PM2.5 source apportionment: reconciling receptor models for U.S. nonurban and urban long-term networks

Chemical mass balance (CMB) and trajectory receptor models were applied to speciated particulate matter with aerodynamic diameter < or =2.5 microm (PM2.5) measurements from Speciation Trends Network (STN; part of the Chemical Speciation Network [CSN]) and Interagency Monitoring of Protected Visual Environments (IMPROVE) monitoring network across the state of Minnesota as part of the Minnesota PM2.5 Source Apportionment Study (MPSAS). CMB equations were solved by the Unmix, positive matrix factorization (PMF), and effective variance (EV) methods, giving collective source contribution and uncertainty estimates. Geological source profiles developed from local dust materials were either incorporated into the EV-CMB model or used to verify factors derived from Unmix and PMF. Common sources include soil dust, calcium (Ca)-rich dust, diesel and gasoline vehicle exhausts, biomass burning, secondary sulfate, and secondary nitrate. Secondary sulfate and nitrate aerosols dominate PM2.5 mass (50-69%). Mobile sources outweigh area sources at urban sites, and vice versa at rural sites due to traffic emissions. Gasoline and diesel contributions can be separated using data from the STN, despite significant uncertainties. Major differences between MPSAS and earlier studies on similar environments appear to be the type and magnitude of stationary sources, but these sources are generally minor (<7%) in this and other studies. Ensemble back-trajectory analysis shows that the lower Midwestern states are the predominant source region for secondary ammoniated sulfate in Minnesota. It also suggests substantial contributions of biomass burning and soil dust from out-of-state on occasions, although a quantitative separation of local and regional contributions was not achieved in the current study. Supplemental materials are available for this article. Go to the publisher's online edition of the Journal of the Air & Waste Management Association for a summary of input data, Unmix and PMF factor profiles, and additional maps.     

Accumulation of 14C-trinitrotoluene and related nonextractable (bound) residues in Eisenia fetida

To determine if trinitrotoluene (TNT) forms nonextractable residues in earthworms and to measure the relative degree of accumulation as compared to TNT and its deaminated metabolites, Eisenia fetida was exposed to ¹⁴C-TNT using dermal contact to filter paper or exposure to soil. Nonextractable residues made up 32-68% of total body burden depending on exposure media and depuration time. Parent TNT accounted for less than 3% of radioactivity, while ADNTs accounted for 7-38%. Elimination half-lives were 61-120 h for TNT, ADNTs, and DANTs, which was significantly lower than the half-lives found for nonextractable residues, 201-240 h. However, over 80% of the nonextractable residue was solubilized using weak acid (pH 2). Based on our findings that TNT accumulation occurs primarily as nonextractable residues, which have a longer half-life, and that nonextractable residues can be solubilized, we propose that nonextractable residues could be used as a selective biomarker for assessing TNT contamination.     

Arsenic tolerances in rice (Oryza sativa) have a predominant role in transcriptional regulation of a set of genes including sulphur assimilation pathway and antioxidant system

World wide arsenic (As) contamination of rice has raised much concern as it is the staple crop for millions. Four most commonly cultivated rice cultivars, Triguna, IR-36, PNR-519 and IET-4786, of the West Bengal region were taken for a hydroponic study to examine the effect of arsenate (As^V) and arsenite (As^III) on growth response, expression of genes and antioxidants vis-à-vis As accumulation. The rice genotypes responded differentially under As^V and As^III stress in terms of gene expression and antioxidant defences. Some of the transporters were up-regulated in all rice cultivars at lower doses of As species, except IET-4786. Phytochelatin synthase, GST and γ-ECS showed considerable variation in their expression pattern in all genotypes, however in IET-4786 they were generally down-regulated in higher As^III stress. Similarly, most of antioxidants such as superoxide dismutase (SOD), ascorbate peroxidase (APX), guaiacol peroxidase (GPX), catalase (CAT), monodehydroascorbate reductase (MDHAR) and dehydroascorbate reductase (DHAR) increased significantly in Triguna, IR-36 and PNR-519 and decreased in IET-4786. Our study suggests that Triguna, IR-36 and PNR-519 are tolerant rice cultivars accumulating higher arsenic; however IET-4786 is susceptible to As-stress and accumulates less arsenic than other cultivars.     

