全文获取类型
收费全文 | 5497篇 |
免费 | 30篇 |
国内免费 | 25篇 |
专业分类
安全科学 | 131篇 |
废物处理 | 296篇 |
环保管理 | 434篇 |
综合类 | 830篇 |
基础理论 | 1368篇 |
环境理论 | 2篇 |
污染及防治 | 1357篇 |
评价与监测 | 396篇 |
社会与环境 | 711篇 |
灾害及防治 | 27篇 |
出版年
2023年 | 43篇 |
2022年 | 78篇 |
2021年 | 60篇 |
2020年 | 29篇 |
2019年 | 42篇 |
2018年 | 78篇 |
2017年 | 90篇 |
2016年 | 111篇 |
2015年 | 72篇 |
2014年 | 146篇 |
2013年 | 418篇 |
2012年 | 167篇 |
2011年 | 241篇 |
2010年 | 214篇 |
2009年 | 222篇 |
2008年 | 254篇 |
2007年 | 251篇 |
2006年 | 243篇 |
2005年 | 208篇 |
2004年 | 188篇 |
2003年 | 216篇 |
2002年 | 175篇 |
2001年 | 254篇 |
2000年 | 161篇 |
1999年 | 101篇 |
1998年 | 41篇 |
1997年 | 58篇 |
1996年 | 53篇 |
1995年 | 60篇 |
1994年 | 64篇 |
1993年 | 59篇 |
1992年 | 58篇 |
1991年 | 61篇 |
1990年 | 66篇 |
1989年 | 52篇 |
1988年 | 56篇 |
1987年 | 54篇 |
1986年 | 55篇 |
1985年 | 41篇 |
1984年 | 47篇 |
1983年 | 48篇 |
1982年 | 48篇 |
1980年 | 30篇 |
1979年 | 32篇 |
1978年 | 29篇 |
1977年 | 28篇 |
1976年 | 28篇 |
1974年 | 31篇 |
1973年 | 30篇 |
1972年 | 27篇 |
排序方式: 共有5552条查询结果,搜索用时 15 毫秒
251.
Heavy metals in untreated/treated urban effluent and sludge from a biological wastewater treatment plant 总被引:1,自引:0,他引:1
Oliveira Ada S Bocio A Trevilato TM Takayanagui AM Domingo JL Segura-Muñoz SI 《Environmental science and pollution research international》2007,14(7):483-489
Background, Aim and Scope
The presence of heavy metals in wastewater is one of the main causes of water and soil pollution. The aim of the present study was to investigate the removal of Cd, Cu, Pb, Hg, Mn, Cr and Zn in urban effluent by a biological wastewater treatment, as well as to quantify the levels of As, Be, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sn, Tl, V and Zn in dewatering sludge from the Biological Wastewater Treatment Plant to Ribeirão Preto (RP-BWTP), Brazil.Materials and Methods
Concentrations of Cd, Cr, Cu, Mn and Pb in wastewater and those of Ni in sludge were determined by atomic absorption spectrophotometry with graphite furnace atomization. Mercury concentrations in wastewater were measured by hydride generation atomic spectrophotometry, and Zn levels were determined by atomic absorption spectrophotometry using acetylene flame. In sludge, the levels of As, Be, Cd, Cr, Cu, Fe, Hg, Mn, Pb, Sn, Tl, V and Zn were determined by inductively coupled plasma-mass spectrometry.Results
The percentages of removal efficiency (RE) were the following: Hg 61.5%, Cd 60.0%, Zn 44.9%, Cu 44.2%, PB 39.7%, Cr 16,5% and Mn 10.4%. In turn, the mean concentrations (mg/kg) of metals in dewatering sludge followed this increasing order: Tl (<0.03), Hg (0.31), Be (0.43), As (1.14), Cd (1.34), V (59.2), Pb (132.1), Sn (166.1), Cr (195.0), Mn (208.1), Ni (239.4), Cu (391.7), Zn (864.4) and Fe (20537).Discussion
The relationship between metal levels in untreated wastewater, as well as the removal efficiency are in agreement with previous data from various investigators, It is important to note that metal removal efficiency is not only affected by metal ion species and concentration, but also by other conditions such as operating parameters, physical, chemical, and biological factors.Conclusions
Metal values recorded for treated wastewater and sludge were within the maximum permitted levels established by the Environmental Sanitation Company (CETESB), São Paulo, Brazil.Recommendations
There is an urgent need for the authorities who are responsible for legislation on sludge uses in agriculture of establishing safety levels for As, Be, Hg, Sn, Tl and V.Perspectives
According to the current metal levels, RP-BWTP sludge might be used for agriculture purposes. However, for an environmentally safe use of sewage sludge, further studies including systematic monitoring are recommended. Annual metal concentrations and predicted variations of those elements in the sludge should be monitored.252.
