全文获取类型
收费全文 | 353篇 |
免费 | 65篇 |
国内免费 | 137篇 |
专业分类
安全科学 | 41篇 |
废物处理 | 12篇 |
环保管理 | 25篇 |
综合类 | 272篇 |
基础理论 | 60篇 |
环境理论 | 1篇 |
污染及防治 | 73篇 |
评价与监测 | 30篇 |
社会与环境 | 17篇 |
灾害及防治 | 24篇 |
出版年
2024年 | 4篇 |
2023年 | 13篇 |
2022年 | 39篇 |
2021年 | 32篇 |
2020年 | 31篇 |
2019年 | 35篇 |
2018年 | 28篇 |
2017年 | 29篇 |
2016年 | 31篇 |
2015年 | 30篇 |
2014年 | 38篇 |
2013年 | 35篇 |
2012年 | 37篇 |
2011年 | 18篇 |
2010年 | 25篇 |
2009年 | 22篇 |
2008年 | 26篇 |
2007年 | 15篇 |
2006年 | 9篇 |
2005年 | 9篇 |
2004年 | 4篇 |
2003年 | 3篇 |
2002年 | 12篇 |
2001年 | 6篇 |
2000年 | 4篇 |
1999年 | 4篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 3篇 |
1994年 | 3篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1989年 | 1篇 |
排序方式: 共有555条查询结果,搜索用时 453 毫秒
351.
352.
Yupei Long Chenchen Yuan Xiaomin Wang Dongyan Jin Hong Zhou Qiongyin Wang Chenyang Lu Yuqi Chen Yanqing Cong Qi Wang Yi Zhang 《环境科学学报(英文版)》2021,33(6):113-127
Dielectric barrier discharge (DBD) plasma applied as surface treatment technology was employed for the modification of Ag2O and graphitic carbon nitride (g-C3N4) powders. Subsequently, the pretreated powders were sequentially loaded onto TiO2 nanorods (TiO2-NRs) via electro-deposition, followed by calcination at N2 atmosphere. The results indicated that at the optimal plasma discharge time of 5 min for modification of g-C3N4 and Ag2O, photocurrent density of ternary composite was 6 times to bare TiO2-NRs under UV-visible light irradiation. Phenol was degraded by using DBD plasma-modified g-C3N4/Ag2O/TiO2-NRs electrode to analyze the photoelectrocatalytic performance. The removal rate of phenol for g-C3N4-5/Ag2O-5/TiO2-NRs electrode was about 3.07 times to that for TiO2-NRs electrode. During active species scavengers’ analysis, superoxide radicals and hydroxyl radicals were the main oxidation active species for pollutants degradation. A possible electron-hole separation and transfer mechanism of ternary composite with high photoelectrocatalytic performance was proposed. 相似文献
353.
Fabrication of electrochemically-modified BiVO4-MoS2-Co3O4composite film for bisphenol A degradation
Yanqing Cong Wenhua Zhang Wenchen Ding Tongtong Zhang Yi Zhang Nianping Chi Qi Wang 《环境科学学报(英文版)》2021,33(4):341-351
A new electrochemically-modified BiVO4-MoS2-Co3O4 (represented as E-BiVO4-MoS2-Co3O4) thin film electrode was successfully synthesized for environmental application. MoS2 and Co3O4 were grown on the surface of BiVO4 to obtain BiVO4-MoS2-Co3O4. E-BiVO4-MoS2-Co3O4 film was achieved by further electrochemical treatment of BiVO4-MoS2-Co3O4. The as-prepared E-BiVO4-MoS2-Co3O4 exhibited significantly enhanced photoelectrocatalytic activity. The photocurrent density of E-BiVO4-MoS2-Co3O4 thin film is 6.6 times that of BiVO4 under visible light irradiation. The degradation efficiency of E-BiVO4-MoS2-Co3O4 for bisphenol A pollutant was 81.56% in photoelectrochemical process. The pseudo-first order reaction rate constant of E-BiVO4-MoS2-Co3O4 film is 3.22 times higher than that of BiVO4. And its reaction rate constant in photoelectrocatalytic process is 14.5 times or 2 times that in photocatalytic or electrocatalytic process, respectively. The improved performance of E-BiVO4-MoS2-Co3O4 was attributed to the synergetic effects of the reduction of interfacial charge transfer resistance, the formation of oxygen vacancies and sub-stoichiometric metal oxides and higher separation efficiency of photogenerated electron-hole pairs. E-BiVO4-MoS2-Co3O4 is a promising composite material for pollutants removal. 相似文献
354.