Evaluation of Kraft Process Pollution Abatement Strategies by Time Series Analysis of Makeup Records

A historical record of monthly chemical makeups for a North American pulp mill has been analyzed by time series methods. The analysis yields estimates for the reduction in sulfur makeup resulting from each of three separate pollution abatement moves: black liquor oxidation, blow heat recovery, and cooking liquor sulfidity reduction. Further analysis yields estimates of sulfurous emissions and of the substantially lower emissions which could have been achieved if sulfidity management had been incorporated in the program.     

Bibliometric investigation of the integration of animal personality in conservation contexts

Consistent individual differences in behavior, commonly termed animal personality, are a widespread phenomenon across taxa that have important consequences for fitness, natural selection, and trophic interactions. Animal personality research may prove useful in several conservation contexts, but which contexts remains to be determined. We conducted a structured literature review of 654 studies identified by combining search terms for animal personality and various conservation subfields. We scored the relevance of personality and conservation issues for each study to identify which studies meaningfully integrated the 2 fields as opposed to surface-level connections or vague allusions. We found a taxonomic bias toward mammals (29% of all studies). Very few amphibian or reptile studies applied personality research to conservation issues (6% each). Climate change (21%), invasive species (15%), and captive breeding and reintroduction (13%) were the most abundant conservation subfields that occurred in our search, though a substantial proportion of these papers weakly integrated conservation and animal personality (climate change 54%, invasive species 51%, captive breeding and reintroduction 40%). Based on our results, we recommend that researchers strive for consistent and broadly applicable terminology when describing consistent behavioral differences to minimize confusion and improve the searchability of research. We identify several gaps in the literature that appear to be promising and fruitful avenues for future research, such as disease transmission as a function of sociability or exploration as a driver of space use in protected areas. Practitioners can begin informing future conservation efforts with knowledge gained from animal personality research.     

Integrating switchgear breakers and contactors into a safety instrumented function

In the process industries, electrical circuit breakers are tripped for a variety of reasons including hazard prevention and mitigation. This paper will discuss the application of tripping electrical breakers for process safety reasons. It often occurs that a risk assessment study has determined the need to include the shutdown of a large electric motor as part of a safety instrumented function (SIF). In the process industries, it is common practice to control and protect large horsepower motors (typically 2000 HP and above), with medium-voltage switchgear breakers. Safety instrumented functions that include electric motors utilizing medium-voltage switchgear for tripping have unique final element subsystems, which require specialized knowledge in order to implement correctly. This paper will discuss the design considerations for integrating medium-voltage switchgear used for shutdown of an electric motor into a safety instrumented function. First, an overview of typical low and medium-voltage electrical equipment used for controlling and protecting electric motors will be discussed. Next, a review of generic sourced failure data for medium-voltage switchgear breakers will be presented. Focus will be on the taxonomy used to classify different breaker types and the relevant failure modes and effects used for quantifying performance. Next, specific SIF design details for tripping medium-voltage switchgear breakers will be analyzed in the context of achieving a certain integrity level. Parameters to be considered include hardware fault tolerance requirements, voting, available diagnostics, energize vs. de-energize to trip shutdown circuits, certified equipment vs. proven-in-use, and alternate means of shutdown (including manual intervention and protective relaying). This paper will also analyze the common electrical equipment that is shared among potential protection layers used to trip the same breaker, and determine how much credit can be taken considering common cause failure. Finally, inspection, test, and preventive maintenance (ITPM) of medium-voltage switchgear will be discussed as a means for maintaining the electrical equipment in the “as good as new” condition.     

