The importance of age-related decline in forest NPP for modeling regional carbon balances.

We show the implications of the commonly observed age-related decline in aboveground productivity of forests, and hence forest age structure, on the carbon dynamics of European forests in response to historical changes in environmental conditions. Size-dependent carbon allocation in trees to counteract increasing hydraulic resistance with tree height has been hypothesized to be responsible for this decline. Incorporated into a global terrestrial biosphere model (the Lund-Potsdam-Jena model, LPJ), this hypothesis improves the simulated increase in biomass with stand age. Application of the advanced model, including a generic representation of forest management in even-aged stands, for 77 European provinces shows that model-based estimates of biomass development with age compare favorably with inventory-based estimates for different tree species. Model estimates of biomass densities on province and country levels, and trends in growth increment along an annual mean temperature gradient are in broad agreement with inventory data. However, the level of agreement between modeled and inventory-based estimates varies markedly between countries and provinces. The model is able to reproduce the present-day age structure of forests and the ratio of biomass removals to increment on a European scale based on observed changes in climate, atmospheric CO2 concentration, forest area, and wood demand between 1948 and 2000. Vegetation in European forests is modeled to sequester carbon at a rate of 100 Tg C/yr, which corresponds well to forest inventory-based estimates.     

How Do River Nitrate Concentrations Respond to Changes in Land-use? A Modelling Case Study of Headwaters in the River Derwent Catchment,North Yorkshire,UK

A combined semi-distributed hydrological model (CASCADE/QUESTOR) is used to evaluate the steady-state that may be achieved after changes in land-use or management and to explore what additional factors need to be considered in representing catchment processes. Two rural headwater catchments of the River Derwent (North Yorkshire, UK) were studied where significant change in land-use occurred in the 1990s and the early 2000s. Much larger increases in mean nitrate concentration (55%) were observed in the catchment with significant groundwater influence (Pickering Beck) compared with the surface water-dominated catchment (13% increase). The increases in Pickering Beck were considerably greater than could be explained by the model in terms of land-use change. Consequently, the study serves to focus attention on the long-term increases in nitrate concentration reported in major UK aquifers and the ongoing and chronic impact this trend is likely to be having on surface water concentrations. For river environments, where groundwater is a source, such trends will mask the impact of measures proposed to reduce the risk of nitrate leaching from agricultural land. Model estimates of within-channel losses account for 15–40% of nitrate entering rivers.     

Acid soil indicators in forest soils of the Cherry River Watershed, West Virginia

Declining forest health has been observed during the past several decades in several areas of the eastern USA, and some of this decline is attributed to acid deposition. Decreases in soil pH and increases in soil acidity are indicators of potential impacts on tree growth due to acid inputs and Al toxicity. The Cherry River watershed, which lies within the Monongahela National Forest in West Virginia, has some of the highest rates of acid deposition in Appalachia. East and West areas within the watershed, which showed differences in precipitation, stream chemistry, and vegetation composition, were compared to evaluate soil acidity conditions and to assess their degree of risk on tree growth. Thirty-one soil pits in the West area and 36 pits in the East area were dug and described, and soil samples from each horizon were analyzed for chemical parameters. In A horizons, East area soils averaged 3.7 pH with 9.4 cmol_c kg^???1 of acidity compared to pH 4.0 and 6.2 cmol_c kg^???1 of acidity in West area soils. Extractable cations (Ca, Mg, and Al) were significantly higher in the A, transition, and upper B horizons of East versus West soils. However, even with differences in cation concentrations, Ca/Al molar ratios were similar for East and West soils. For both sites using the Ca/Al ratio, a 50% risk of impaired tree growth was found for A horizons, while a 75% risk was found for deeper horizons. Low concentrations of base cations and high extractable Al in these soils translate into a high degree of risk for forest regeneration and tree growth after conventional tree harvesting.     

The distribution and composition of hydrocarbons in sediments from the Fladen Ground, North Sea, an area of oil production

The distribution and composition of hydrocarbons in sediment from the Fladen Ground oilfield in the northern North Sea have been investigated. The total PAH concentrations (2- to 6-ring parent and alkylated PAHs, including the 16 US EPA PAHs) in sediments were relatively low (<100 microg kg(-1) dry weight). The PAH, the Forties crude and diesel oil equivalent concentrations were generally higher in sediment of fine grain size and higher organic carbon concentration. PAH distributions and concentration ratios indicated a predominantly pyrolytic input, being dominated by the heavier, more persistent, 5- and 6-ring compounds, and with a high proportion of parent PAHs. The n-alkane profiles of a number of the sediments contained small, high boiling point, UCMs, indicative of weathered oil arising from a limited petrogenic input. The geochemical biomarker profiles of the sediments that contained UCMs showed a small bisnorhopane peak and a high proportion of norhopane relative to hopane, indicating that there was contamination from both Middle Eastern and North Sea oils. Therefore contamination was not directly as a result of oil exploration activity in the area. The most likely source of petrogenic contamination was from general shipping activity.     

Passive sampling: partition coefficients for a silicone rubber reference phase

Silicone rubber sheeting can be used as a passive sampling device for hydrophobic organic contaminants in the environment to determine the available concentrations in water and sediments. Reliable sampler-water partition coefficients are required to determine the sampling rates and the dissolved contaminant concentrations in water and in sediment pore water. Log partition coefficients (logK(sr,w)) for silicone rubber-water have been estimated for 32 polycyclic aromatic hydrocarbons (PAHs), 2 deuterated PAH analogues and 32 chlorobiphenyls (CBs) using the cosolvent method, with methanol as cosolvent. Strong linear relationships were found with literature values for the corresponding log octanol-water partition coefficients (logK(ow)) for both CBs and PAHs, confirming that partitioning into the silicone rubber is strongly determined by the hydrophobicity of the compounds, which suggests logK(ow) is a good predictor of logK(sr,w) and that absorption is the main mechanism for accumulation of analytes into the silicone rubber polymer.     

