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401.
This paper examines local perceptions of two international humanitarian organisations, the International Rescue Committee (IRC) and Malteser International, in the eastern Democratic Republic of the Congo (DRC) (formerly known as Zaire). At times, the self‐perception of these organisations differs considerably from the perceptions of local beneficiaries and stakeholders. This study begins by reviewing the current status of research on local perceptions of externally‐introduced humanitarian action. It goes on to discuss the local perceptions of the IRC and Malteser International, as well as the origins of these perceptions, and to show that three different narratives are used by local actors to explain their different perceptions. The paper ends with an examination of the factors that help to account for the differences in perceptions and of the implications of this type of research for humanitarian principles and management, as well as for the study of local perceptions.  相似文献   
402.
Hundreds of chemical contaminants have been identified in the Great Lakes System of North America. Depending on the agency or organization, various subset lists of these contaminants have been identified as chemicals of potential concern. However, there is no agreement on the method that should be used to make management decisions. Except for consensus on approximately 40 chemicals that most North American agencies agree can cause deleterious effects if released into the environment, no agreement has been reached regarding the priority that contaminants should receive for further action. That leaves hundreds of chemicals that have been, are being, or potentially could be released into the environment that have not been evaluated yet. A profile for potential chemicals of concern is generally thought to include persistence in the environment, potential to bioaccumulate, and ability to cause toxic effects at environmentally relevant concentrations. Except for the International Joint Commission’s definition of persistence (> 8 weeks residence time in air, water, soil or sediment), there is little concurrence about what defines these characteristics. For instance, the State of Michigan currently has no established definitions or profiles of persistent, bioaccumulative, toxic substances. Furthermore, there is no standard process to rank chemicals relative to these characteristics. The Chemical Scoring and Ranking Assessment Model (SCRAM) has been developed to provide a process to rank-order chemicals based on these characteristics. The SCRAM system was developed primarily for use in the Great Lakes region of North America and particularly in Michigan, but it is not site-specific. Use of this system may assist in pollution prevention activities and other future chemical control efforts, allowing attention to be focused first on those chemicals likely to present the greatest hazard.  相似文献   
403.
How can we monitor companies' progress towards the goal of sustainability? No one set of metrics is recognized universally, although several approaches have been proposed. This article uses the environmental reports of ten leading companies to evaluate the GRI Sustainability Reporting Guidelines. © 2001 John Wiley & Sons, Inc.  相似文献   
404.
This study investigates the fate and behavior of lead (Pb), copper (Cu), antimony (Sb), and arsenic (As) in a shooting range soil. The soil samples were collected from the surface (0–15 cm) and the subsurface (15–40 cm and 40–55 cm) of a grassy and wood chip covered impact area behind a firing position. Optical microscopy images indicate significant amounts of corroded bullet fragments and organic wood chips in the surface soil. Analysis by X-ray powder diffraction (XRPD) and scanning electron microscopy electron dispersive X-ray spectroscopy (SEM-EDS) showed that metallic Pb was transformed into lead oxides (litharge PbO and massicot PbO) and lead carbonates (hydrocerussite Pb3(CO3)2(OH)2, cerussite PbCO3, and plumbonacrite Pb5(CO3)3O(OH)2). Rietveld quantification indicated the surface soil contained 14.1% metallic Pb, 17.9% hydrocerussite, 5.2% plumbonacrite, 5.9% litharge, and 3.9% massicot on a dry weight basis, or a total of 39.7% Pb, far in excess of lead concentrations typically found in US shooting range soils. Metallic Cu (bullet jacket material) appeared stable as no secondary minerals were detected in the surface soil. As and Sb concentrations were on the order of 1,057 mg/kg and 845 mg/kg respectively. The elevated soil pH coupled with high organic carbon content is thought to have caused downward migration of metals, especially for Pb, since 4,153 mg Pb/kg was observed at a depth of 55 cm. More than 60% of Pb was concentrated in the coarse soil (> 0.425 mm) fraction, suggesting soil clean-up possible by physical soil washing may be viable. The concentrations of Pb, As, and Sb in the toxicity characteristic leaching procedure (TCLP) extracts were 8,869 mg/L, 6.72 mg/L, and 6.42 mg/L respectively, were above the USEPA non-hazardous regulatory limit (As and Pb) of 5 mg/L. The elevated Sb and As concentrations draw concern because there is historically limited information concerning these metals at firing ranges and several values exceeded local soil cleanup criteria. As the high Pb concentrations appeared to be linked to the presence of organic-rich berm cover materials, the use of wood chips as berm cover to prevent soil erosion requires reconsideration as a shooting range management practice.  相似文献   
405.
