Continuous monitoring of odours from a composting plant using electronic noses

The odour impact of a composting plant situated in an urbanized area was evaluated by continuously monitoring the ambient air close to the plant during a period of about 4 days using two electronic noses. One electronic nose was installed in a nearby house, and the other one inside the perimeter of the composting plant in order to compare the response of both instruments. The results of the monitoring are represented by tables that report the olfactory class and the odour concentration value attributed to the analyzed air for each of the 370 measurements carried out during the monitoring period. The electronic nose installed at the house detected the presence of odours coming from the composting plant for about 7.8% of the monitoring total duration. Of the odour detections, 86% (25 of 29 measurements) were classified as belonging to the olfactory class corresponding to the open air storage of the waste screening overflows heaps, which was therefore identified to be the major odour source of the monitored composting plant. In correspondence of the measurements during which the electronic nose inside the house detected the presence of odours from the composting plant, the olfactory classes recognized by both instruments coincide. Moreover, the electronic nose at the house detected the presence of odours from the composting plant at issue in correspondence of each odour perception of the house occupants. The results of the study show the possibility of using an electronic nose for environmental odours monitoring, which enables the classification of the quality of the air and to quantify the olfactory nuisance from an industrial source in terms of duration and odour concentration.     

The Effect of Regulation Caused by a Dam on the Distribution of the Functional Feeding Groups of the Benthos in the Sub Basin of the Grande River (San Luis, Argentina)

The construction of small dams in principal streams is one of the most common forms of regulation in the province of San Luis since they cause changes of physical, chemical and biological nature downstream. The purpose of this study was to analyze the short-term modifications in the food organization of benthic macroinvertebrates communities due to the construction of a dam in the Grande River (San Luis, Argentina). Two sampling sites were established: one before the dam and another one after it. The samplings were carried out with Surber sampler and during an annual cycle extending from April 1997 to March 1998, and two complementary samplings were done in low and high waters. The field sampling design was stratified randomly, and 3 pseudo replicas were taken in a transect seasonally and monthly and were then averaged. Macroinvertebrates were classified in different functional feeding groups. The comparisons at the level of physical and chemical variables and absolute abundances of the functional groups were carried out by means of the Wilcoxon test for two related samples. The collector-filterers, scrapers and predators increase whereas the collector-gatherers and shredders decreased. There were significant differences at the level of gatherers and shredders.     

Trace element biomonitoring using mosses in urban areas affected by mud volcanoes around Mt. Etna. The case of the Salinelle, Italy

Trace element impact was assessed using mosses in a densely inhabited area affected by mud volcanoes. Such volcanoes, locally called Salinelle, are phenomena that occur around Mt. Etna (Sicily, Italy) and are interpreted as the surface outflow of a hydrothermal system located below Mt. Etna, releasing sedimentary fluids (hydrocarbons and NaCl brines) along with magmatic gases (mainly CO(2) and He). To date, scarce data are available about the presence of trace elements, and no biomonitoring campaigns are reported about the cumulative effects of such emissions. In this study, concentrations of Al, As, Cd, Cr, Cu, Hg, Mn, Ni, Pb, V, and Zn were detected in the moss Bryum argenteum, in soil and water. Results showed that the trace element contribution of the Salinelle to the general pollution was significant for Al, Mn, Ni, and Zn. The comparison of trace concentrations in mosses from Salinelle and Etna showed that the mud volcanoes release a greater amount of Al and Mn, whereas similar values of Ni were found. Natural emissions of trace elements could be hazardous in human settlements, in particular, the Salinelle seem to play an important role in environmental pollution.     

Remediation of phenanthrene-contaminated soil by simultaneous persulfate chemical oxidation and biodegradation processes

Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous compounds with carcinogenic and/or mutagenic potential. To address the limitations of individual remediation techniques and to achieve better PAH removal efficiencies, the combination of chemical and biological treatments can be used. The degradation of phenanthrene (chosen as a model of PAH) by persulfate in freshly contaminated soil microcosms was studied to assess its impact on the biodegradation process and on soil properties. Soil microcosms contaminated with 140 mg/kg_{DRY SOIL} of phenanthrene were treated with different persulfate (PS) concentrations 0.86–41.7 g/kg_{DRY SOIL} and incubated for 28 days. Analyses of phenanthrene and persulfate concentrations and soil pH were performed. Cultivable heterotrophic bacterial count was carried out after 28 days of treatment. Genetic diversity analysis of the soil microcosm bacterial community was performed by PCR amplification of bacterial 16S rDNA fragments followed by denaturing gradient gel electrophoresis (DGGE). The addition of PS in low concentrations could be an interesting biostimulatory strategy that managed to shorten the lag phase of the phenanthrene biological elimination, without negative effects on the physicochemical and biological soil properties, improving the remediation treatment.     

