Sequestration of metals in active cap materials: A laboratory and numerical evaluation

Active capping involves the use of capping materials that react with sediment contaminants to reduce their toxicity or bioavailability. Although several amendments have been proposed for use in active capping systems, little is known about their long‐term ability to sequester metals. Recent research has shown that the active amendment apatite has potential application for metals‐contaminated sediments. The focus of this study was to evaluate the effectiveness of apatite in the sequestration of metal contaminants through the use of short‐term laboratory column studies in conjunction with predictive, numerical modeling. A breakthrough column study was conducted using North Carolina apatite as the active amendment. Under saturated conditions, a spike solution containing elemental As, Cd, Co, Se, Pb, Zn, and a nonreactive tracer was injected into the column. A sand column was tested under similar conditions as a control. Effluent water samples were periodically collected from each column for chemical analysis. Relative to the nonreactive tracer, the breakthrough of each metal was substantially delayed by the apatite. Furthermore, breakthrough of each metal was substantially delayed by the apatite compared to the sand column. Finally, a simple 1‐D, numerical model was created to qualitatively predict the long‐term performance of apatite based on the findings from the column study. The results of the modeling showed that apatite could delay the breakthrough of some metals for hundreds of years under typical groundwater flow velocities. © 2012 Wiley Periodicals, Inc.     

Validation and use of in vivo solid phase micro-extraction (SPME) for the detection of emerging contaminants in fish

A variety of emerging chemicals of concern are released continuously to surface water through the municipal wastewater effluent discharges. The ability to rapidly determine bioaccumulation of these contaminants in exposed fish without sacrificing the animal (i.e. in vivo) would be of significant advantage to facilitate research, assessment and monitoring of their risk to the environment. In this study, an in vivo solid phase micro-extraction (SPME) approach was developed and applied to the measurement of a variety of emerging contaminants (carbamazepine, naproxen, diclofenac, gemfibrozil, bisphenol A, fluoxetine, ibuprofen and atrazine) in fish. Our results indicated in vivo SPME was a potential alternative extraction technique for quantitative determination of contaminants in lab exposures and as well after exposure to two municipal wastewater effluents (MWWE), with a major advantage over conventional techniques due to its ability to non-lethally sample tissues of living organisms.     

An Approach to Setting a Sulfur Standard for Coal

Over 313,000 people are working at jobs produced in part as a result of clean air regulations, according to a study just completed by the Industrial Gas Cleaning Institute. The study mitigates arguments that clean air regulations have caused the loss of jobs. According to IGCI President Robert G. Huntington, the Clean Air Act has actually created a substantial number of jobs in the pollution control equipment, engineering, and construction industries as well.     

Life on the Edge: Vulnerability and Adaptation of African Ecosystems to Global Climate Change

Donor countriesare providing financial and technicalsupport for global climate change countrystudies to help African nations meet theirreporting needs under the United NationsFramework Convention on Climate Change(UNFCCC). Technical assistance to completevulnerability and adaptation assessmentsincludes training of analysts, sharing ofcontemporary tools (e.g. simulationmodels), data and assessment techniques,information-sharing workshops and aninternational exchange programme foranalysts. This chapter summarizes 14African country studies (Botswana, Côted'Ivoire, Egypt, Ethiopia, the Gambia,Kenya, Malawi, Mauritius, Nigeria, SouthAfrica, Tanzania, Uganda, Zambia andZimbabwe) assessing vulnerabilities toglobal climate change and identifyingadaptation options. The analysis revealedthat the participating African countriesare vulnerable to global climate change inmore than one of the followingsocio-economic sectors: coastal resources,agriculture, grasslands and livestock,water resources, forests, wildlife, andhuman health. This vulnerability isexacerbated by widespread poverty,recurrent droughts, inequitable landdistribution, environmental degradation,natural resource mismanagement anddependence on rain-fed agriculture. Arange of practical adaptation options wereidentified in key socio-economic sectors ofthe African nations analysed. However,underdeveloped human and institutionalcapacity, as well as the absence ofadequate infrastructure, renders manytraditional coping strategies (rooted inpolitical and economic stability)ineffective or insufficient. FutureAfrican country studies should be moreclosely coordinated with development ofnational climate change action plans     

东非地区的海洋保护区：它们取得了多大的成功?

