FACTORS INFLUENCING ACUTE TOXICfrY OF COAL ASH TO RAINBOW TROUT (SALMO GAIRDNERI) AND BLUEGILL SUNFISH (LEPOMIS MACROCHIRUS)1

ABSTRACT: The potentially toxic components in coal ash (ash particles, heavy metals) were evaluated in laboratory static, acute (96 hr) bioassays, both separately and in various combinations with extreme pH (5.0 and 8.5), using rainbow trout (Salmo gairdneri) and bluegifi sunfish (Lepomis macrochirus). Ash particle morphology and metal distribution anlaysis, using electron microscopy and surface-subsurface analysis by ion microscopy, showed that metals could be either clumped or evenly distributed on the surface of fly ash. Surface enrichment on fly ash particles from electrostatic precipitators, as measured by ion microscopy, was found for cadmium, copper, chromium, nickel, lead, mercury, titanium, arsenic, and selenium. Bottom (heavy) ash was not acutely toxic to either fish species at concentrations of up to 1500 mg/l total suspended solids (TSS) at pH 5.0, 7.5, or 8.5. Fly ash particles were not acutely toxic to blue-gill at levels up to 1360 mg/l TSS. Rainbow trout were highly sensitive to fly ash (25 to 60 percent mortality) at concentrations of 4.3 to 20.5 mg/I TSS when dissolved metal availability was high but were not sensitive at higher particulate concentrations (58 to 638 mg/I TSS) when dissolved metals were low. When metals were acid-leached from fly ash prior to testing, no rainbow trout mortality occurred at TSS concentrations of up to 2,350 mg/l TSS. When the percent of dissolved metal was high (e.g., 50–90 percent of the total), fish mortality was increased. Rainbow trout were nearly two orders of magnitude more sensitive than bluegill when subjected to a blend of cadmium, chromium, copper, nickel, lead, and zinc. The two species were similar in their acute sensitivity to acidic pH at levels at or below 4.0 and alkaline pH of 9.1. If the pH of coal ash effluent is contained within the range 6.0 to 9.0, acute toxicity to fish can be attributed to trace element availability from fly ash but not heavy ash. Control of holding pond and effluent pH and maximizing pond residence time are important strategies for minimizing effects of ash pond discharges on fish.     

GEOHYDROLOGY AND HYDROCHEMISTRY OF THE DAKOTA AQUIFER,CENTRAL UNITED STATES1

ABSTRACT: The Dakota aquifer, composed of the Dakota Sandstone and stratigraphically equivalent sandstone units of Cretaceous age, is the upper-most regional aquifer underlying the extensively developed High Plains aquifer of the midwestern United States. The concentration of dissolved solids in ground water of the Dakota aquifer ranges from less than 500 milligrams per liter in calcium bicarbonate type water in the eastern outcrop area to more than 100,000 milligrams per liter in sodium chloride type oilfield brine in the Denver Basin to the west. Preliminary maps showing the distribution of dissolved solids confirm the complex nature of the Dakota aquifer as inferred from stratigraphic and hydraulic evidence. Extensive vertical leakage through confining layers, local recharge at the truncated eastern boundary, and a barrier to recharge along the western edge of the Denver Basin are consistent with the distribution of hydraulic head and dissolved solids.     

CHARACTERIZATION OF HYDROLOGIC CONDITIONS TO SUPPORT PLATTE RIVER SPECIES RECOVERY EFFORTS1

ABSTRACT: Efforts are under way to recover habitat for several threatened and endangered species in and along the Platte River in central Nebraska. A proposed recovery program for these species requires a means of characterizing “wet” versus “normal” versus “dry” hydrologic conditions in order to set corresponding Platte River instream flow targets. Methods of characterizing hydrologic conditions in real time were investigated for this purpose. Initially, 10 watershed variables were identified as potentially valuable indicators of hydrologic conditions. Ultimately, six multiple linear regression equations were developed for six periods of the year using a subset of these variables expressed as frequencies of nonexceedence. The adequacy of these equations for characterizing conditions was assessed by evaluating their historic correlation to subsequent flow in the central Platte River (1947–1994). These equations explained 54 to 82 percent of variability in the observed flow exceedences in the validation datasets, depending upon the period of year evaluated. These equations will provide initial criteria for setting applicable flow targets to determine, in real time, whether water regulation projects associated with the species recovery effort can divert or store flows without conflicting with recovery objectives.     

