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71.
Uncertainty based optimal monitoring network design for a chlorinated hydrocarbon contaminated site 总被引:1,自引:0,他引:1
Sreenivasulu Chadalavada Bithin Datta Ravi Naidu 《Environmental monitoring and assessment》2011,173(1-4):929-940
An application of a newly developed optimal monitoring network for the delineation of contaminants in groundwater is demonstrated in this study. Designing a monitoring network in an optimal manner helps to delineate the contaminant plume with a minimum number of monitoring wells at optimal locations at a contaminated site. The basic principle used in this study is that the wells are installed where the measurement uncertainties are minimum at the potential monitoring locations. The development of the optimal monitoring network is based on the utilization of contaminant concentration data from an existing initial arbitrary monitoring network. The concentrations at the locations that were not sampled in the study area are estimated using geostatistical tools. The uncertainty in estimating the contaminant concentrations at such locations is used as design criteria for the optimal monitoring network. The uncertainty in the study area was quantified by using the concentration estimation variances at all the potential monitoring locations. The objective function for the monitoring network design minimizes the spatial concentration estimation variances at all potential monitoring well locations where a monitoring well is not to be installed as per the design criteria. In the proposed methodology, the optimal monitoring network is designed for the current management period and the contaminant concentration data estimated at the potential observation locations are then used as the input to the network design model. The optimal monitoring network is designed for the consideration of two different cases by assuming different initial arbitrary existing data. Three different scenarios depending on the limit of the maximum number of monitoring wells that can be allowed at any period are considered for each case. In order to estimate the efficiency of the developed optimal monitoring networks, mass estimation errors are compared for all the three different scenarios of the two different cases. The developed methodology is useful in coming up with an optimal number of monitoring wells within the budgetary limitations. The methodology also addresses the issue of redundancy, as it refines the existing monitoring network without losing much information of the network. The concept of uncertainty-based network design model is useful in various stages of a potentially contaminated site management such as delineation of contaminant plume and long-term monitoring of the remediation process. 相似文献
72.
Amit Kumar Manoj Datta Arvind K. Nema R. K. Singh 《Environmental Modeling and Assessment》2016,21(4):489-505
Leachate emission from uncontrolled municipal solid waste landfills (referred to as waste sites in the present study) is a major threat to the environment and living beings in its vicinity. Surface water contamination potential resulting from leachate may be used as one of the criteria for prioritization of sites for remediation purposes. The existing hazard rating systems that prioritize waste sites considering surface water contamination potential as one of the criteria are mainly suited for the developed countries where these were developed initially. In developing countries like India, the set of conditions differ from those in developed countries, and therefore the existing systems may not be suitable for developing countries. Thus in the present study, an improved system is proposed to assess surface water contamination potential from MSW sites. The system is based on the concept of Source, Pathway and Receptor. The proposed system employs parameters derived from the review of existing rating systems and selects their best and worst values based on literature review, design standards and field conditions. The importance weights of the system parameters have been decided based on expert judgment using Delphi technique. Sensitivity analysis of the system shows that the improved system is more sensitive than the existing systems for the site conditions encountered in developing countries. Monte Carlo analysis of the proposed system confirms the spread of the scores obtained from the system over the full scale of 0–1000. The improved system is compared with existing systems by applying it to waste sites from metropolitan cities of India and performing clustering analysis on the rating scores. The clustering analysis shows that the rating scores from the improved system are less clustered as compared to the scores from the existing systems. This demonstrates that the improved system makes a better tool to distinctly prioritize the waste sites for remediation purpose. 相似文献
73.
Sarkar D Ferguson M Datta R Birnbaum S 《Environmental pollution (Barking, Essex : 1987)》2005,136(1):187-195
Two methods of biostimulation were compared in a laboratory incubation study with monitored natural attenuation (MNA) for total petroleum hydrocarbon (TPH) degradation in diesel-contaminated Tarpley clay soil with low carbon content. One method utilized rapid-release inorganic fertilizers rich in N and P, and the other used sterilized, slow-release biosolids, which added C in addition to N and P. After 8 weeks of incubation, both biostimulation methods degraded approximately 96% of TPH compared to MNA, which degraded 93.8%. However, in the first week of incubation, biosolids-amended soils showed a linear two orders of magnitude increase in microbial population compared to MNA, whereas, in the fertilizer-amended soils, only a one order of magnitude increase was noted. In the following weeks, microbial population in the fertilizer-amended soils dropped appreciably, suggesting a toxic effect owing to fertilizer-induced acidity and/or NH(3) overdosing. Results suggest that biosolids addition is a more effective soil amendment method for biostimulation than the commonly practiced inorganic fertilizer application, because of the abilities of biosolids to supplement carbon. No statistically significant difference was observed between the biostimulation methods and MNA, suggesting that MNA can be a viable remediation strategy in certain soils with high native microbial population. 相似文献
74.
