Distribution and bioaccumulation of steroidal and phenolic endocrine disrupting chemicals in wild fish species from Dianchi Lake, China

The distribution and bioaccumulation of steroidal and phenolic endocrine disrupting chemicals (EDCs) were studied in various tissues of wild fish species from Dianchi Lake, China. In muscle tissue, 4-tert-octylphenol, 4-cumylphenol, 4-nonlyphenol and bisphenol A were detected in fish from each sampling site, with maximal concentrations of 4.6, 4.4, 18.9 and 83.5 ng/g dry weight (dw), respectively. Steroids (estrone, 17β-estradiol 17α-ethynylestradiol and estriol) were found at lower levels (<11.3 ng/g dw) and less frequently in muscle samples. The highest concentrations of steroids and phenols were found in liver, followed by those in gill and the lowest concentration was found in muscle. The field bioconcentration factors (BCFs) of phenols were calculated in fish species ranged from 18 to 97. Moreover, the measured tissue concentrations were utilized in order to estimate water concentration of steroids (4.4-18.0 ng/L). These results showed that steroidal and phenolic EDCs were likely ubiquitous contaminants in wild fish.     

磁强化臭氧氧化生化处理二级出水的试验研究

在外加磁场作用下,采用臭氧氧化对青岛某污水处理厂生化处理二级出水进行了处理.考察了臭氧投加量、反应时间、磁场强度对处理效果的影响.经过多次试验得到的最佳运行参数为:臭氧投加量3.5 mg/L;反应时间10 min;磁场强度3 000Gs.外加磁场提高了臭氧氧化的效率,缩短了反应时间.     

竹林土壤中甲基对硫磷降解菌的降解效果及其与土壤物理特性的关系

采用实验室控制试验研究了甲基对硫磷降解菌在竹林土壤生态系统中的降解效果及其与土壤物理特性的关系。试验结果表明,邻单胞菌（DLL-1）具有高效性,甲基对硫磷初始浓度为15 mg/kg干土,第5 d竹林土壤上、中和下层的降解率分别为88.6%、85.9%和79.2%,相应的半衰期为2.5、2.84与3.79 d。甲基对硫磷在土壤中的不同粒径范围吸附情况是不同的,从而影响DLL-1菌的降解效果,表现为土壤中粘粒含量与降解率呈显著正相关。孔隙度也是影响降解效果的一个因素,上中下3层的降解率随着孔隙度的减小而降低。     

上埋式管道穿越高填方填挖结合部位的受力状态研究

以延安新区黄土高填方工程中的上埋式排水管道为原型,开展了相似比为1:2的室内试验,试验前在模型箱底部一定位置预设沉降底板模拟实际填方的工后沉降过程,在试验土体和管道中布设压力盒、位移计和应变片,以采集试验过程中的管土接触压力、管-土相对位移和管道应变等数据。研究表明,负土拱效应对管道的上部压力影响明显,竖向压力系数最大达3.4,与沉降量的关系符合三次多项式曲线,负土拱效应对管道的影响不可忽略。开挖纵向剖面后发现管道下部土层间出现明显的脱空裂缝,是管道下部管-土接触压力减小的原因。该成果为黄土高填方场地中管周土压力的计算、管道变形控制提供参考。     

侧吸导烟技术的经济性分析

介绍了侧吸导烟技术的技术背景,分析计算了焦炉装煤烟尘成分及含量,经对该技术的经济效益进行概算后显示,该技术可以有效改善焦炉区及周边环境,每年还可创造可观的经济效益,是一项值得研究推广的技术。     