Effect of Cage Design on Growth of Transplanted Asian Clams: Implications for Assessing Bivalve Responses in Streams

This study was designed to determine whether survivorship and growth of Asian clams (Corbicula fluminea [Müller]) differed significantly between two types of field enclosures. Enclosures were either flexible mesh bags or rigid cages (hereto after referred as bioboxes) designed to homogenize substrate among study sites and accommodate Asian clam feeding mechanisms. For 96d, cages remained at 12 Clinch River (CR), Hurricane Fork (HF), and Dump's Creek (DC) sites upstream and downstream of a coal-fired power plant discharge, coal mining effluent, and coal combustion-related disposal facilities in Carbo, Virginia. Although survivorship was not significantly different between cage types, mean growth of clams in bioboxes was significantly greater overall (p = 0.0157). Despite the difference in growth between the two cage types, both confirmed significant reductions of survivorship and growth directly below the power plant discharge. Additionally, coefficient of variance values for biobox growth data were reduced at most study sites (averages of 16% for bioboxes versus 19% for mesh bags). Our results have implications toward strengthening weight-of-evidence approaches used to link impairment of transplanted bivalves to environmental contaminants. More importantly, these results suggest that ecotoxicological impairment of bivalves transplanted downstream of the coal-fired power plant discharge functioned independently of site-specific substrate provisions.     

Nitrogen removal and nitrate leaching for two perennial,sod-based forage systems receiving dairy effluent

In northern Florida, year-round forage systems are used in dairy effluent sprayfields to reduce nitrate leaching. Our purpose was to quantify forage N removal and monitor nitrate N (NO3(-)-N) concentration below the rooting zone for two perennial, sod-based, triple-cropping systems over four 12-mo cycles (1996-2000). The soil is an excessively drained Kershaw sand (thermic, uncoated Typic Quartzip-samment). Effluent N rates were 500, 690, and 910 kg ha(-1) per cycle. Differences in N removal between a corn (Zea mays L.)-bermudagrass (Cynodon spp.)-rye (Secale cereale L.) system (CBR) and corn-perennial peanut (Arachis glabrata Benth.)-rye system (CPR) were primarily related to the performance of the perennial forages. Nitrogen removal of corn (125-170 kg ha(-1)) and rye (62-90 kg ha(-1)) was relatively stable between systems and among cycles. The greatest N removal was measured for CBR in the first cycle (408 kg ha(-1)), with the bermudagrass removing an average of 191 kg N ha(-1). In later cycles, N removal for bermudagrass declined because dry matter (DM) yield declined. Yield and N removal of perennial peanut increased over the four cycles. Nitrate N concentrations below the rooting zone were lower for CBR than CPR in the first two cycles, but differences were inconsistent in the latter two. The CBR system maintained low NO3(-)-N leaching in the first cycle when the bermudagrass was the most productive; however, it was not a sustainable system for long-term prevention of NO3(-)-N leaching due to declining bermudagrass yield in subsequent cycles. For CPR, effluent N rates > or = 500 kg ha(-1) yr(-1) have the potential to negatively affect ground water quality.     

Chemistry of Selected High-Elevation Lakes in Seven National Parks in the Western United States

A chemical survey of 69 high-altitude lakes in seven national parks in the western United States was conducted during the fallof 1999; the lakes were previously sampled during the fall of 1985, as part of the Western Lake Survey. Lakes in parks in the Sierra/southern Cascades (Lassen Volcanic, Yosemite, Sequoia/Kings Canyon National Parks) and in the southern RockyMountains (Rocky Mountain National Park) were very dilute; medianspecific conductance ranged from 4.4 to 12.2 S cm^-1 andmedian alkalinity concentrations ranged from 32.2 to 72.9 eqL^-1. Specific conductances and alkalinity concentrations were substantially higher in lakes in the central and northernRocky Mountains parks (Grand Teton, Yellowstone, and GlacierNational Parks), probably due to the prevalence of more reactivebedrock types. Regional patterns in lake concentrations of NO₃ and SO₄ were similar to regional patterns in NO₃ and SO₄ concentrations in precipitation, suggestingthat the lakes are showing a response to atmospheric deposition.Concentrations of NO₃ were particularly high in Rocky Mountain National Park, where some ecosystems appear to be undergoing nitrogen saturation.     

