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271.
Gary Z. Whitten Gookyoung Heo Yosuke Kimura Elena McDonald-Buller David T. Allen William P.L. Carter Greg Yarwood 《Atmospheric environment (Oxford, England : 1994)》2010,44(40):5346-5355
Toluene is ubiquitous in urban atmospheres and is a precursor to tropospheric ozone and aerosol (smog). An important characteristic of toluene chemistry is the tendency of some degradation products (e.g., cresols and methyl-catechols) to form organic nitro and nitrate compounds that sequester NOx (NO and NO2) from active participation in smog formation. Explaining the NOx sinks in toluene degradation has made mechanism development more difficult for toluene than for many other organic compounds. Another challenge for toluene is explaining sources of radicals early in the degradation process. This paper describes the development of a new condensed toluene mechanism consisting of 26 reactions, and evaluates the performance of CB05 with this new toluene scheme (Toluene Update, TU) against 38 chamber experiments at 7 different environmental chambers, and provides recommendations for future developments. CB05 with the current toluene mechanism (CB05-Base) under-predicted the maximum O3 and O3 production rate for many of these toluene–NOx chamber experiments, especially under low-NOx conditions ([NOx]t=0 < 100 ppb). CB05 with the new toluene mechanism (CB05-TU) includes changes to the yields and reactions of cresols and ring-opening products, and showed better performance than CB05-Base in predicting the maximum O3, O3 formation rate, NOx removal rate and cresol concentration. Additional environmental chamber simulations with xylene–NOx experiments showed that the TU mechanism updates tended to improve mechanism performance for xylene. 相似文献
272.
273.
Caroline Lanier Estelle Richard Natacha Heutte Rachel Picquet Valérie Bouchart David Garon 《Atmospheric environment (Oxford, England : 1994)》2010,44(16):1980-1986
In agricultural areas, the contamination of feedstuffs with molds and mycotoxins presents major environmental and health concerns. During cattle feeding, fungi and mycotoxins were monitored in corn silage, oilseed cakes and bioaerosols collected in Normandy. Most of the corn silages were found to be contaminated by deoxynivalenol (mean concentration: 1883 μg kg?1) while a few of oilseed cakes were contaminated by alternariol, fumonisin B1 or gliotoxin. In ambient bioaerosols, the values for fungi per cubic meter of air varied from 4.3 × 102 to 6.2 × 105 cfu m?3. Seasonal variations were observed with some species like Aspergillus fumigatus which significantly decreased between the 2 seasons (P = 0.0186) while the Penicillium roqueforti group significantly increased during the second season (P = 0.0156). In the personal bioaerosols, the values for fungi per cubic meter of air varied from 3.3 103 to 1.7 106 cfu m?3 and the number of A. fumigatus spores significantly decreased between the 2 seasons (P = 0.0488). Gliotoxin, an immunosuppressive mycotoxin, was quantified in 3 personal filters at 3.73 μg m?3, 1.09 μg m?3 and 2.97 μg m?3. 相似文献
274.
Research into national innovation systems (NISs) has received extensive academic and policy attention, and is especially relevant
with latecomer countries seeking to innovate in challenging industrial environments. In playing catch up with their early
industrializing counterparts, methods of learning take on increased importance in determining industrial success for latecomers.
The wind turbine technology innovation system is one that is highly dependent on both the extent of the national learning
processes and the strength of the national social-institutional setting. This research investigates the case of Taiwan, a
country which has embarked on a program to build its national innovative capacity in wind turbine technologies with specific
emphasis on Taiwan’s social sector. Within this system, the spotlight will be on four types of learning processes that interplay
during wind turbine development: learning by searching, learning by doing, learning by using, and learning by interacting. Through a case study of the emergence of Taiwan’s burgeoning large-scale wind power technology initiatives, the paper aims
to add to the understanding on how methods of learning impact upon the success of innovation systems. The findings show that
the industry’s future prospects are constrained because of the limited learning by interacting processes between turbine component producers, turbine owners, and researchers and because of weaknesses in the institutional
framework. This research also recognizes the importance that culture has on dominant forms of learning. 相似文献
275.
Sex-biased predation is thought to have important implications for sexual selection, sex allocation, and population dynamics (Magnhagen, 1991; Le-Galliard et al., 2005 for an example in lizards). Most studies found that males are subjected to higher predation pressure than females during the reproductive season (Korpimäki, 1985; Lodé et al., 2004; Christe et al., 2006; Costantini et al., 2007). In that period, males are very mobile, emit acoustic signals and exhibit brilliant colourations, which are needed to attract females but may make them more visible to predators. With regard to lizards, a recent study provided the first evidence that males of a lizard species may be preyed on more than females (Costantini et al., 2007). In the present study, we investigated whether there is sex-biased predation on two small lacertid species, the common wall lizard Podarcis muralis (Laurenti, 1768) and the Italian wall lizard Podarcis sicula (Rafinesque-Schmaltz, 1810), by Eurasian kestrels (Falco tinnunculus) during the reproductive season. We also examined whether (1) the rate of predation differed between species and (2) the rate of predation differed across years or among hunting habitats for each species. 相似文献
276.
