全文获取类型
收费全文 | 20116篇 |
免费 | 282篇 |
国内免费 | 184篇 |
专业分类
安全科学 | 632篇 |
废物处理 | 824篇 |
环保管理 | 2963篇 |
综合类 | 3042篇 |
基础理论 | 5548篇 |
环境理论 | 12篇 |
污染及防治 | 4937篇 |
评价与监测 | 1348篇 |
社会与环境 | 1130篇 |
灾害及防治 | 146篇 |
出版年
2023年 | 105篇 |
2022年 | 177篇 |
2021年 | 157篇 |
2020年 | 155篇 |
2019年 | 171篇 |
2018年 | 311篇 |
2017年 | 360篇 |
2016年 | 485篇 |
2015年 | 371篇 |
2014年 | 595篇 |
2013年 | 1557篇 |
2012年 | 705篇 |
2011年 | 967篇 |
2010年 | 803篇 |
2009年 | 807篇 |
2008年 | 918篇 |
2007年 | 934篇 |
2006年 | 804篇 |
2005年 | 696篇 |
2004年 | 692篇 |
2003年 | 645篇 |
2002年 | 624篇 |
2001年 | 729篇 |
2000年 | 568篇 |
1999年 | 322篇 |
1998年 | 241篇 |
1997年 | 263篇 |
1996年 | 264篇 |
1995年 | 310篇 |
1994年 | 301篇 |
1993年 | 243篇 |
1992年 | 248篇 |
1991年 | 224篇 |
1990年 | 237篇 |
1989年 | 222篇 |
1988年 | 179篇 |
1987年 | 201篇 |
1986年 | 189篇 |
1985年 | 193篇 |
1984年 | 193篇 |
1983年 | 185篇 |
1982年 | 177篇 |
1981年 | 163篇 |
1980年 | 143篇 |
1979年 | 141篇 |
1978年 | 129篇 |
1977年 | 127篇 |
1975年 | 94篇 |
1973年 | 99篇 |
1972年 | 93篇 |
排序方式: 共有10000条查询结果,搜索用时 484 毫秒
821.
Global generation of human hair waste and its disposal at landfills could contribute to the leaching of nitrates into ground water. High concentrations of nitrogen (N) and other elements suggest that the waste could be a source of plant nutrients and differences in ethnic hair types could affect nutrient release and fertiliser value. The objective of this study was to determine the effects of hair type, as an N source, and pre-incubation time on dry-matter yield, nutrient uptake by spinach (Spinacia oleracea L.) and residual soil nutrients. Salons in Pietermaritzburg provided bulk African and Caucasian hair waste, without distinguishing age, sex, health status or livelihood of the individuals. The hair waste was analysed for elemental composition. A pot experiment was set up under glasshouse conditions. The hair waste was incorporated (400 kg N ha?1) into a loamy oxisol and pre-incubated for 0, 28, 56 and 84 days before planting spinach. Potassium (K) and phosphorus (P) were corrected to the same level for all treatments. Spinach seedlings were then cultivated for 6 weeks. Shoot dry-matter and the uptake of all nutrients, except P, were increased by the pre-incubation of hair. African hair pre-incubated for 28 days resulted in greater dry-matter, N, K, Mn and S uptake than Caucasian hair. Increasing pre-incubation resulted in a decline in the residual soil pH and exchangeable K. The findings suggested that pre-incubation improves the N fertiliser value of hair and that African hair has greater value than Caucasian hair when pre-incubated for a short period. 相似文献
822.
David C. Carslaw Paul S. Goodman Frank C.H. Lai Oliver M.J. Carsten 《Atmospheric environment (Oxford, England : 1994)》2010,44(23):2674-2680
In recent years sophisticated technologies have been developed to control vehicle speed based on the type of road the vehicle is driven on using Global Positioning Systems and in-car technology that can alter the speed of the vehicle. While reducing the speed of road vehicles is primarily of interest from a safety perspective, vehicle speed is also an important determinant of vehicle emissions and thus these technologies can be expected to have impacts on a range of exhaust emissions. This work analyses the results from a very large, comprehensive field trial that used 20 instrumented vehicles with and without speed control driven almost 500,000 km measuring vehicle speed at 10 Hz. We develop individual vehicle modal emissions models for CO2 for 30 Euro III and Euro IV cars at a 1-Hz time resolution. Generalized Additive Models were used to describe how emissions from individual vehicles vary depending on their driving conditions, taking account of variable interactions and time-lag effects. We quantify the impact that vehicle speed control has on-vehicle emissions of CO2 by road type, fuel type and driver behaviour. Savings in CO2 of ≈6% were found on average for motorway-type roads when mandatory speed control was used compared with base case conditions. For most other types of road, speed control has very little effect on emissions of CO2 and in some cases can result in increased emissions for low-speed limit urban roads. We also find that there is on average a 20% difference in CO2 emission between the lowest and highest emitting driver, which highlights the importance of driver behaviour in general as a means of reducing emissions of CO2. 相似文献
823.