The limits to risk aversion: Part 2: The permission point and worked examples

Part 2 extends the analysis to show that it is possible to find the “permission point”, the value of (the coefficient of relative) risk-aversion, at which decisions to sanction environmental protection are most likely to be made. The mathematical model describes the process by which the decision maker varies his risk-aversion over a range of feasible values to find the risk-aversion that will give him the greatest desire to invest in the protection system under consideration. If he can find such a risk-aversion before losing discrimination (because the system is too expensive, given its performance), he will adopt it as his “permission point” and decide in favour of the expenditure. The permission point is, of course, bounded above by the point of indiscriminate decision. A maximum Risk Multiplier calculated at the point of indiscriminate decision may be applied to the protection expenditure at monetary break-even to give the maximum, rational outlay on protection. Moreover, it is possible to model how the average UK adult should take decisions on protection to maximise his utility. Different situations will call for different values of risk-aversion, which may explain why economists have come up with differing estimates of this parameter in the past. However, a central, average risk-aversion may be calculated for the average UK adult as 0.85, which is within 4% of the value, 0.82, found from the newly reported method based on a trade-off between income and future free time, and is consistent with several recent economic estimates. Worked examples assess how much an organisation should spend on a protection scheme to prevent accidents with very large environmental consequences.     

Status and trends of circumpolar peregrine falcon and gyrfalcon populations

Ambio - The peregrine falcon (Falco peregrinus) and the gyrfalcon (Falco rusticolus) are top avian predators of Arctic ecosystems. Although existing monitoring efforts are well established for both...     

Impact of an Extreme Flood Event on Streambank Retreat: Cedar River,Nebraska, USA

The 2010 dam breach and consequent anomalous flood event on the Cedar River in Nebraska, USA provided an opportunity to study the following objectives: (1) evaluate the impact of an extreme flood event on streambank retreat along a 45 km stretch relative to the average annual retreat; (2) quantify the changes in streambank retreat for each km segment downstream of the breach; and (3) examine the influence of riparian vegetation and radius of curvature on meander bank erosion rate. During the hydrologic event, discharge peaked at nearly three times greater than the next highest recorded rate and equated to a return period of 2,000 years. Aerial images and ArcGIS were utilized to calculate the average annual streambank retreat for each year during the preflood (2006–2010), flood (2010), and postflood (2010–2016) periods. The 2010 flood period had a significantly higher average annual streambank retreat of 2,820 m²/km/yr than the preflood and postflood periods, which, respectively, measured 576 and 384 m²/km/yr. From 2006 to 2016, 29% of all streambank erosion was from this one extreme flood event, thus demonstrating the impact that one extreme flood event can have on streambank retreat and the geomorphology of a stream system.     

Mason Valley Groundwater Model: Linking Surface Water and Groundwater in the Walker River Basin,Nevada1

Carroll, Rosemary W.H., Greg Pohll, David McGraw, Chris Garner, Anna Knust, Doug Boyle, Tim Minor, Scott Bassett, and Karl Pohlmann, 2010. Mason Valley Groundwater Model: Linking Surface Water and Groundwater in the Walker River Basin, Nevada. Journal of the American Water Resources Association (JAWRA) 46(3):554-573. DOI: 10.1111/j.1752-1688.2010.00434.x Abstract: An integrated surface water and groundwater model of Mason Valley, Nevada is constructed to replicate the movement of water throughout the different components of the demand side of water resources in the Walker River system. The Mason Valley groundwater surface water model (MVGSM) couples the river/drain network with agricultural demand areas and the groundwater system using MODFLOW, MODFLOW’s streamflow routing package, as well as a surface water linking algorithm developed for the project. The MVGSM is capable of simulating complex feedback mechanisms between the groundwater and surface water system that is not dependent on linearity among the related variables. The spatial scale captures important hydrologic components while the monthly stress periods allow for seasonal evaluation. A simulation spanning an 11-year record shows the methodology is robust under diverse climatic conditions. The basin-wide modeling approach predicts a river system generally gaining during the summer irrigation period but losing during winter months and extended periods of drought. River losses to the groundwater system approach 25% of the river’s annual budget. Reducing diversions to hydrologic response units will increase river flows exiting the model domain, but also has the potential to increase losses from the river to groundwater storage.