水环境中石油类物质分析方法探讨

在详述了国内外石油类分析方法的基础上,对各方法的适用范围、优缺点及可比性进行了深入分析,阐述了各类方法存在的共性问题,指出按照石油类物质毒性大小分别定量分析的方法将是未来的发展趋势。     

Comparison of the daily global solar radiation from different data sources in Northwest China climate

The solar radiation data are of high importance to the solar energy systems. Conventional methods to obtain the solar radiation data are from weather stations, solar radiation models, commercial software databases, and field measurements. In the present study, a new daily global solar radiation model is proposed, by combining the quadratic function of sunshine fraction and sine function of the day of the year. The solar radiation model calculated data are then compared with China Meteorological Data Sharing System (CMDSS) data, TRNSYS data, and field-measured data in Northwest China climate. It is found that the newly proposed solar radiation model has better performance than the other nine solar radiation models in the literature. The solar radiation model calculated data fit well with the CMDSS annually average data. The TRNSYS data are a bit larger than the CMDSS annually average data in summer half year and a little smaller than those in winter half year. The solar radiation model and the CMDSS annually average data have the best correlation, whereas the TRNSYS data and the field-measured data have the worst correlation. The solar radiation model calculated data have the best correlation with the other three data sources.     

Model evaluation of the phytoextraction potential of heavy metal hyperaccumulators and non-hyperaccumulators

Evaluation of the remediation ability of zinc/cadmium in hyper- and non-hyperaccumulator plant species through greenhouse studies is limited. To bridge the gap between greenhouse studies and field applications for phytoextraction, we used published data to examine the partitioning of heavy metals between plants and soil (defined as the bioconcentration factor). We compared the remediation ability of the Zn/Cd hyperaccumulators Thlaspi caerulescens and Arabidopsis halleri and the non-hyperaccumulators Nicotiana tabacum and Brassica juncea using a hierarchical linear model (HLM). A recursive algorithm was then used to evaluate how many harvest cycles were required to clean a contaminated site to meet Taiwan Environmental Protection Agency regulations. Despite the high bioconcentration factor of both hyperaccumulators, metal removal was still limited because of the plants' small biomass. Simulation with N. tabacum and the Cadmium model suggests further study and development of plants with high biomass and improved phytoextraction potential for use in environmental cleanup.     

废弃印刷线路板碘化法浸金研究

针对碘化法从废弃印刷线路板中提取金的工艺设计,分别考察了碘的质量分数、n(I₂)/n(I^-)比值、固液比、双氧水的质量分数、pH值、浸出时间和浸出温度对金浸出率的影响。结合正交设计优化实验方法,提出了从废弃印刷线路板中碘化法浸取金的最佳工艺条件：碘的质量分数为1.1％,n(I₂)∶n(I^-)=1∶10,双氧水的质量分数为1.5％,浸出时间4 h,固液比为1∶10,浸出温度为常温（25℃）,溶液pH值为中性,此时金浸出率可达97.5％。     

液-固流化床回收印刷线路板中金属的研究

根据废弃印刷线路板中材料密度不同,采用水介质流化床对印刷线路板粉末中的金属进行回收,对0.25～0.177、0.177～0.104、0.104～0.074和-0.074 mm 4个粒级范围内的物料进行分选试验。试验结果表明,在上述4个粒级范围内,随介质流速的增大,金属回收率降低;金属回收率η与实际操作速度（ua）和颗粒终端沉降速度（ut）的比值φ（ua/ut）存在一定线性关系,分析模拟了η与φ之间的相关性方程,外推试验的结果证明了相关性方程的可靠性;在合适的操作条件下,各粒级范围内金属的回收率分别为95.02%、90.07%、87.5%和92.68%。     

砒霜生产化工厂危险废物处置工程设计

通过对砒霜生产化工厂原场址废渣及污染场地调查的基础上,进行了处置方案比选及技术经济比较,确定了就地安全填埋的处置方案。根据区域性危险废物集中安全填埋场的设计经验,本工程采用先进的HDPE双层防渗的安全填埋方式,并设置了雨水分流系统、渗滤液收集系统、封场处理和填埋气体导排系统,整个场区布置合理,对周围环境的影响小,投资少,取得了良好的社会效益和环境效益,并对危险废物处理处置工程设计中应注意的问题提出了建议。     

聚硅酸锌铝的制备及其性能研究

以硅酸钠、硫酸锌、硫酸铝为原料,通过共聚法制备了无机高分子絮凝剂聚硅酸锌铝（PSZAS）,研究了Na₂SiO₃的摩尔浓度、活化时间、Al/Si、Zn/Si 配比及絮凝剂的投加量对絮凝效果的影响,用X-射线衍射（XRD）和电子扫描电镜（SEM）对该絮凝剂的结构及形貌进行了表征。结果表明：当硅酸钠的浓度为0.4 mol/L,硅酸活化时间为2 h,Si∶Al∶Zn=1∶1∶1.5,絮凝剂投加量为20 mL/L废水时,絮凝剂的电中和能力和吸附架桥能力最强,絮凝剂对含H-酸染料模拟废水的絮凝效果最好。     

新型转式垃圾焚烧过程中脱氯脱硫机理的研究

为了探讨有机垃圾焚烧过程钙基添加剂对HCl,SO_x生成特性的影响,分别在自行设计的中空水冷转式垃圾焚烧炉和固定床加热炉中进行了一系列的实验,研究结果表明新型转式焚烧炉具有强化传热传质特性,能提高HCl、SO_x的脱除率,可抑制有害气体的生成;同时也研究了 HCl,SO₂气体同时存在时,钙基添加剂对脱氯脱硫效率的影响规律。     

基于工业以太网的烟粉尘在线监测系统的研究

为实现工厂矿山的烟粉尘浓度的实时在线监测,提出了在废气排放监测装置中引入工业以太网技术。以嵌入式S3C2410芯片为核心,扩展相应的外围电路,实现对废气中烟粉尘浓度等参数监测功能,集显示、信息处理、监测和通讯等功能于一体。文章给出了烟粉尘浓度的采样原理和系统的软硬件设计方案,详细给出了以太网控制芯片CS8900A与ARM硬件接口方法与软件实现方案。     

Hydrogeochemical Indicators of Groundwater Flow Systems in the Yangwu River Alluvial Fan,Xinzhou Basin,Shanxi, China

Based on analysis of groundwater hydrochemical and isotopic indicators, this article aims to identify the groundwater flow systems in the Yangwu River alluvial fan, in the Xinzhou Basin, China. Groundwater δ²H and δ¹⁸O values indicate that the origin of groundwater is mainly from precipitation, with local evaporative influence. d-excess values lower than 10% in most groundwaters suggest a cold climate during recharge in the area. Major ion chemistry, including rCa/rMg and rNa/rCl ratios, show that groundwater salinization is probably dominated by water–rock interaction (e.g., silicate mineral weathering, dissolution of calcite and dolomite and cation exchange) in the Yangwu River alluvial fan, and locally by intensive evapotranspiration in the Hutuo River valley. Cl and Sr concentrations follow an increasing trend in shallow groundwater affected by evaporation, and a decreasing trend in deep groundwater. ⁸⁷Sr/⁸⁶Sr ratios reflect the variety of lithologies encountered during throughflow. The groundwater flow systems (GFS) of the Yangwu River alluvial fan include local and intermediate flow systems. Hydrogeochemical modeling results, simulated using PHREEQC, reveal water–rock interaction processes along different flow paths. This modeling method is more effective for characterizing flow paths in the intermediate system than in the local system. Artificial exploitation on groundwater in the alluvial fan enhances mixing between different groundwater flow systems.