‘End to end’ planktonic trophic web and its implications for the mussel farms in the Mar Piccolo of Taranto (Ionian Sea,Italy)

The Mar Piccolo is a semi-enclosed basin subject to different natural and anthropogenic stressors. In order to better understand plankton dynamics and preferential carbon pathways within the planktonic trophic web, an integrated approach was adopted for the first time by examining all trophic levels (virioplankton, the heterotrophic and phototrophic fractions of pico-, nano- and microplankton, as well as mesozooplankton). Plankton abundance and biomass were investigated during four surveys in the period 2013–2014. Beside unveiling the dynamics of different plankton groups in the Mar Piccolo, the study revealed that high portion of the plankton carbon (C) pool was constituted by small-sized (<2 μm) planktonic fractions. The prevalence of small-sized species within micro- and mesozooplankton communities was observed as well. The succession of planktonic communities was clearly driven by the seasonality, i.e. by the nutrient availability and physical features of the water column. Our hypothesis is that beside the ‘bottom-up’ control and the grazing pressure, inferred from the C pools of different plankton groups, the presence of mussel farms in the Mar Piccolo exerts a profound impact on plankton communities, not only due to the important sequestration of the plankton biomass but also by strongly influencing its structure.     

Mechanical,Barrier and Antioxidant Properties of Chitosan Films Incorporating Cinnamaldehyde

Chitosan films (CF) [1 and 2% w/v] alone and with cinnamaldehyde (CNE) [0.25, 0.5 and 1% v/v] were prepared using an emulsion method, and the obtained films were characterized in terms of water vapor permeability (WVP), water solubility and optical, mechanical and antioxidant properties. The incorporation of CNE at 1% (v/v) significantly decreased the water solubility of the film by approximately 4% for the 1 and 2% CF films, whereas the WVP increased (2.5–3.5 times). The incorporation of CNE (0.25 and 0.5%) into 2% CF significantly increased the tensile strength (TS) (62 and 34%, respectively) and the percent elongation (%E) values, 26, 30 and 52% for CF that contained 0.25, 0.5 and 1% CNE, respectively. The largest value of the elasticity modulus (EM) was observed for 2% CF with 0.25% CNE. All films exhibited a yellow appearance (b*), but the CNE content had a marked impact on the coloration of the films. The CNE recoveries of the CF films (1 and 2%) with 1% of CNE were high (43 and 67%). The antioxidant activities indicated that the incorporation of 1% CNE into CF films (1 and 2%) increased the antioxidant activity. The protective effects of the films with and without CNE on erythrocytes were very strong (36–72% hemolysis inhibition). These results suggest there are potential applications for CF-CNE films as active packaging for the preservation of food products.     

Testing DAYCENT model simulations of corn yields and nitrous oxide emissions in irrigated tillage systems in Colorado

Agricultural soils are responsible for the majority of nitrous oxide (N(2)O) emissions in the USA. Irrigated cropping, particularly in the western USA, is an important source of N(2)O emissions. However, the impacts of tillage intensity and N fertilizer amount and type have not been extensively studied for irrigated systems. The DAYCENT biogeochemical model was tested using N(2)O, crop yield, soil N and C, and other data collected from irrigated cropping systems in northeastern Colorado during 2002 to 2006. DAYCENT uses daily weather, soil texture, and land management information to simulate C and N fluxes between the atmosphere, soil, and vegetation. The model properly represented the impacts of tillage intensity and N fertilizer amount on crop yields, soil organic C (SOC), and soil water content. DAYCENT N(2)O emissions matched the measured data in that simulated emissions increased as N fertilization rates increased and emissions from no-till (NT) tended to be lower on average than conventional-till (CT). However, the model overestimated N(2)O emissions. Lowering the amount of N(2)O emitted per unit of N nitrified from 2 to 1% helped improve model fit but the treatments receiving no N fertilizer were still overestimated by more than a factor of 2. Both the model and measurements showed that soil NO(3)(-) levels increase with N fertilizer addition and with tillage intensity, but DAYCENT underestimated NO(3)(-) levels, particularly for the treatments receiving no N fertilizer. We suggest that DAYCENT could be improved by reducing the background nitrification rate and by accounting for the impact of changes in microbial community structure on denitrification rates.     