Headcuts are points of accelerated channel erosion that frequently have ecological consequences. A particularly large and dynamic headcut in southwest Wyoming has affected natural and anthropogenic resources for decades. To better understand and address this issue, we undertook a review of the headcut’s upstream retreat, followed by photogrammetric monitoring of the present condition for erosion monitoring. Aerial photography shows the Bitter Creek headcut retreated >?200 m upstream in 68 years (1948–2016) at ~?1.4 m year?1. Following installation of a concrete slab structure in the mid-1970s, headcut retreat slowed to ~?0.5 m year?1. Channel sinuosity downstream of the headcut is greater than upstream, which we attribute to the presence of the headcut, given that there are no major changes in valley geometry, geology, or soils through this reach. Both aerial and terrestrial-based image platforms were used to collect stereo imagery and create 3D photogrammetric models of the headcut in 2016. From these two models, we measured soil loss downstream of the headcut at ~?126 m3 m?1 valley length. Since 1954, soil loss within the channel has been ~?98 m3 year?1 or ~871 t ha?1 year?1since then. Models created from aerial- and terrestrial-based images differed in volumetric estimates by 2%, indicating that either method could be used for this type of monitoring. The ground-based imagery model showed more detail, especially on vertical and overhanging surfaces, while the aerial imagery model produced a more realistic orthomosaic and efficiently covered a larger area. Ground-based image acquisition took longer and was more costly per unit area, but is an efficient method for small project areas, or areas where aerial imagery cannot be safely or practically acquired. Historical imagery and photogrammetric modeling proved very useful in elucidating stream dynamics associated with this large, dynamic headcut.  相似文献   
406.
We examined nitrogen transport and wetland primary production along hydrologic flow paths that link nitrogen‐fixing alder (Alnus spp.) stands to downslope wetlands and streams in the Kenai Lowlands, Alaska. We expected that nitrate concentrations in surface water and groundwater would be higher on flow paths below alder. We further expected that nitrate concentrations would be higher in surface water and groundwater at the base of short flow paths with alder and that streamside wetlands at the base of alder‐near flow paths would be less nitrogen limited than wetlands at the base of long flow paths with alder. Our results showed that groundwater nitrate‐N concentrations were significantly higher at alder‐near sites than at no‐alder sites, but did not differ significantly between alder‐far sites and no‐alder sites or between alder‐far sites and alder‐near sites. A survey of 15N stable isotope signatures in soils and foliage in alder‐near and no‐alder flow paths indicated the alder‐derived nitrogen evident in soils below alder is quickly integrated downslope. Additionally, there was a significant difference in the relative increase in plant biomass after nitrogen fertilization, with the greatest increase occurring in the no‐alder sites. This study demonstrates that streamside wetlands and streams are connected to the surrounding landscapes through hydrologic flow paths, and flow paths with alder stands are potential “hot spots” for nitrogen subsidies at the hillslope scale.  相似文献   
407.
Open burning for waste disposal is, in many countries, the dominant source of polychlorinated dibenzodioxins, dibenzofurans and biphenyls (PCDD/PCDF/PCB) release to the environment. To generate emission factors for open burning, experimental pile burns of about 100 kg of household waste were conducted with emissions sampling. From these experiments and others conducted by the same authors it is found that less compaction of waste or active mixing during the fire - “stirring” - promotes better combustion (as evidenced by lower CO/CO2 ratio) and reduces emissions of PCDD/PCDF/PCB; an intuitive but previously undemonstrated result. These experiments also support previous results suggesting PCDD/PCDF/PCB generation in open burning - while still highly variable - tends to be greater in the later (smoldering) phases of burning when the CO/CO2 ratio increases.  相似文献   
408.