The 2001 National Land Cover Database (NLCD) provides 30-m resolution estimates of percentage tree canopy and percentage impervious
cover for the conterminous United States. Previous estimates that compared NLCD tree canopy and impervious cover estimates
with photo-interpreted cover estimates within selected counties and places revealed that NLCD underestimates tree and impervious
cover. Based on these previous results, a wall-to-wall comprehensive national analysis was conducted to determine if and how
NLCD derived estimates of tree and impervious cover varies from photo-interpreted values across the conterminous United States.
Results of this analysis reveal that NLCD significantly underestimates tree cover in 64 of the 65 zones used to create the
NCLD cover maps, with a national average underestimation of 9.7% (standard error (SE) = 1.0%) and a maximum underestimation
of 28.4% in mapping zone 3. Impervious cover was also underestimated in 44 zones with an average underestimation of 1.4% (SE = 0.4%)
and a maximum underestimation of 5.7% in mapping zone 56. Understanding the degree of underestimation by mapping zone can
lead to better estimates of tree and impervious cover and a better understanding of the potential limitations associated with
NLCD cover estimates. 相似文献
277.
Humans can dive with critically endangered grey nurse sharks (Carcharias taurus) along the east coast of Australia. This study investigated both compliance of tourist divers to a code of conduct and legislation
and the behaviour of grey nurse sharks in the presence of divers. A total of 25 data collection dives were conducted from
December 2008 to January 2009. Grey nurse shark and diver behaviour were documented using 2-min scan samples and continuous
observation. The proportion of time spent observing human–shark interactions was 9.4% of total field time and mean human–shark
interaction time was 15.0 min. Results were used to gauge the effectiveness of current management practices for the grey nurse
shark dive industry at Fish Rock in New South Wales, Australia. Grey nurse shark dive tourists were compliant to stipulations
in the code of conduct and legislation (compliance ranged from 88 to 100%). The research detailed factors that may promote
compliance in wildlife tourism operations such as the clarity of the stipulations, locality of the target species and diver
perceptions of sharks. Results indicated that grey nurse sharks spent the majority of their time milling (85%) followed by
active swimming (15%). Milling behaviour significantly decreased in the presence of more than six divers. Distance between
sharks and divers, interaction time and number of sharks were not significantly correlated with grey nurse shark school behaviour.
Jaw gaping, rapid withdrawal and stiff or jerky movement were the specific behaviours of grey nurse sharks that occurred most
frequently and were associated with distance between divers and sharks and the presence of six or more divers. Revision of
the number of divers allowed per interaction with a school of grey nurse sharks and further research on the potential impacts
that shark-diving tourism may pose to grey nurse sharks is recommended. 相似文献
278.
Nurul Leksmono Paul Dorfman Frank Burnet David Gibbs Emma Weitkamp 《Journal of Environmental Planning and Management》2010,53(5):559-571
Schedule 11 of the Environment Act 1995 underpins the requirement for consultation on air quality issues. The ongoing air quality review and assessment process represents one of the largest locally based science policy and communication initiatives ever undertaken in the UK. This paper outlines the practice of consultation and communication for Air Quality Management (AQM) and reviews the interaction between Environmental Health professionals, as the leading actor in the AQM process and other stakeholders involved in air quality consultation, including the public. Results are presented from a widespread questionnaire survey of English local authorities. Data indicate that the majority of air quality consultation has been carried out with statutory consultees (by sending the review and assessment reports) and the public (via websites and leaflets) in the form of information dissemination. 相似文献
279.
Albert L. Juhasz Euan Smith Richard Stewart 《Environmental pollution (Barking, Essex : 1987)》2010,158(2):585-591
The impact of residual PAHs (2250 ± 71 μg total PAHs g−1) following enhanced natural attenuation (ENA) of creosote-contaminated soil (7767 ± 1286 μg total PAHs g−1) was assessed using a variety of ecological assays. Microtox™ results for aqueous soil extracts indicated that there was no significant difference in EC50 values for uncontaminated, pre- and post-remediated soil. However, in studies conducted with Eisenia fetida, PAH bioaccumulation was reduced by up to 6.5-fold as a result of ENA. Similarly, Beta vulgaris L. biomass yields were increased 2.1-fold following ENA of creosote-contaminated soil. While earthworm and plant assays indicated that PAH bioavailability was reduced following ENA, the residual PAH fraction still exerted toxicological impacts on both receptors. Results from this study highlight that residual PAHs following ENA (presumably non-bioavailable to bioremediation) may still be bioavailable to important receptor organisms such as earthworms and plants. 相似文献
280.
David G. Angeler Craig R. Allen Hannah E. Birgé Stina Drakare Brendan G. McKie Richard K. Johnson 《Ambio》2014,43(1):113-125
Freshwater ecosystems are important for global biodiversity and provide essential ecosystem services. There is consensus in the scientific literature that freshwater ecosystems are vulnerable to the impacts of environmental change, which may trigger irreversible regime shifts upon which biodiversity and ecosystem services may be lost. There are profound uncertainties regarding the management and assessment of the vulnerability of freshwater ecosystems to environmental change. Quantitative approaches are needed to reduce this uncertainty. We describe available statistical and modeling approaches along with case studies that demonstrate how resilience theory can be applied to aid decision-making in natural resources management. We highlight especially how long-term monitoring efforts combined with ecological theory can provide a novel nexus between ecological impact assessment and management, and the quantification of systemic vulnerability and thus the resilience of ecosystems to environmental change. 相似文献