Planning‐level source decay models to evaluate impact of source depletion on remediation time frame

A recent United States Environmental Protection Agency (US EPA) Expert Panel on Dense Nonaqueous Phase Liquid (DNAPL) Source Remediation concluded that the decision‐making process for implementing source depletion is hampered by quantitative uncertainties and that few useful predictive tools are currently available for evaluating the benefits. This article provides a new planning‐level approach to aid the process. Four simple mass balance models were used to provide estimates of the reduction in the remediation time frame (RTF) for a given amount of source depletion: step function, linear decay, first‐order decay, and compound. As a shared framework for assessment, all models use the time required to remediate groundwater concentrations below a particular threshold (e.g., goal concentration or mass discharge rate) as a metric. This value is of interest in terms of providing (1) absolute RTF estimates in years as a function of current mass discharge rate, current source mass, the remediation goal, and the source‐ reduction factor, and (2) relative RTF estimates as a fraction of the remediation time frame for monitored natural attenuation (MNA). Because the latter is a function of the remediation goal and the remaining fraction (RF) of mass following remediation, the relative RTF can be a valuable aid in the decision to proceed with source depletion or to use a long‐term containment or MNA approach. Design curves and examples illustrate the nonlinear relationship between the fraction of mass remaining following source depletion and the reduction in the RTF in the three decay‐based models. For an example case where 70 percent of the mass was removed by source depletion and the remediation goal (C_g/C₀) was input as 0.01, the improvement in the RTF (relative to MNA) ranged from a 70 percent reduction (step function model) to a 21 percent reduction (compound model). Because empirical and process knowledge support the appropriateness of decay‐based models, the efficiency of source depletion in reducing the RTF is likely to be low at most sites (i.e., the percentage reduction in RTF will be much lower than the percentage of the mass that is removed by a source‐depletion project). Overall, the anticipated use of this planning model is in guiding the decision‐making process by quantifying the relative relationship between RTF and source depletion using commonly available site data. © 2005 Wiley Periodicals, Inc.     

Field demonstration of the combined effects of absorption and evapotranspiration on septic system drainfield capacity.

Drainfields for disposal of septic tank effluents are typically designed by considering the loss of water by either upward evapotranspiration into the atmosphere or lateral and downward absorption into the adjacent soil. While this approach is appropriate for evapotranspiration systems, absorption systems allow water loss by both mechanisms. It was proposed that, in areas where high evapotranspiration rates coincide with permeable soils, drainfield sizes could be substantially reduced by accounting for both mechanisms. A two-year field demonstration was conducted to determine appropriate design criteria for areas typical of the Texas High Plains. The study consisted of evaluating the long-term acceptance rates for three different drainfield configurations: evapotranspiration only, absorption only, and combined conditions. A second field demonstration repeated the experiments for additional observation of the combined evapotranspiration and absorption and achieved similar results as the first study. The field tests indicated that the current design loading criteria may be increased by at least a factor of two for the Texas High Plains region and other Texas areas with similar soil composition and evapotranspiration rates, while still retaining a factor of safety of two.     

Nitrous oxide (N2O) emissions from waste and biomass to energy plants.

Following the Kyoto protocol with respect to reducing emissions of greenhouse gases emissions, and EU energy policy and sustainability in waste management, there has been an increased interest in the reduction of emissions from waste disposal operations. From the point of view of nitrous oxide (N2O) emissions, waste incineration and waste co-combustion are very acceptable methods for waste disposal. In order to achieve very low N2O emissions from waste incineration, particularly for waste with higher nitrogen content (e.g. sewage sludge), two factors are important: temperature of incineration over 900 degrees C and avoiding the selective non-catalytic reduction (SNCR) de-NO(X) method based on urea or ammonia treatments. The more modern selective catalytic reduction (SCR) systems for de-NO(X) give rise to negligible sources of N2O.     

Role of amniotic fluid interphase fluorescence in situ hybridization (FISH) analysis in patient management

We retrospectively reviewed 309 amniotic fluid interphase fluorescence in situ hybridization (FISH) analyses performed from October 1995 to June 1999 to assess the role of interphase FISH in the management of patients at increased risk for fetal aneuploidies. Gestational age and indications for amniocentesis, clinical interventions after FISH results, as well as interventions after final culture reports were analyzed. There were 244 (79%) normal, 50 (16%) abnormal and 15 (5%) inconclusive FISH results. There were no false-positive or false-negative results, but there were nine (3%) clinically significant chromosomal abnormalities not detectable by FISH. Of the 50 women with abnormal FISH results, 26 (52%) elected to terminate the pregnancy prior to the availability of the standard chromosome analysis. In two of the fetuses with trisomy 21 no abnormalities were reported by ultrasound examination. Our experience indicates that interphase FISH results played an important role in decision making, especially for pregnancies close to 24 weeks' gestation. Standard karyotype analysis is still required for detection of chromosome abnormalities not detectable by interphase FISH techniques and for clarification of unusual or inconclusive FISH results. Copyright © 2001 John Wiley & Sons, Ltd.     

VALUE OF WOODY RWER CORRIDORS IN LEVEE PROTECTION ALONG THE MISSOURI RWER IN 19931

ABSTRACT: Following the Midwest flood of 1993, a study was initiated along a 39-mile segment of the Missouri River to determine if there was an association between woody corridors and levee stability. A systematic sample of levee failures revealed that primary levees which did not fail had a significantly wider woody corridor than failed levees. Analysis of the total inventory of failed levees revealed that as the width of the woody corridor decreased, the length of the levee failure increased. Number of levee failures and their severity of damage could be reduced if woody corridors were at least 300 feet wide.     

Influence of flue-gas desulfurization systems on coal combustion by-product quality at kentucky power stations burning high-sulfur coal

Two Kentucky power plants burning similar blends of high-sulfur western Kentucky and southern Indiana coal provide a unique opportunity to examine the variations in coal combustion by-products due to differences in the method of wet flue-gas desulfurization (FGD). One plant employed carbide lime-based scrubbing for two units and a dual-alkali process for the third unit. The second plant employed a Mississippian limestone from Kentucky for all four units. This study provides an example of optical and SEM petrographic techniques, supplemented by chemical analyses, applied to the study of, at least from the geologic perspective, non-traditional materials. The coal sources comprise a blend of high volatile C and B bituminous, high vitrinite (85–90%, mmf), high-sulfur (> 3%, dry) coals. The fly ash is dominated by glassy phases (70–80%) with about 5–10% spinel (predominately magnetite), 3–10% quartz, and 4–10% isotropic coke comprising the remaining portion of the ash. SEM observations indicate that the glassy particles exhibit a bimodal size distribution with sub-micron glass spheres and a population of larger (several 10s of microns) spheres. The bottom ash has higher proportions of spinels and mullite, with negligible carbon forms, compared to the fly ash from the same units. Fly ashes were observed to be lower in Fe and higher in Al, Si, and S compared to the bottom ashes. Carbide lime, a by-product of acetylene manufacture, soda ash, and limestone were the reagents used in the flue-gas desulfurization processes. The primary FGD by-product is a calcium sulfite slurry which is vacuum filtered and mixed with fly ash and, usually, lime, to form a stable product for disposal. The FGD by-products have some potential, as yet unrealized, for utilization.