Singh Simranjeet Kumar Vijay Datta Shivika Dhanjal Daljeet Singh Singh Satyender Kumar Sanjay Kapoor Dhriti Prasad Ram Singh Joginder 《Environmental science and pollution research international》2021,28(30):40233-40248
Environmental Science and Pollution Research - Metalloids are a subset of particular concern to risk assessors and toxicologists because of their well-documented potential hazards to plant system.... 相似文献
75.
Raj Kumar Singh Manoj Datta Arvind Kumar Nema 《Journal of environmental management》2009,90(2):344-357
In developing countries, several unregulated landfills exist adjacent to large cities, releasing harmful contaminants to the underlying aquifer. Normally, landfills are constructed to hold three types of waste, namely hazardous waste, municipal solid waste, and construction and demolition waste. Hazardous waste and municipal solid waste landfills are of greater importance as these pose greater hazard to groundwater, in comparison with landfills holding waste from construction and demolition. The polluting landfills need to be prioritized to undertake necessary control and remedial measures. This paper assesses existing site hazard rating systems and presents a new groundwater contamination hazard rating system for landfills, which can be used for site prioritization. The proposed system is based on source-pathway-receptor relationships and evaluates different sites relative to one another. The system parameters have been selected based on literature. The Delphi technique is used to derive the relative importance weights of the system parameters. The proposed system is compared with nine existing systems. The comparison shows that the site hazard scores produced by the existing systems for hazardous waste, municipal solid waste, and construction and demolition waste landfills are of the same order of magnitude and tend to overlap each other but the scores produced by the proposed system for the three types of landfills vary almost by an order of magnitude, which shows that the proposed system is more sensitive to the type of waste. The comparison further shows that the proposed system exhibits greater sensitivity also to varied site conditions. The application of different systems to six old municipal solid waste landfills shows that whereas the existing systems produce clustered scores, the proposed system produces significantly differing scores for all the six landfills, which improves decision making in site ranking. This demonstrates that the proposed system makes a better tool for prioritization of landfills for adopting control measures and remediation. 相似文献
76.
The types, frequency, and intensity of human interference with forests markedly affect the vegetation dynamics. Assessment of the impact of anthropogenic disturbances on forest diversity and structure is one of the central issues related to human behaviour and forest ecosystems and management. Both species diversity and density are very sensitive to local anthropogenic disturbance, which can be reduced depending on land-use systems. We used 10 line transects of 500 × 10 m to record and measure all plants ≥10 cm girth in some of the remaining forests surrounding villages in Tripura, Northeast India. To predict the effects of anthropogenic pressure on species richness and forest structure, we recorded and scored all ongoing disturbances in all transects of the forests. Although our study did not show any significant effects on the mean number of species, all diversity indices were significantly affected by disturbance. Total stem density (F = 128.60, p < 0.0001) and basal area (F = 65.30, p < 0.0001) of the forest stands were significantly affected by disturbance. Disturbance significantly (F = 84.81, p < 0.0001) impacts the abundance of mature voluminous trees removed by extensive illegal logging. Further, stem density at the middle (F = 10.01, p < 0.05) and upper (F = 131.70, p < 0.0001) canopy stories was also reduced by high disturbance intensity. The present analysis will be useful to policy-makers and planners for implementation of sustainable forest management at both the local and regional scale. 相似文献
77.