循环式超声强化光催化降解双酚A

设计了一种循环式超声强化光催化反应器,以TiO2作为光催化剂,研究了超声功率、TiO2加入量、循环液流速和空气流量对双酚A(BPA)降解效果的影响。实验结果表明:超声与光催化过程在循环式超声强化光催化反应器中实现了较好的协同效应;在初始BPA质量浓度为20.0mg/L、超声功率为600W、TiO2加入量为7g/L、循环液流速为4.05×10-2m/s、空气流量为200mL/min的条件下,反应150min后,BPA降解率可达90.5%,溶液中剩余BPA质量浓度仅为1.8mg/L,反应240min后TOC去除率可达84.5%。     

Occurrence, distribution, and sources of six phenolic endocrine disrupting chemicals in the 22 river estuaries around Dianchi Lake in China

The objectives of this study are to track the occurrence, distribution, and sources of phenolic endocrine disrupting compounds (EDCs) in the 22 rivers around Dianchi Lake in China, to estimate the input and output amounts of phenolic EDCs in the water system, and to provide more comprehensive fundamental data for risk assessment and contamination control of phenolic EDCs in aquatic environment. Six phenolic EDCs were systematically evaluated in water and surface sediment in the estuaries of those rivers. The water and sediment samples were preconcentrated by solid-phase extraction system and microwave-assisted extraction system, respectively. Phenolic EDCs were analyzed by GC-MS (Thermo Fisher Scientific, USA) after derivatization. Phenolic EDCs were found ubiquitously in the aquatic environment. The total concentrations ranged from 248 to 4,650 ng/L in water, and 113 to 3,576 ng/g dry weight in surface sediment. The residue amount of phenolic EDCs in Dianchi Lake was 258 kg/a. Concentrations of the phenolic EDCs in the Lake decreased with increase in distance to the estuaries of those rivers which run through urban and industrial areas. The rivers seriously contaminated by phenolic EDCs were Xin River, Yunliang River, Chuanfang River, Cailian River, Jinjia River, Zhengda River, and Daqing River which run through the old area of Kunming City. Satisfying correlations were observed between the concentrations of the target compounds in water and in surface sediment. NP1EO, NP2EO, and BPA were identified as the three predominant phenolic EDCs. There were significant correlations between phenolic EDCs and many basic water quality parameters. Urban and industrial areas are the major contributors for phenolic EDCs, especially in Kunming City. Compositional profiles of phenolic EDCs in surface sediment were similar to those in river water. The concentrations of phenolic EDCs in the rivers located in the northwest part of the valley were very high, and posed a potential risk to aquatic organisms and even human. The concentrations of NP2EO, NP1EO, and BPA were at moderate levels of other areas. The basic water quality parameters (TOC, TN, DO, and pH) play important roles on the distribution, fate, and behavior of phenolic EDCs in the valley.     

氢氧混合气体爆炸临界条件实验研究

可燃气体的燃烧、爆炸是工业生产中常见的灾害性事故,危害极大.通过爆轰管实验装置,采用疏密分布的压力传感器测量氢氧混合气体的爆轰特性,并依据压力和波速在燃烧转爆轰瞬间发生突跃,判断混合气体爆炸的临界条件.实验结果表明,爆炸压力随氢气初始浓度呈∩形变化,50%氢气体积分数为爆炸最佳浓度值;在常温常压下,氢氧混合物爆炸的临界氢气体积分数是15%和90%;化学计量比的氢氧混合气体发生爆炸的临界初始压力为0.01 MPa;氮-氢-氧三元混合气体爆炸的临界氮气体积分数为60%.     

冲压机械伤害风险评价信息系统研究

研究冲压机械伤害风险评价信息系统,无论对企业内部事故预防还是对职工健康安全,还是节省国家因事故造成的经济损失,都十分必要。应用计算机编程语言和数据库软件,对冲压作业进行综合管理评价、设备设施的固有危险性评价及劳动卫生与作业环境评价,进而对冲压作业风险进行评价分级,建立动态的冲压机械伤害风险评价数据库管理信息系统。该系统可保存所有评价的项目资料,供应用和参考,实现了对冲压机械伤害风险评价的数据库动态管理,使风险评价分析工作组织化、条理化、系统化。