Nitrogen, tillage, and crop rotation effects on nitrous oxide emissions from irrigated cropping systems

We evaluated the effects of irrigated crop management practices on nitrous oxide (N(2)O) emissions from soil. Emissions were monitored from several irrigated cropping systems receiving N fertilizer rates ranging from 0 to 246 kg N ha(-1) during the 2005 and 2006 growing seasons. Cropping systems included conventional-till (CT) continuous corn (Zea mays L.), no-till (NT) continuous corn, NT corn-dry bean (Phaseolus vulgaris L.) (NT-CDb), and NT corn-barley (Hordeum distichon L.) (NT-CB). In 2005, half the N was subsurface band applied as urea-ammonium nitrate (UAN) at planting to all corn plots, with the rest of the N applied surface broadcast as a polymer-coated urea (PCU) in mid-June. The entire N rate was applied as UAN at barley and dry bean planting in the NT-CB and NT-CDb plots in 2005. All plots were in corn in 2006, with PCU being applied at half the N rate at corn emergence and a second N application as dry urea in mid-June followed by irrigation, both banded on the soil surface in the corn row. Nitrous oxide fluxes were measured during the growing season using static, vented chambers (1-3 times wk(-1)) and a gas chromatograph analyzer. Linear increases in N(2)O emissions were observed with increasing N-fertilizer rate, but emission amounts varied with growing season. Growing season N(2)O emissions were greater from the NT-CDb system during the corn phase of the rotation than from the other cropping systems. Crop rotation and N rate had more effect than tillage system on N(2)O emissions. Nitrous oxide emissions from N application ranged from 0.30 to 0.75% of N applied. Spikes in N(2)O emissions after N fertilizer application were greater with UAN and urea than with PCU fertilizer. The PCU showed potential for reducing N(2)O emissions from irrigated cropping systems.     

Environmental education for small- and medium-sized enterprises: methodology and e-learning experience in the Valencian region

The last decades have shown an increasing social demand for environmental awareness, which firms are inevitably required to adapt to. More and more, small- and medium-sized enterprises (SMEs) are finding it necessary to train their staff in environmental issues if they wish to survive in a market where it is no longer sufficient to excel in price competitiveness exclusively, but where quality, service and environmental standards also play an important role.     

Heavy metal distribution between contaminated soil and Paulownia tomentosa, in a pilot-scale assisted phytoremediation study: influence of different complexing agents

The distribution of Cd, Cu, Pb and Zn between a contaminated soil and the tree species Paulownia tomentosa was investigated in a pilot-scale assisted phytoremediation study. The influence of the addition of EDTA, tartrate and glutamate at 1, 5 and 10mM concentrations on metal accumulation by the plant and on metal mobilization in soil was evaluated. Root/shoot metal concentration ratios were in the range of 3-5 for Zn, 7-17 for Cu, 9-18 for Cd and 11-39 for Pb, depending on the type and concentration of complexing agent. A significant enhancement of metal uptake in response to complexing agent application was mainly obtained in roots for Pb (i.e. 359 mg kg(-1) for EDTA 10mM and 128 mg kg(-1) for the control), Cu (i.e. 594 mg kg(-1) for glutamate 10mM and 146 mg kg(-1) for the control) and, with the exception of glutamate, also for Zn (i.e. 670 mg kg(-1) for tartrate 10mM and 237 mg kg(-1) for the control). Despite its higher metal mobilization capacity, EDTA produced a metal accumulation in plants quite similar to those obtained with tartrate and glutamate. Consequently the concentration gradient between soil pore water and plant tissues does not seem to be the predominant mechanism for metal accumulation in Paulownia tomentosa and a role of the plant should be invoked in the selection of the chemical species taken up. Metal bioavailability in soil at the end of the experiment was higher in the trials treated with EDTA than in those treated with tartrate and glutamate, the latter not being significantly different from the control. These findings indicated the persistence of a leaching risk associated to the use of this chelator, while an increase of the environmental impact is not expected when glutamate and tartrate are applied.