355.
根据国内大型桥梁建设工程区对气象安全保障的特殊要求及目前常规气象监测与预报预警的现状 ,笔者提出桥梁工程区气象环境监测、预报预警、安全保障建设的整体思路和技术框架 ,并据此研制成功一个基于通用分组无线业务 (GPRS) ,由工程区数据采集、分析及预报制作、信息传输、应急措施 4部分组成的桥梁工程区气象安全保障系统。该系统克服了以往桥梁施工气象安全保障中的缺陷 ,满足了建设部门随时随地掌握工程区当前和未来气象环境及其他安全保障对工程区气象基础数据的需求。系统应用于苏通长江公路大桥施工期的气象安全保障中 ,已取得明显实效 ,为该大桥建设规避气象灾害 ,降低不利天气条件影响 ,保障施工安全及施工计划安排提供了决策依据。 相似文献
356.
The vapor phase organics (VPOs) in the air of Beijing, Langfang and Tianjin were detected by a capillary gas chromatography and GC/MS during the winter and the summer separately. The tentatively identified compounds include alkanes, cyclic hydrocarbons, alkenes, aromatics, acids, alcohols, aldehydes, ketones, esters, halocarbons and so on. The numbers of VPOs found are 118 in Beijing, 83 in Lang-fang and 65 in Tianjin in the winter, and 56, 39 and 72 in the summer respectively. Based on the data of some representative compounds determined quantitatively by GC and GC/MS, a profile of organic pollution in the air of the three cities is presented. 相似文献
357.
基于2H&18O和水化学成分的永定河流域地下水循环特征解析 总被引:2,自引:0,他引:2
运用环境同位素和水化学成分作为水循环研究的示踪剂, 揭示了永定河流域中下游地下水
循环特征。通过现场调查并对浅层和深层地下水采样, 进行室内水化学和氢氧同位素组成测定, 分
析了流域内深层和浅层地下水的氢氧同位素和水化学组成的空间分布规律和演化趋势, 揭示了流
域地下水循环特征。结果表明, 降水是山前地下水的主要补给源, 地下水在接受降水的补给后经过
了不同程度的蒸发作用, 山区受蒸发影响较小, 平原区较大, 尤其是平原区浅层地下水呈现出强烈
的蒸发浓缩作用; 水化学特征表现为自西部山区到山前平原至滨海平原, 自浅层到深层, 地下水的
矿化度逐渐升高; 平原区浅层和深层地下水含水层之间存在明显的越流补给现象; 沿海地区未发现
海水入侵现象。 相似文献
358.
359.
污水排海工程设计的初步研究 总被引:1,自引:0,他引:1
本文结合我国国情根据混合区边缘污染物背景值以及海域功能,从而确定允许的污染物最大增加值,并具此推算出扩散器长度和起始稀释度。 相似文献
360.
Effects of arsenic on concentration and distribution of nutrients in the fronds of the arsenic hyperaccumulator Pteris vittata L 总被引:7,自引:0,他引:7
Pteris vittata was the first terrestrial plant known to hyperaccumulate arsenic (As). However, it is unclear how As hyperaccumulation influences nutrient uptake by this plant. P. vittata fern was grown in soil spiked with 0-500 mg As kg(-1) in the greenhouse for 24 weeks. The concentrations of essential macro- (P, K, Ca, and Mg) and micro- (Fe, Mn, Cu, Zn, B and Mo) elements in the fronds of different age were examined. Both macro- and micronutrients in the fronds were found to be within the normal concentration ranges for non-hyperaccumulators. However, As hyperaccumulation did influence the elemental distribution among fronds of different age of P. vittata. Arsenic-induced P and K enhancements in the fronds contributed to the As-induced growth stimulation at low As levels. The frond P/As molar ratios of 1.0 can be used as the threshold value for normal growth of P. vittata. Potassium may function as a counter-cation for As in the fronds as shown by the As-induced K increases in the fronds. The present findings not only demonstrate that P. vittata has the ability to maintain adequate concentrations of essential nutrients while hyperaccumulating As from the soil, but also have implications for soil management (fertilization in particular) of P. vittata in As phytoextraction practice. 相似文献