Consequences of manganese compounds: a review

Manufacturing of manganese (Mn) compounds, their industrial applications as well as mining overburden, has generated a potential environmental pollutant. Occupational exposure to elevated levels of Mn occurs during mining, welding, smelting and other industrial anthropogenic sources. Chronic and acute exposure of this metal pollutant leads to adverse consequences and is clinically categorized by various symptoms of neurotoxicity including cognitive, psychiatric symptoms, Parkinson's disease, extra pyramidal signs, manganism, dystonia, and motor system dysfunction. The aim of this review is to summarize the possible mechanism underlying Mn compounds-mediated neurotoxicity leading to neurodegenerative diseases. Our review endeavours to examine recent advances in research on Mn-related environmental pollution, Mn-induced poisoning, molecular mechanisms underlying Mn-induced neurotoxicity with case studies as well as current approaches employed for treatment and prevention of Mn exposure.     

Suppression of inhibition of substrate photodegradation by scavengers of hydroxyl radicals: the solvent-cage effect of bromide on nitrate photolysis

In this paper we show that bromide scavenges the ^·OH radicals formed upon photolysis of nitrate, before they leave the solvent cage. Bromide can thus inhibit the in-cage recombination between ^·OH and ^·NO₂. The consequence is an increased generation of ^·NO₂ and nitrite and of Br₂ ^?· + ^·OH, compared to ^·OH alone in the absence of bromide. We show that this effect compensates for the lower reactivity of Br ₂ ^?· compared to ^·OH toward certain organic substrates, e.g. phenol and tryptophan. Our findings could lead to a deep revision of the present views of the role of bromide in saltwater photochemistry.     

Association between skin lesion and arsenic concentration in hair by mixed bivariate model in chronic arsenic exposure

Skin lesion is one of the important health hazards caused by high intake of arsenic through drinking water and diet, and the other hazards include several types of cancers (viz. skin, lung and urinary bladder), ischemic heart disease, hypertension, etc. Two most important biomarkers to measure arsenic intake in a human body are arsenic concentration in urine and hair. The primary interest of this paper is the association between skin lesion and arsenic concentration in hair for participants with chronic arsenic exposure from West Bengal, India, using bivariate regression model based on copula function. The result showed participants with high arsenic concentration in hair had higher incidence of developing skin lesion. Arsenic concentration in hair was significantly higher for the participants with an arsenic concentration in water?>?10 mg/L.     

Natural radioactivity and radiation exposure in the high background area at Chhatrapur beach placer deposit of Orissa, India

A high natural background radiation area is reported for the Chhatrapur beach placer deposit of Orissa state, on the southeastern coast of India, due to the presence of radiogenic heavy minerals. The average activity concentrations of radioactive elements 232Th, 238U and 40K were measured by gamma-ray spectrometry using a HPGe detector, and found to be 2500 +/-1850, 230 +/- 140 and 120 +/- 35 Bq kg-1, respectively, for the bulk sand samples. The absorbed gamma dose rates in air due to the naturally occurring radionuclides varied from 375 to 5000 nGy h-1, with an average value of 1625 +/- 1200 nGy h-1. The external annual effective dose rate of the region ranged from 0.46 to 6.12 mSv y-1, with an average value of 1625 +/- 1200 mSv y-1. The absorbed gamma dose rate levels of Chhatrapur beach area were similar to the monazite sand-bearing high background radiation areas of southern and southwestern coastal tracts of India and other similar areas of the world. The major contributors to the enhanced level of radiation are monazite and zircon sands.     

Effect of the herbicides oxadiazon and oxyfluorfen on phosphates solubilizing microorganisms and their persistence in rice fields

A field experiment has been conducted with two herbicides viz. oxadiazon [5-terbutyl-3-(2,4-dichloro-5-isopropoxyphenyl)-1,3,4-oxadiazol-2-one] and oxyfluorfen [2-chloro-1-(3-ethoxy-4-nitrophenyl)-4-(trifluoromethyl) benzene] at rates of 0.4 and 0.12 kg a.i. ha(-1), respectively, to investigate their effect on the growth and activities of phosphate solubilizing microorganisms in relation to availability of phosphorus as well as persistence of the herbicides in the rhizosphere soil of wetland rice (Oryza sativa L. variety IR-36). Application of herbicides stimulated the population and activities of phosphate solubilizing microorganisms and also the availability of phosphorus in the rhizosphere soil. Oxyfluorfen provided greater microbial stimulation than oxadiazon. Dissipation of oxyfluorfen and oxadiazon followed first order reaction kinetics with half-life (T(1/2)) of 8.8 and 12 days, respectively. Sixty days after application 0.5% and 3% of the applied oxadiazon and oxyfluorfen residues persisted, respectively, in the rhizosphere soil of rice.     

Stochastic landslide vulnerability modeling in space and time in a part of the northern Himalayas, India

Little is known about the quantitative vulnerability analysis to landslides as not many attempts have been made to assess it comprehensively. This study assesses the spatio-temporal vulnerability of elements at risk to landslides in a stochastic framework. The study includes buildings, persons inside buildings, and traffic as elements at risk to landslides. Building vulnerability is the expected damage and depends on the position of a building with respect to the landslide hazard at a given time. Population and vehicle vulnerability are the expected death toll in a building and vehicle damage in space and time respectively. The study was carried out in a road corridor in the Indian Himalayas that is highly susceptible to landslides. Results showed that 26% of the buildings fall in the high and very high vulnerability categories. Population vulnerability inside buildings showed a value >0.75 during 0800 to 1000 hours and 1600 to 1800 hours in more buildings that other times of the day. It was also observed in the study region that the vulnerability of vehicle is above 0.6 in half of the road stretches during 0800 hours to 1000 hours and 1600 to 1800 hours due to high traffic density on the road section. From this study, we conclude that the vulnerability of an element at risk to landslide is a space and time event, and can be quantified using stochastic modeling. Therefore, the stochastic vulnerability modeling forms the basis for a quantitative landslide risk analysis and assessment.     

Evaporative Cooling of Water in a Small Vessel Under Varying Ambient Humidity

Evaporative cooling of water in a small porous clay vessel was studied under controlled humidity conditions. In steady-state experiments performed at an ambient temperature of 23 °C, the cooling effect increased from 4.7 to 8.3 °C as the ambient relative humidity decreased from 60 to 15%. External heat and mass transfer coefficients, estimated from the steady-state measurements, were used in mathematical models to predict the experimentally observed transient temperature variation of the water under ramp changes of the ambient relative humidity. With a prototypical cool chamber containing water tested in Kolkata, India under an ambient temperature of 34.5–35 °C, the cooling effect reached a maximum of 7 °C between 3 and 3:30 PM and then declined to 4.5 °C around 6 PM.     

Salt marsh restoration: an overview of techniques and success indicators

Environmental Science and Pollution Research - Coastal wetlands including salt marshes are among the most productive ecosystems on Earth. They are known for improving the quality of coastal water...     

Nexus between indigenous ecological knowledge and ecosystem services: a socio-ecological analysis for sustainable ecosystem management

Environmental Science and Pollution Research - The well-being of the human society cannot be ensured and sustainable unless the flow of Ecosystem Services (ESs) would be matching with their...