EFFECTS OF FOREST FERTILIZATION ON STREAM WATER CHEMISTRY IN THE APPALACHIANS1

ABSTRACT: Stream water chemistry was monitored on two watersheds on the Fernow Experimental Forest in north-central West Virginia to determine the effects of forest fertilization on annual nutrient exports. Ammonium nitrate and triple superphosphate were applied simultaneously at rates of 336 kg ha^?1 N and 224 kg ha^?1 P₂O₅, respectively, which are similar to rates used in commercial forest operations. The treatment significantly increased outputs of several ions. Annual outputs of nitrate N increased as much as 18 times over pretreatment levels, and calcium and magnesium increased as much as three times over pretreatment levels the first year after fertilization. Outputs for these nutrients were elevated for all three post-treatment years. Although nitrate N increased significantly, only about 20 percent of the applied fertilizer was accounted for in stream water exports. Outputs of phosphate P declined following fertilization, probably because the watersheds are phosphorus deficient, but by the third year, they slightly exceeded predicted values. Estimated nutrient losses to deep seepage were substantial, especially on the leakier south-facing catchmeat, on which some nutrient losses were equal to or greater than those in stream water. When the nutrient exports associated with both stream discharge and ground water recharge were combined, the percentages of applied N that were lost were similar on the two watersheds, averaging 27.5 percent. Less than 1 percent of the applied P was lost from either watershed in the combination of streamflow and deep seepage.     

DETERMINATION OF BEST TIMING FOR POULTRY WASTE DISPOSAL: A MODELING APPROACH1

ABSTRACT: Confined production of poultry results in significant volumes of waste material which are typically disposed of by land application. Concerns over the potential environmental impacts of poultry waste disposal have resulted in ongoing efforts to develop management practices which maintain high quality of water downstream of disposal areas. The timing of application to minimize waste constituent losses is a management practice with the potential to ensure high quality of streams, rivers, and lakes downstream of receiving areas. This paper describes the development and application of a method to identify which time of year is best, from the standpoint of surface water quality, for land application of poultry waste. The procedure consists of using a mathematical simulation model to estimate average nitrogen and phosphorus losses resulting from different application timings, and then identifying the timings which minimize losses of these nutrients. The procedure was applied to three locations in Arkansas, and three different criteria for optimality of application timing were investigated. One criterion was oriented strictly to water quality, one was oriented only to crop production, and the last was a combination. The criteria resulted in different windows of time being identified as optimal. Optimal windows also varied with location of the receiving area. The results indicate that it is possible to land-apply poultry waste at times which both minimize nutrient losses and maximize crop yield.     

Water, environment and development

This paper for the most part constitutes the address which was made to the Consortium for International Development at their recent Presidential Symposium at Colorado State University on 30 July 1992. It raises some of the global issues in water resources development and management which are likely to confront the international community in the 1990s and beyond. The issues pose the challenge to institutions involved in the water resources field in both developed and developing countries.     

Sustainable Tourism and the Touristic Ecological Footprint

There is growing interest in ecological footprint analysis in aiding our understanding of societal demands upon the biosphere. Increasingly, attention is being focused on potential new applications of the technique. Tourism is one of the world's largest industries and can play a major part in encouraging more consumerist lifestyles. It is now widely accepted that tourism development may have profound impacts on local environments, and that, consequently, the sustainable development of tourism at destination areas is an important issue. However, sustainable tourism studies rarely look beyond the destination area, and there has been no substantive recognition of the wider ecological footprint of tourism activities. This paper attempts to connect, conceptually, the realms of sustainable tourism and ecological footprint thinking. In so doing, various conceptualisations of the 'touristic ecological footprint' (TEF) are suggested, along with some potential applications. It is argued that primary research should focus on calculating the touristic ecological footprint associated with individual tourism products, throughout the product's life-cycle. As well as bringing another dimension to our understanding of tourism's actual ecological demand, it is also argued that the concept of the touristic ecological footprint may be used to clarify theoretical aspects of the sustainable tourism debate, helping to rejuvenate this debate in the process.     

Sensitivity and first-step uncertainty analyses for the preferential flow model MACRO

Sensitivity analyses for the preferential flow model MACRO were carried out using one-at-a-time and Monte Carlo sampling approaches. Four different scenarios were generated by simulating leaching to depth of two hypothetical pesticides in a sandy loam and a more structured clay loam soil. Sensitivity of the model was assessed using the predictions for accumulated water percolated at a 1-m depth and accumulated pesticide losses in percolation. Results for simulated percolation were similar for the two soils. Predictions of water volumes percolated were found to be only marginally affected by changes in input parameters and the most influential parameter was the water content defining the boundary between micropores and macropores in this dual-porosity model. In contrast, predictions of pesticide losses were found to be dependent on the scenarios considered and to be significantly affected by variations in input parameters. In most scenarios, predictions for pesticide losses by MACRO were most influenced by parameters related to sorption and degradation. Under specific circumstances, pesticide losses can be largely affected by changes in hydrological properties of the soil. Since parameters were varied within ranges that approximated their uncertainty, a first-step assessment of uncertainty for the predictions of pesticide losses was possible. Large uncertainties in the predictions were reported, although these are likely to have been overestimated by considering a large number of input parameters in the exercise. It appears desirable that a probabilistic framework accounting for uncertainty is integrated into the estimation of pesticide exposure for regulatory purposes.