本文探讨了东非地区海洋保护区(MPA)及其所包含的珊瑚礁的管理。这一地区包括科摩罗、肯尼亚、马达加斯加、毛里求斯、莫桑比克、坦桑尼亚以及塞舌尔。     

Advancing Towards a Hydrogen Energy Economy: Status,Opportunities and Barriers

Performance reliability advances and cost reductions have been achieved with hydrogen and fuel cell technologies in both the transportation and distributed energy sectors. This paper reviews the status of hydrogen and fuel cell technologies, identifies key business and policy drivers for the hydrogen economy, critically examines key barriers to implementing the hydrogen economy, identifies and discusses key national initiatives to advance the hydrogen economy, and identifies and discusses key intergovernmental initiatives and activities to advance the hydrogen economy. Hydrogen and fuel cell technology advances, coupled with a reduction in costs and improvements in performance reliability, present new opportunities for developed and developing countries to achieve energy, economic and environmental security. Substantial national research and development investments in hydrogen production, storage, transport, end-use technologies (e.g., fuel cells), safety and public education underscore future opportunities. Intergovernmental bodies such as Asia Pacific Economic Cooperation (APEC), International Energy Agency (IEA) and the International Partnership for the Hydrogen Economy (IPHE) provide a multilateral framework for development of a global hydrogen economy. While the pathway forward for the hydrogen economy is precarious alternative energy options offer substantially fewer public benefits.     

The global carbon cycle and climate change: responses and feedbacks from below-ground systems

According to most global climate models, a continued build-up of CO2 and other greenhouse gases will lead to significant changes in temperature and precipitation patterns over large parts of the Earth. Below-ground processes will strongly influence the response of the biosphere to climate change and are likely to contribute to positive or negative biospheric feedbacks to climate change. Current global carbon budgets suggest that as much as 2000 Pg of carbon exists in soil systems. There is considerable disagreement, however, over pool sizes and flux (e.g. CO2, CH4) for various ecosystems. An equilibrium analysis of changes in global below-ground carbon storage due to a doubled-CO2 climate suggests a range from a possible sink of 41 Pg to a possible source of 101 Pg. Components of the terrestrial biosphere could be managed to sequester or conserve carbon and mitigate accumulation of greenhouse gases in the atmosphere.     

Subject indicators to present the nature and limit of environmental studies in US graduate schools

Summary The purpose of this paper is to examine subjects to show the nature and limit of interdisciplinary communication in existing environmental programmes in US graduate schools. Ultimately, this analysis may provide more effective communication with the general public. Following comparative historical reviews of both the sciences and the human activity for environmental protection, and a content analysis of empirical documents used by the public, a mushroom computer model has been produced. This model is based on organizational behaviour theory and contains the following 15 subjects which were originally introduced before the lack of communication resulting from curriculum failure in the 19th century: philosophy, politics, economics, architecture, sociology, biology, medicine, agriculture, ecology, public health, mathematics, physics, chemistry, geology, statistics. The subjects should foster effective communication with the general public, leading to more effective environmental protection.Dr Hong S. Kim is at the Environmental Studies Program, California State University, Fullerton, USA. He received a PhD from the Administration and Management Program at Walden University, Minneapolis, Minnesota, USA. His numerous papers are focused on environmental pollution analysis, environmental impact assessment, environmental management, and environmental law. He has written a book entitledEnvironmentology which is forthcoming.Dr James P. Dixon is the Chairperson of Health Services at Walden University, Minneapolis, Minnesota 55401, USA. He was recently Professor of the Department of Policy and Administration at the University of North Carolina at Chapel Hill, USA. He was also past President of Antioch College (1959–1975). His many publications are concentrated in the areas of organizational development, public health and preventive medicine, and administration of human service organizations.     

Mercury in fish from three rift valley lakes (Turkana,Naivasha and Baringo), Kenya,East Africa

Total mercury (THg) concentrations were measured for various fish species from Lakes Turkana, Naivasha and Baringo in the rift valley of Kenya. The highest THg concentration (636 ng g(-1) wet weight) was measured for a piscivorous tigerfish Hydrocynus forskahlii from Lake Turkana. THg concentrations for the Perciformes species, the Nile perch Lates niloticus from Lake Turkana and the largemouth bass Micropterus salmoides from Lake Naivasha ranged between 4 and 95 ng g(-1). The tilapiine species in all lakes, including the Nile tilapia Oreochromis niloticus, had consistently low THg concentrations ranging between 2 and 25 ng g(-1). In Lake Naivasha, the crayfish species, Procambrus clarkii, had THg concentrations similar to those for the tilapiine species from the same lake, which is consistent with their shared detritivore diet. THg concentrations in all fish species were usually consistent with their known trophic position, with highest concentrations in piscivores and declining in omnivores, insectivores and detritivores. One exception is the detritivore Labeo cylindricus from Lake Baringo, which had surprisingly elevated THg concentrations (mean=75 ng g(-1)), which was similar to those for the top trophic species (Clarias and Protopterus) in the same lake. Except for two Hydrocynus forskahlii individuals from Lake Turkana, which had THg concentrations near or above the international marketing limit of 500 ng g(-1), THg concentrations in the fish were generally below those of World Health Organization's recommended limit of 200 ng g(-1) for at-risk groups.