Investigation on the relationship between the fine particle emission and crystallization characteristics of gypsum during wet flue gas desulfurization process

The relationship between the fine particles emitted after desulfurization and gypsum crystals in the desulfurization slurry was investigated, and the crystallization characteristics varying with the operation parameters and compositions of the desulfurization slurry were discussed. The results showed that the fine particles generated during the desulfurization process were closely related to the crystal characteristics in the desulfurization slurry by comparison of their morphology and elements. With the higher proportion of fine crystals in the desulfurization slurry, the number concentration of fine particles after desulfurization was increased and their particle sizes were smaller, indicating that the optimization of gypsum crystallization was beneficial for the reduction of the fine particle emission. The lower pH value and an optimal temperature of the desulfurization slurry were beneficial to restrain the generation of fine crystals in the desulfurization slurry. In addition, the higher concentrations of the Fe^3 + ions and the F⁻ ions in the desulfurization slurry both promoted the generation of fine crystals with corresponding change of the morphology and the effect of the Fe^3 + ions was more obvious. With the application of the desulfurization synergist additive, it was beneficial for the inhibition of fine crystals while the thinner crystals were generated.     

煤制烯烃废水处理与回用技术解析

针对煤制烯烃项目废水的来源及水质特点,从生化处理技术与回用处理技术方面阐述了煤制烯烃废水处理现状及存在问题,展望了煤制烯烃废水处理与回用技术未来发展方向,指出了新型脱氮工艺、膜集成工艺及分质结晶技术在煤制烯烃废水处理中的可行性,为煤化工废水处理与资源化利用提供理论参考。     

燃煤烟气同时脱硫脱硝方法的研究进展及分析

近年来,烟气同时脱硫脱硝技术因占地面积小,可同时控制多种污染物而引起广泛的关注,但该技术多数仍停留在实验阶段。文章重点介绍了等离子体法、固相吸附法、溶液吸收法及微生物法等方法研究进展,对各方法的脱硫脱硝特点及功效进行评述,分析其问题与不足,并提出燃煤烟气同时脱硫脱硝方法的研究方向,为同时脱硫脱硝技术的改进提出建议。     

Dietary exposure to di-isobutyl phthalate increases urinary 5-methyl-2′-deoxycytidine level and affects reproductive function in adult male mice

Phthalates are a large family of ubiquitous environmental pollutants suspected of being endocrine disruptors. Epidemiological studies have associated phthalate metabolites with decreased reproductive parameters and linked phthalate exposure with the level of urinary 5-methyl-2′-deoxycytidine(5mdC, a product of methylated DNA). In this study, adult male mice were exposed to 450 mg di-isobutyl phthalate(DiBP)/(kg·day) via dietary exposure for 28 days. Mono-isobutyl phthalate(Mi BP, the urinary metabolite) and reproductive function parameters were determined. The levels of 5mdC and 5-hydroxymethyl-2′-deoxycytidine(5hmdC) were measured in urine to evaluate if their contents were also altered by DiBP exposure in this animal model. Results showed that DiBP exposure led to a significant increase in the urinary 5mdC level and significant decreases in sperm concentration and motility in the epididymis, accompanied with reduced testosterone levels and downregulation of the P450 cholesterol side-chain cleavage enzyme(P450scc) gene in the mice testes. Our findings indicated that exposure to DiBP increased the urinary 5mdC levels,which supported our recent epidemiological study about the associations of urinary 5mdC with phthalate exposure in the male human population. In addition, DiBP exposure impaired male reproductive function, possibly by disturbing testosterone levels; P450scc might be a major steroidogenic enzyme targeted by DiBP or other phthalates.     

海平面上升叠加风暴潮对2050年中国海洋经济的影响研究

本研究基于ArcGIS的淹没模型与夜光遥感的GDP空间化处理结果,同时结合对2050年中国海洋经济增长预测,评估海平面上升叠加风暴潮三种情景对中国沿海各省市海洋经济的影响效应。模拟结果表明:海平面上升叠加风暴潮与天文潮的CHmax-0.3 m情景下全国海洋经济损失最大,2050年损失达到35444.59亿元,占海洋生产总值的9.39%;从2050年各省海洋经济损失比例来看（CHmax-0.3 m情景）,辽宁省损失比例最大,其次为广东省,福建省和广西省;从各省海洋经济损失的绝对值来看,在海平面上升0.3 m的三种情景下,广东、辽宁、江苏、山东均为海洋经济损失绝对值最大的四个省份。     

石化行业有机液体储罐VOCs损耗估算方法浅析

总结了实测法、公式法、模型法等国内外石化行业有机液体储罐VOCs排放估算方法的主要特点和适用范围;运用公式法估算国内某石化企业典型油品储罐的VOCs排放量;分析了在我国直接套用美国环保署(EPA)开发的TANKS模型存在的问题;根据估算方法的实际应用研究,就美国AP-42源强手册第五版第七章(chapter 7:Liquid storage tank)中评价公式的"本土化"提出相关的建议。     

HAZOP分析在常减压装置的应用及问题探讨

运用"HAZOP+LOPA+风险矩阵"复合式风险分析技术,对金陵分公司常减压装置进行危险辨识和风险分析,识别装置存在的主要问题和隐患,并对HAZOP技术应用中存在的适应性问题进行了探讨,对装置风险控制提出了针对性的建议措施,为装置的"安、稳、长、满、优"运行提供指导。     

大兴安岭地区生态产品优势分析研究

大兴安岭地区生态优良、环境优美、地域广阔、森林浩瀚,是特有的寒温带生态系统.近年来,省委省政府落实"绿水青山就是金山银山"发展理念,结合我省大小兴安岭地区生态优势,制定保护规划、实施天保工程,有效提高了森林生态系统的服务功能.大兴安岭地区何以能生产出优质的生态产品?以蓝莓产业和产品为案例进行分析,认为:大兴安岭地区整体生态优势明显,主要体现在具有"冬季寒冷自然休眠、夏季昼长温差大"的气候条件;具有"纬度高、山坡缓、河流繁、水量大"的地理特征;具有"气洁、水清、土沃、排放少"的环境优势;具有"林广、树密、生物多样、生境完整"的生态优势;具有"质优、安全、营养、环保"的产品品质.     

本溪地区灰霾天气时空分布特征分析研究

近年来,灰霾天气对本溪地区的影响越来越严重,由霾引发的环境污染对人们生产生活造成的影响也越来越大,因此对灰霾天气发生的时空分布特征的研究就尤为重要.文章运用本溪地面观测2012-2014年本溪市、本溪县、桓仁县3个国家基本站的观测资料,对霾日进行筛选和统计,分析本溪地区霾日发生的时空分布特征,本溪地区霾日数呈逐年增长趋势,2014年霾日数增长迅速.本溪地区冬半年霾日明显多于夏半年,两县霾日少于市区,空气质量优于市区.     

省级生态保护红线划定实践研究 ——以青岛市为例

在省级及以上禁止开发区、重点生态功能保护区等进行调查分析的基础上,以青岛市为实践区域,与多类规划衔接,划定青岛市省级生态保护红线.青岛市最终划定59处省级生态保护红线区,面积合计1120.65 km2,占国土面积的9.9%.划定的生态保护红线符合确立"三生"空间和落实"多规合一"的要求,有利于改善生态系统服务功能,保障人居环境安全,增强经济社会可持续发展能力,对于青岛市市级生态保护红线的划定和生态安全格局的构建具有非常重要的意义.