Nicholas A. Martin Edward J. Leming Malcolm H. Henderson Robert P. Lipscombe John K. Black Scott D. Jarvis 《Atmospheric environment (Oxford, England : 1994)》2010,44(28):3378-3385
There is a requirement to verify the performance of sorbent-based passive or active samplers and to extend their use, where possible, to monitor volatile organic compounds (VOCs) that are known to be photochemical ozone pre-cursors or are relevant to the activities of the petrochemical industry. We report measurements of the 14-day diffusive uptake rates for the VOCs: i-butane (2-methyl propane), n-butane, i-pentane (2-methyl butane), n-pentane, n-hexane, benzene, toluene, and m-xylene (at environmental level concentrations) for industry standard axial samplers (Perkin–Elmer-type samplers) containing the sorbents Carbopack-X, -Z, -B or Tenax-TA. We also present data on back-diffusion, blank levels, and storage for the above sorbents, and describe the simultaneous use of the sorbent Carbopack-X for pumped sampling of certain VOCs. The results were obtained by dosing samplers in a controlled atmosphere test facility (CATFAC) operating under well-defined conditions of concentration, nominal temperature of 20 °C, wind speed of 0.5 m s?1, and relative humidities of 0% and 80%. Field measurements were also obtained to provide supplementary data to support the laboratory study. Results are compared to existing published data, where these are available. 相似文献
824.
C.V. Srinivas R. Venkatesan V. Yesubabu C. Nagaraju K.M. Somayajai P. Chellapandi Baldev Raj 《Atmospheric environment (Oxford, England : 1994)》2010,44(24):2846-2864
A mesoscale atmospheric model PSU/NCAR MM5 is used to provide operational weather forecasts for a nuclear emergency response decision support system on the southeast coast of India. In this study the performance of the MM5 model with assimilation of conventional surface and upper-air observations along with satellite derived 2-d surface wind data from QuickSCAT sources is examined. Two numerical experiments with MM5 are conducted: one with static initialization using NCEP FNL data and second with dynamic initialization by assimilation of observations using four dimensional data assimilation (FDDA) analysis nudging for a pre-forecast period of 12 h. Dispersion simulations are conducted for a hypothetical source at Kalpakkam location with the HYSPLIT Lagrangian particle model using simulated wind field from the above experiments. The present paper brings out the differences in the atmospheric model predictions and the differences in dispersion model results from control and assimilation runs. An improvement is noted in the atmospheric fields from the assimilation experiment which has led to significant alteration in the trajectory positions, plume orientation and its distribution pattern. Sensitivity tests using different PBL and surface parameterizations indicated the simple first order closure schemes (Blackadar, MRF) coupled with the simple soil model have given better results for various atmospheric fields. The study illustrates the impact of the assimilation of the scatterometer wind and automated weather stations (AWS) observations on the meteorological model predictions and the dispersion results. 相似文献
825.
David Widory Xiande Liu Shuping Dong 《Atmospheric environment (Oxford, England : 1994)》2010,44(30):3679-3687
Even after its being phased out in gasoline in the late 90s, lead (Pb) is still present at relatively high levels in the atmosphere of Beijing, China (0.10–0.18 μg m?3). Its origin is subject to debate as several distinct sources may contribute to the observed pollution levels. This study proposes to constrain the origin(s) of Pb and strontium (Sr) in aerosols, by coupling both Pb and Sr isotope systematics. The characterisation of the main pollution sources (road traffic, smelters, metal refining plants, coal combustion, cement factories, and soil erosion) shows that they can unambiguously be discriminated by the multi-isotope approach (206Pb/204Pb and 87Sr/86Sr). The study of total suspended particulates (TSP) and fine particles (PM2.5) from Beijing and its vicinity indicates that both size fractions are controlled by the same sources. Lead isotopes indicate that metal refining plants are the major source of atmospheric lead, followed by thermal power stations and other coal combustion processes. The role of this latter source is confirmed by the study of strontium isotopes. Occasionally, emissions from cement plants and/or input from soil alteration are isotopically detectable. 相似文献
826.
Jorge Pey Andrés Alastuey Xavier Querol Noemí Pérez Michael Cusack 《Atmospheric environment (Oxford, England : 1994)》2010,44(39):5112-5121
The present work shows a straightforward procedure to indirectly estimate the chemical composition at a given site only from the determination of the PM concentrations, and the classification of the days according to the main meteorological scenarios. A previous study based on the mean chemical composition associated to the main meteorological scenarios is required.This experiment has been carried out with data from two monitoring sites in the North-Western Mediterranean, one regional and one suburban background. At both sites, one-year datasets on chemical PM10 composition were obtained. Based on these datasets, the mean PM10 compositions according to the most relevant meteorological situations were calculated for both locations. After that, the reconstruction of the chemical composition for all the days with available PM10 concentrations was completed. Subsequently, the estimated PM10 composition was compared with that determined experimentally. The comparison between the rebuilt and the experimental results was very satisfactory in the case of the regional background site, and relatively replaced in the other case. Furthermore, the validation of the method at the regional background site has been conducted from the reconstruction of a 4-year data base, and subsequent comparison with the experimental chemical composition.Our results show that it is possible to attain a good approach to the chemical composition at regional background sites, where local emission sources are negligible. Conversely, when the local sources rise in importance, i.e., at a suburban background site, the approach is suitable only for those components with a more regional origin and/or those from long range transport of air masses. 相似文献
827.