The ventilation and pollutant transport in a two-dimensional (2D) street canyon of building-height-to-street-width (aspect) ratio h/b = 1 under different unstable stratifications were examined. To characterize the combined wind-buoyancy-driven flow and pollutant transport at different Richardson number Ri, a computational fluid dynamics (CFD) model based on the Reynolds-averaged Navier–Stokes (RANS) equations with the Renormalization Group (RNG) k ? ε turbulence model was adopted. Unlike the isothermal condition, a secondary recirculation is initiated at the ground-level windward corner of the street canyon once the unstable stratification is switched on (Ri < 0). It traps the ground-level pollutant leading to elevated pollutant concentration there. As Ri further decreases, the enlarging secondary recirculation enables direct pollutant removal from its core to the shear layer that offsets the ground-level pollutant accumulation. The ventilation and pollutant removal performance under different unstable stratifications are compared by the air (ACH) and pollutant (PCH) exchange rates, and pollutant retention time (τ). Both the mean and turbulent components of ACH are found to increase with decreasing Ri, suggesting that unstable stratification promotes ventilation in street canyons. Moreover, the CFD results agree well with our theoretical model that ACH2 varies linearly with Ri. Turbulent transport originally dominates the pollutant removal under isothermal condition. However, progressive domination of pollutant removal by mean wind can be observed with decreasing stability (decreasing Ri from 0 to ?10.6). The critical value is estimated to be Ri = ?8, below which mean wind is the major pollutant removal carrier. Reduction in τ is also observed with decreasing Ri. Hence, in unstable stratification, pollutant resides shorter time in the street canyon compared with its isothermal counterpart, and the ventilation and pollutant removal are more favorable.  相似文献   
409.
Abstract: A tool for providing the linkage between air and water‐quality modeling needed for determining the Total Maximum Daily Load (TMDL) and for analyzing related nonpoint‐source impacts on watersheds has been developed. Using gridded output of atmospheric deposition from the Community Multiscale Air Quality (CMAQ) model, the Watershed Deposition Tool (WDT) calculates average per unit area and total deposition to selected watersheds and subwatersheds. CMAQ estimates the wet and dry deposition for all of its gaseous and particulate chemical species, including ozone, sulfur species, nitrogen species, secondary organic aerosols, and hazardous air pollutants at grid scale sizes ranging from 4 to 36 km. An overview of the CMAQ model is provided. The somewhat specialized format of the CMAQ files is not easily imported into standard spatial analysis tools. The WDT provides a graphical user interface that allows users to visualize CMAQ gridded data and perform further analyses on selected watersheds or simply convert CMAQ gridded data to a shapefile for use in other programs. Shapefiles for the 8‐digit (cataloging unit) hydrologic unit code polygons for the United States are provided with the WDT; however, other user‐supplied closed polygons may be used. An example application of the WDT for assessing the contributions of different source categories to deposition estimates, the contributions of wet and dry deposition to total deposition, and the potential reductions in total nitrogen deposition to the Albemarle‐Pamlico basin stemming from future air emissions reductions is used to illustrate the WDT capabilities.  相似文献   
410.
A combination field and laboratorystudy was conducted to evaluate the ability of arecently developed bioindicator to detect detrimentalnutrient conditions in streams. The method utilizesbacterial growth on aquatic insects to determinenutrient impacts. Field investigations indicated thatelevated concentrations of nitrate and phosphate wereassociated with growth of filamentous bacteria oninsect body surfaces, and that there was a significantreduction in the density of major insect taxa in thenutrient-enriched stream reaches. Laboratoryinvestigations confirmed a strong linkage betweenbacterial growth and reduced survival of insects. Survival was examined for insects with bacterialinfestation ranging from 0% to greater than 50%coverage of the body surface. A threshold forcatastrophic mortality occurred at about 25% bodycoverage; there were few survivors above that amount. Based on these findings, the diagnostic endpoint forthe bioindicator is 25% body coverage by bacterialgrowth, a level that signifies major impacts and isalso easy to detect visually. This study providesadditional evidence that the insect-bacteriabioindicator is a reliable tool for assessing nutrientimpacts on stream macroinvertebrate communities. Thebioindicator should prove useful for identifyingnutrient-impacted sites as well as monitoring thesuccess of management actions to improve water quality.  相似文献   
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