复合人工湿地系统酶活性及其与污染物净化效果的相关性

构建目前广泛应用的复合垂直流人工湿地系统,从酶学角度探讨湿地主要污染物净化机理。通过对下行流-上行流复合人工湿地和下行流-下行流复合人工湿地2套系统磷酸酶、脲酶活性的测定发现,磷酸酶、脲酶活性随系统流程逐级降低,一级池磷酸酶、脲酶活性较高且日变化较大,同一一级池中磷酸酶、脲酶活性呈显著相关性。系统脲酶活性和TN去除率相关性显著,磷酸酶活性与TP去除率不存在显著相关性,磷酸酶、脲酶活性与COD去除率相关性亦不显著。     

A 1-dodecanethiol-based phase transfer protocol for the highly efficient extraction of noble metal ions from aqueous phase

A 1-dodecanethiol-based phase-transfer protocol is developed for the extraction of noble metal ions from aqueous solution to a hydrocarbon phase, which calls for first mixing the aqueous metal ion solution with an ethanolic solution of 1-dodecanethiol, and then extracting the coordination compounds formed between noble metal ions and 1-dodecanethiol into a non-polar organic solvent. A number of characterization techniques, including inductively coupled plasma atomic emission spectroscopy, Fourier transform infrared spectroscopy, and thermogravimetric analysis demonstrate that this protocol could be applied to extract a wide variety of noble metal ions from water to dichloromethane with an efficiency of > 96%, and has high selectivity for the separation of the noble metal ions from other transition metals. It is therefore an attractive alternative for the extraction of noble metals from water, soil, or waste printed circuit boards.     

Synthesis,crystal structure,photodegradation kinetics and photocatalytic activity of novel photocatalyst ZnBiYO4

ZnBiYO₄ was synthesized by a solid-state reaction method for the first time. The structural and photocatalytic properties of ZnBiYO₄ were characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy and UV–Vis diffuse reflectance. ZnBiYO₄ crystallized with a tetragonal spinel structure with space group I41/A. The lattice parameters for ZnBiYO₄ were a = b = 11.176479 Å and c = 10.014323 Å. The band gap of ZnBiYO₄ was estimated to be 1.58 eV. The photocatalytic activity of ZnBiYO₄ was assessed by photodegradation of methyl orange under visible light irradiation. The results showed that ZnBiYO₄ had higher catalytic activity compared with N-doped TiO₂ under the same experimental conditions using visible light irradiation. The photocatalytic degradation of methyl orange with ZnBiYO₄ or N-doped TiO₂ as catalyst followed first-order reaction kinetics, and the first-order rate constant was 0.01575 and 0.00416 min^− 1 for ZnBiYO₄ and N-doped TiO₂, respectively. After visible light irradiation for 220 min with ZnBiYO₄ as catalyst, complete removal and mineralization of methyl orange were observed. The reduction of total organic carbon, formation of inorganic products, SO₄^2 − and NO₃⁻, and evolution of CO₂ revealed the continuous mineralization of methyl orange during the photocatalytic process. The intermediate products were identified using liquid chromatography–mass spectrometry. The ZnBiYO₄/(visible light) photocatalysis system was found to be suitable for textile industry wastewater treatment and could be used to solve other environmental chemical pollution problems.     

高职环保类专业职业技能培养课程体系开发

课程体系是高职专业办出特色、持续发展的载体。针对高职环保类专业人才培养存在课程体系不合理、实践教学薄弱、职业技能培养方法陈旧等问题，以职业岗位需求为基础，以职业技能培养为主线，构建了以实际污染治理项目为载体的高职环保类专业职业课程体系和职业核心课程。通过职业核心课程建设、双师型师资队伍建设、校内外实训基地建设等措施实现职业技能的培养。     

金属非金属地下矿山监测监控系统研究

为了使监测监控系统在金属非金属地下矿山中最大限度地发挥作用,结合国家相关标准规范和矿山实际,对金属非金属地下矿山监测监控系统进行了分析研究,提出了金属非金属地下矿山监测监控系统的系统架构及各子系统的组成和工作原理,并对各子系统进行了系统设计,指出了建设金属非金属地下矿山监测监控系统的要点.明确了金属非金属地下矿山监测监控系统的建设内容和建设原则,并进一步阐释并弥补了国家相关标准规范对监测监控系统设计与建设要点较为模糊的不足,为我国金属非金属地下矿山建设完善并更好使用监测监控系统提供了依据,有利于提高金属非金属地下矿山的本质安全生产水平.     

某石化企业职业卫生检测现状分析

通过收集某石化企业近两年的日常检测数据,并结合企业的职业卫生管理及防护设施运行情况,分析了该企业的职业卫生检测现状.     

高等师范院校非环境类专业环境教育课程化的探讨

在对高等师范院校环境教育的现状及存在问题进行全面分析的基础上,提出了环境教育课程化的基本方式,包括开设环境教育的系列课程和加强实践性环境教育活动.对高等师范院校非环境类专业环境教育的课程化问题提出一些看法和建议:高等师范院校非环境类专业的环境教育应强化学生的职前培训,实施环境教育的课程化,建立完善的课程体系并采用多种课程教育模式,加强社会实践活动,将传统的师范教育课程体系改为更为广泛的多种课程体系.同时还要注重环境教育师资培养、加强学生的环保法律法规教育、创建绿色校园环境.     

利用灰色Verhulst模型对烟台市空气质量综合评价研究

确定空气中的污染物,预测发展趋势,对改善空气质量状况有着积极的意义.以烟台市2009年-2013年的空气质量为历史数据,利用灰色Verhulst模型预测出未来几年的空气质量数据,其结果显示烟台的空气质量状况在逐年改善,几年后可达到国家一级环境标准.为了确定影响烟台空气质量的主要因素,利用灰色关联分析法得到工厂生活中排放的、烟(粉)尘是最主要的影响因素,私人汽车拥有量和绿化面积是相对重要的影响因素.     

Impact of socioeconomic and meteorological factors on reservoirs’ air quality: a case in the Three Gorges Reservoir of Chongqing (TGRC), China over a 10-year period

Environmental Science and Pollution Research - The Three Gorges Dam’s construction and industrial transfer have resulted in a new air pollution pattern with the potential to threaten the...