agricultural and domestic purposes. The calibrated model was used to assess the effects of different water management scenarios for the period 2007–2025. If the base case (status quo) scenario continues, groundwater levels are in a continuous drawdown trend. Some wells would run dry by August 2017, and water demand may not be met without incurring in an overdraft. The optimistic scenario implies the achievement of the mean groundwater recharge and discharge. Groundwater level depletion could be stopped and restored. The sustainable scenario implies the reduction of current extraction (up to about 50 %), when groundwater level depletion could be stopped. A reduction in current extraction mitigates water stress in the aquifer but cannot solely reverse declining water tables across the region. The combination of reduced current extraction and an implemented alternative solution (such as groundwater artificial recharge), provides the most effective measure to stabilize and reverse declining groundwater levels while meeting water demands in the region. 相似文献
160.
Schmitt C Oetken M Dittberner O Wagner M Oehlmann J 《Environmental pollution (Barking, Essex : 1987)》2008,152(2):322-329
The two UV screens 3-benzylidene-camphor (3-BC) and 3-(4'-methylbenzylidene)-camphor (4-MBC) were tested regarding their toxicity and estrogenic activity. The Yeast Estrogen Screen (YES) and two sediment assays with the freshwater invertebrates Lumbriculus variegatus and Potamopyrgus antipodarum were performed. In the YES, both substances activated the human estrogen receptor alpha with EC50 values of 44.2 microM for 3-BC and 44.3 microM for 4-MBC, whereby 4-MBC attained only 8% of the maximal response of 17beta-estradiol. For P. antipodarum embryo production increased after exposure to both substances (EC50 of 4.60 microM 4-MBC=1.17 mg kg(-1)dw) while mortality increased at high concentrations. The reproduction of L. variegatus was decreased by 3-BC with an EC50 of 5.95 microM (=1.43 mg kg(-1)dw) and also by 4-MBC, where no EC50 could be calculated. While reproduction decreased, the worms' weight increased after exposure to 3-BC with an EC50 of 26.9 microM (=6.46 mg kg(-1) dw), hence the total biomass remained unaffected. 相似文献