L.-W. Antony Chen John G. Watson Judith C. Chow David W. DuBois Lisa Herschberger 《Atmospheric environment (Oxford, England : 1994)》2010,44(38):4908-4918
The Minnesota Particulate Matter 2.5 (PM2.5) Source Apportionment Study was undertaken to explore the utility of PM2.5 mass, element, ion, and carbon measurements from long-term speciation networks for pollution source attribution. Ambient monitoring data at eight sites across the state were retrieved from the archives of the Interagency Monitoring of Protected Visual Environments (IMPROVE) and the Speciation Trends Network (STN; part of the Chemical Speciation Network [CSN]) and analyzed by an Effective Variance – Chemical Mass Balance (EV-CMB) receptor model with region-specific geological source profiles developed in this study. PM2.5 was apportioned into contributions of fugitive soil dust, calcium-rich dust, taconite (low grade iron ore) dust, road salt, motor vehicle exhaust, biomass burning, coal-fired utility, and secondary aerosol. Secondary sulfate and nitrate contributed strongly (49–71% of PM2.5) across all sites and was dominant (≥60%) at IMPROVE sites. Vehicle exhausts accounted for 20–70% of the primary PM2.5 contribution, largely exceeding the proportion in the primary PM2.5 emission inventory. The diesel exhaust contribution was separable from the gasoline engine exhaust contribution at the STN sites. Higher detection limits for several marker elements in the STN resulted in non-detectable coal-fired boiler contributions which were detected in the IMPROVE data. Despite the different measured variables, analytical methods, and detection limits, EV-CMB results from a nearby IMPROVE-STN non-urban/urban sites showed similar contributions from regional sources – including fugitive dust and secondary aerosol. Seasonal variations of source contributions were examined and extreme PM2.5 episodes were explained by both local and regional pollution events. 相似文献
828.
Kelly P. Grogan Robert A. Fjeld Timothy A. DeVol 《Journal of environmental radioactivity》2010,101(10):847-853
The effect of the spatial variability of Kd on calculations of contaminant travel time in the vadose zone was determined. Depth discrete measurements of Kd were made for a suite of radionuclides (109Cd, 57Co, 60Co, 85Sr, 137Cs, and 88Y) utilizing a sediment core from the E-Area at the Savannah River Site. The Kd’s were ordered as 85Sr2+ < 137Cs+ < 109Cd2+ < 57Co2+ = 60Co2+ << 88Y3+ and the values generally fell below or near the lowest quartile of values reported in the literature. Correlations were generally weak between soil properties and Kd values. Most importantly, all of the Kd distributions could be reasonably approximated as log-normal. Deterministic and stochastic calculations of contaminant travel time to the water table were made. The deterministic calculations were based on each of three conceptual models of the vadose zone: complete stratification (17 strata, each with a different Kd), two strata (two sections of the vadose zone, each characterized by a single, average Kd), and unstratified (a single zone with an average Kd). Stochastic calculations were based on log-normal fits to the Kd data. The two strata model generally yielded travel times 2× greater than those in the completely stratified model. The unstratified model yielded travel times that were between 3 and 5 times greater than the completely stratified model. The stochastic mean travel times were comparable to those of the two strata model. 相似文献
829.
Significantly high radiation level and radionuclide concentration along Quilon beach area of coastal Kerala have been reported by several investigators. Detailed gamma radiation level survey was carried out using a portable scintillometer. Detailed studies on radionuclides concentration in different environmental matrices of high background areas were undertaken in the coastal areas of Karunagapalli, Kayankulam, Chavara, Neendakara and Kollam to study the distribution and enrichment of the radionuclides in the region. The absorbed gamma dose rates in air in high background area are in the range 43-17,400 nGyh−1. Gamma radiation level is found to be maximum at a distance of 20 m from the sea waterline in all beaches. The soil samples collected from different locations were analysed for primordial radionuclides by gamma spectrometry. The activity of primordial radionuclides was determined for the different size fractions of soil to study the enrichment pattern. The highest activity of 232Th and 226Ra was found to be enriched in 125-63 μ size fraction. The preferential accumulation of 40K was found in <63 μ fraction. The minimum 232Th activity was 30.2 Bq kg−1, found in 1000-500 μ particle size fraction at Kollam and maximum activity of 3250.4 Bq kg−1 was observed in grains of size 125-63 μ at Neendakara. The lowest 226Ra activity observed was 33.9 Bq kg−1 at Neendakara in grains of size 1000-500 μ and the highest activity observed was 482.6 Bq kg−1 in grains of size 125-63 μ in Neendakara. The highest 40K activity found was 1923 Bq kg−1 in grains of size <63 μ for a sample collected from Neendakara. A good correlation was observed between computed dose and measured dose in air. The correlation between 232Th and 226Ra was also moderately high. The results of these investigations are presented and discussed in this paper. 相似文献
830.