Black carbon (BC) is a promising sediment amendment, as proven by its considerable adsorption capacity for hydrophobic organic pollutants and accessibility, but its reliability when used for the removal of pollutants in natural sediments still needs to be evaluated. For example, the ageing process, resulting in changing of surface physicochemical properties of BC, will decrease the adsorption capacity and performance of BC when applied to sediment pollution control. In this study, how the ageing process and BC proportion affect the adsorption capacity of BC-sediment systems was modelled and quantitatively investigated to predict their adsorption capacity under different ageing times and BC additions. The results showed that the ageing process decreased the adsorption capacity of both BC-sediment systems, due to the blockage of the non-linear adsorption sites of BC. The adsorption capacity of rice straw black carbon (RC)-sediment systems was higher than that of fly ash black carbon (FC)-sediment systems, indicating that RC is more efficient than FC for nonylphenol (NP) pollution control in sediment. The newly established model for the prediction of adsorption capacity fits the experimental data appropriately and yields acceptable predictions, especially when based on parameters from the Freundlich model. However, to fully reflect the influence of the ageing process on BC-sediment systems and make more precise predictions, it is recommended that future work considering more factors and conditions, such as modelling of the correlation between the adsorption capacity and the pore volume or specific surface area of BC, be applied to build an accurate and sound model. 相似文献
Environmental Science and Pollution Research - Colored dissolved organic matter (CDOM) is the main constituent of dissolved organic matter (DOM), also a key indicator of water quality conditions.... 相似文献
Environmental Science and Pollution Research - Over the past 40 years since China’s reform and opening up, the industrial structure has undergone tremendous changes. The rapid... 相似文献
Environmental Science and Pollution Research - The present work investigates the primary adsorption mechanisms of lead (II) and cadmium (II) cations onto pomelo fruit peel (PFP) from aqueous... 相似文献
Surface sediments from estuarine and coast of CanGio wetland (CGW) of Hochiminh City, Vietnam, were investigated to identify the spatial and temporal variations of polycyclic aromatic hydrocarbons (PAHs). The total PAHs showed wide variation but similar to patterns observed (F?=?0.901, p?=?0.46) in LongTau (31?±?77 ng/g dry weight, n?=?13), SoaiRap (53?±?81, n?=?4), ThiVai (60?±?62, n?=?10) estuaries, and coastal areas (112?±?211, n?=?9). A decreasing trend in the wet season (F?=?8.8, p?=?0.01) reflected that inland sources such as wastewater discharged and atmospherically transported contaminants contributed to PAHs in sediments. The risk posed by the PAHs in the coastal and estuarine areas of CGW is still negligible. The present study provides baseline data, which can be used for regular monitoring and future strategy of environmental protection for the study area.
Resource-based cities face vital economic, social, and environmental problems during their industrial transformation. Urban industrial structure is a traditional primary industrial pattern, which is resource-based and resource-intensive economy with low level technology and efficiency. They encounter tremendous pressure of unemployment and social security. Resources of such cities are on the verge of extinction, in addition, the environmental pollution and ecological conditions are becoming worse. The cities have significant institutional issues and their innovation capacity is inadequate. Therefore, it is necessary to carry out strategic innovations to realize the successful economic transformation of resource-based cities. The strategic innovations include innovation of development goals, equalization of social welfare, sustainable economic development, coordinative development between eco-environment and socioeconomy, and circular economy development strategies optimizing diversified industrial structures. In addition, forming eco-industrial system and changing traditional growth pattern, strategy of resource and industrial substitution and supplement, scientific and technological innovation strategy —late-comer's advantages of development of new high-tech ecocity development strategy and innovation of institutional mechanism and systems. 相似文献