Relating net nitrogen input in the Mississippi River basin to nitrate flux in the lower Mississippi River: a comparison of approaches

A quantitative understanding of the relationship between terrestrial N inputs and riverine N flux can help guide conservation, policy, and adaptive management efforts aimed at preserving or restoring water quality. The objective of this study was to compare recently published approaches for relating terrestrial N inputs to the Mississippi River basin (MRB) with measured nitrate flux in the lower Mississippi River. Nitrogen inputs to and outputs from the MRB (1951 to 1996) were estimated from state-level annual agricultural production statistics and NOy (inorganic oxides of N) deposition estimates for 20 states that comprise 90% of the MRB. A model with water yield and gross N inputs accounted for 85% of the variation in observed annual nitrate flux in the lower Mississippi River, from 1960 to 1998, but tended to underestimate high nitrate flux and overestimate low nitrate flux. A model that used water yield and net anthropogenic nitrogen inputs (NANI) accounted for 95% of the variation in riverine N flux. The NANI approach accounted for N harvested in crops and assumed that crop harvest in excess of the nutritional needs of the humans and livestock in the basin would be exported from the basin. The U.S. White House Committee on Natural Resources and Environment (CENR) developed a more comprehensive N budget that included estimates of ammonia volatilization, denitrification, and exchanges with soil organic matter. The residual N in the CENR budget was weakly and negatively correlated with observed riverine nitrate flux. The CENR estimates of soil N mineralization and immobilization suggested that there were large (2000 kg N ha-1) net losses of soil organic N between 1951 and 1996. When the CENR N budget was modified by assuming that soil organic N levels have been relatively constant after 1950, and ammonia volatilization losses are redeposited within the basin, the trend of residual N closely matched temporal variation in NANI and was positively correlated with riverine nitrate flux in the lower Mississippi River. Based on results from applying these three modeling approaches, we conclude that although the NANI approach does not address several processes that influence the N cycle, it appears to focus on the terms that can be estimated with reasonable certainty and that are correlated with riverine N flux.     

ESTIMATED STREAM FLOW REQUIREMENTS FOR FISHES OF THE WASHITA RIVER BELOW FOSS RESERVOIR,WESTERN OKLAHOMA1

Velocity and depth preference curves for juvenile and adult red shiners (Notropis lutrensis) were developed for each season of the year. The incremental methodology, developed by the U.S. Fish and Wildlife Service for quantifying the amount of physical habitat available for fish, was applied as a basis for recommending minimum stream flows for life stages of red shiners and channel catfish (Ictalurus punctatus) in the Washita River below Foss Reservoir. The minimum stream flow required to support populations of red shiners and channel catfish was estimated to be 0.60 m³/s during all months except April and May, during which flushing flows of 3.0 m³/s were recommended. Under drought conditions a contingency flow of 0.18 m³/s was recommended for August through March, a flushing flow of 2.4 m³/s for April and May, and a flow of 0.30 m³/s for channel catfish spawning in June and July. Standing crop of adult red shiners per weighted usable area averaged 2.73 g/m² (27 kg/ha) for two sites on the Washita River. A positive relation between standing crop and weighted usable area was suggested. Use of the incremental methodology on the study reach below Foss Reservoir required 96 person-hours of labor, excluding training, travel, and developing preference curves, and a total cost of $1,762, of which $1,200 was for the purchase of equipment.     

COST REDUCTIONS DUE TO SEASONAL VARIATION IN MUNICIPAL WASTE WATER TREATMENT LEVELS1

ABSTRACT: Varying treatment levels to meet seasonal variation in assimilative capacity of streams can reduce total costs of treatment. A mathematical model of a Pennsylvania stream based on a theoretically sound approximation of the physical relationships underlying the distribution of DO in a river system was used to determine discharge constraints for an economic optimization model which produced estimates of sewage treatment cost savings. Increasing the number of flow periods during the year enhances cost reducing opportunities even when land application processes are considered. Also, the least cost treatment process for year around operation may not be the least costly under multiple flow period management.