Santosh K. Deshmukh Anil Kumar Singh Siba Prasad Datta K. Annapurna 《Environmental monitoring and assessment》2011,175(1-4):601-612
Impact of wastewater irrigation on some biological properties was studied in an area where treated sewage water is being supplied to the farmers since 1979 in the western part of National Capital Territory of New Delhi under Keshopur Effluent Irrigation Scheme. Three fields were selected which had been receiving irrigation through wastewater for last 20, 10 and 5 years. Two additional fields were selected in which the source of irrigation water was tubewell. The soil bacterial and fungal population density was studied in soil layers of 0?C15, 15?C30, 30?C60 and 60?C120 cm depths. Groundwater samples were collected from the piezometers installed in the field irrigated with sewage water for last 20, 10 and 5 years. Results indicate that there was significant increase in bacterial and fungal count in sewage-irrigated soils as compared to their respective control. The population density of bacteria and fungi in waste water-irrigated soils increased with the duration of sewage water application and decreased with increasing depth. The bacterial and fungal count was also directly proportional to organic carbon, sand and silt content and negatively correlated to the clay content, electrical conductivity, pH and bulk density of the soil. Groundwater under sewage-irrigated fields had higher values of most probable number (MPN) index as compared to that of tubewell water-irrigated fields. All the shallow and deep groundwaters were found to be contaminated with faecal coliforms. The vadose zone had filtered the faecal coliform to the tune of 98?C99%, as the MPN index was reduced from ??18,000 per 100 ml of applied waste water to 310 per 100 ml of groundwater under 20 years sewage-irrigated field. The corresponding values of MPN were 250 and 130 per 100 ml of shallow groundwater under 10 and 05 years sewage-irrigated fields, respectively. Rapid detection of faecal contamination suggested that the Citrobacter freundii and Salmonella were dominant in shallow groundwater, while Escherichia coli was dominant in deep groundwater collected from sewage-irrigated field. 相似文献
78.
Although organoarsenical pesticides are being phased out, sites with high concentrations of organic arsenical residues still exist due to the long-term application of these pesticides. The biotic and abiotic speciation of dimethylarsinic acid (DMA) can result in the formation of inorganic arsenic (As) species. Oxidation state, retention, and thereby persistence, varies according to temporal changes, influencing the availability and toxicity of contaminants. The current greenhouse study aimed at evaluating temporal changes in the oxidation state of As, geochemical partitioning, and bioaccessibility. Four soils with varying physiochemical properties were contaminated with DMA at two concentrations (675 and 1500 mg kg−1 of As). Rice plants were grown for a 6 months period, following which, the soils were allowed to age. The operationally defined forms of As and its bioaccessibility was analyzed at 0, 6 months, 1 year, and 3 years. Changes in oxidation state of As were evaluated immediately after spiking and after 3 years of soil-pesticide equilibration. Results show that geochemical partitioning of As was affected significantly (P < 0.05) by soil type, loading rates, and equilibration time. Arsenic was bound mainly to the poorly-crystalline Fe/Al-oxyhydroxides in the soil. However, these interactions did not affect As bioaccessibility, presumably due to the dissolution of the bound fractions of As in the acidic stomach. While 74-94% of the total bioaccessible As was transformed to As(V), 4-19% was transformed to the more toxic As(III). This study indicates that although aging affected the geochemical partitioning of As in the soil, bioaccesibility was controlled by the gastric pH. 相似文献
79.
Effluents originating from pesticides, agro-chemicals, textile dyes and dyestuffs industries are always associated with high
turbidity, colour, nutrient load, and heavy metals, toxic and persistent compounds. But even with such an anthropogenic nature,
these effluents contain dynamic cyanobacterial communities. Documentation of cyanobacterial cultures along the water channels
of effluents discharged by above mentioned industries along the west coast of India and their relationship with water quality
is reported in this study. Intensity of pollution was evaluated by physico-chemical analysis of water. Higher load of solids,
carbon and nutrients were found to be persistent throughout the analysis. Sediment and water samples were found to be colored
in nature. Cyanobacterial community structure was found to be influenced by the anthropogenic pollution. 40 different cyanobacterial
species were recorded from 14 genera of 5 families and an elevated occurrence of Phormidium, Oscillatoria and Chroococcus genera was observed in all the sampling sites. 相似文献
80.
Somani Mohit Datta Manoj Ramana G. V. Hölzle Ingo Sundaram Ravi Sreekrishnan T. R. 《Journal of Material Cycles and Waste Management》2022,24(5):1902-1912
Journal of Material Cycles and Waste Management - This study characterizes the municipal solid waste (MSW) accumulated for more than 25 years at Bhalswa dumpsite, Delhi, India. 50... 相似文献