Somerset VS Klink MJ Baker PG Iwuoha EI 《Journal of environmental science and health. Part. B》2007,42(3):297-304
The behavior of an amperometric organic-phase biosensor consisting of a gold electrode modified first with a mercaptobenzothiazole self-assembled monolayer, followed by electropolymerization of polyaniline in which acetylcholinesterase as enzyme was immobilized, has been developed and evaluated for organophosphorous pesticide detection. The voltammetric results have shown that the formal potential shifts anodically as the Au/MBT/PANI/AChE/PVAc thick-film biosensor responded to acetylthiocholine substrate addition under anaerobic conditions in selected organic solvent media containing 2% v/v 0.05 M phosphate buffer, 0.1 M KCl (pH 7.2) solution. Detection limits in the order of 0.147 ppb for diazinon and 0.172 ppb for fenthion in acetone-saline phosphate buffer solution, and 0.180 ppb for diazinon and 0.194 ppb for fenthion in ethanol-saline phosphate buffer solution has been achieved. 相似文献
253.
254.
Kristen A. Conner Author Vitae Author Vitae Jonathan I. Groner Author Vitae Author Vitae 《Journal of Safety Research》2008,39(5):469-475
Problem
Motorized recreational vehicle (MRV)-related injuries can result in severe medical and financial consequences. The objective of this study was to describe the epidemiology, and clinical and financial impact of MRV-related injuries in Ohio.Method
Probabilistically linked statewide Emergency Medical Services (EMS) and hospital (inpatient and emergency department) data for 2003 and 2004 were examined. Record pairs with a MRV-related E-code (E821-E823, E825) were included in this study.Results
There were 2,893 patients with MRV-related injuries, who had linked EMS and hospital records, resulting in more than $15 million in hospital charges and 1,921 inpatient days of hospitalization. The male-to-female ratio was nearly 4:1, and 19% were younger than 16. Almost 82% of cases were not wearing a helmet; there was a trend of decreasing helmet use with increasing age. Mean (SE) inpatient hospital charges and length of stay (LOS) were $22,218 ($1,290) and 3.8 (0.2) days, respectively. The mean (SE) Injury Severity Score (ISS) for inpatients was 9.2 (0.4). Individuals injured on a street/highway were 3.20 times more likely to sustain an ISS ≥ 16 (95% CI: 1.03, 9.88; p = 0.044) and 3.05 times more likely to sustain a traumatic brain injury (TBI) (95% CI: 1.17, 7.94; p = 0.024) than those who were injured at a place designated for sport or recreation. Children aged 12 to 15 and young adults aged 16 to 25 were 2.47 and 2.14 times more likely, respectively, to sustain a TBI than adults aged 36 or older (aged 12 to 15: 95% CI: 1.13, 5.38; p = 0.024; aged 16 to 25: 95% CI: 1.26, 3.64; p = 0.005). Higher ISS was associated with both higher total charges (p < 0.001) and longer LOS (p < 0.001).Discussion
This study demonstrates that MRV-related injuries are an important public health problem in Ohio, with a substantial clinical and financial impact.Impact on Industry
Enactment and enforcement of statewide MRV safety legislation and training of MRV users offer valuable opportunities to prevent these costly injuries. 相似文献255.
One of the primary challenges in resource and environmental planning is successful implementation of plans. Plan implementation is a complex process influenced by many factors. This study identifies 19 criteria affecting implementation success and tests the impact of these criteria through a case study of collaborative plan implementation in British Columbia, Canada. The significance of criteria and degree to which they are met is assessed by a survey of senior officials responsible for plan implementation. An implementation evaluation index (IEI) is constructed to assess the quality of plan implementation systems and best practices for effective implementation are identified. 相似文献
256.
Agricultural reuse of reclaimed water and uptake of organic compounds: pilot study at Mutah University wastewater treatment plant, Jordan 总被引:1,自引:0,他引:1
The residues of polynuclear aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), chlorinated benzenes (CBs) and phenols were investigated for soil, wastewater, groundwater and plants. The uptake concentration of these compounds was comparatively determined using various plant types: Zea mays L., Helianthus annus L., Capsicum annum L., Abelmoschus esculentus L., Solanum melongena L. and Lycopersicon esculentum L. which were grown in a pilot site established at Mutah University wastewater treatment plant, Jordan. Soil, wastewater, groundwater and various plant parts (roots, leaves and fruits) samples were extracted in duplicate, cleaned up by open-column chromatography and analyzed by a multi-residue analytical methods using gas chromatography equipped with either mass selective detector (GC/MS), electron capture detector (GC/ECD), or flame ionization detector (FID). Environmentally relevant concentrations of targeted compounds were detected for wastewater much higher than for groundwater. The overall distribution profiles of PAHs and PCBs appeared similar for groundwater and wastewater indicating common potential pollution sources. The concentrations of PAHs, PCBs and phenols for different soils ranged from 169.34 to 673.20 microg kg(-1), 0.04 to 73.86 microg kg(-1) and 73.83 to 8724.42 microg kg(-1), respectively. However, much lower concentrations were detected for reference soil. CBs were detected in very low concentrations. Furthermore, it was found that different plants have different uptake and translocation behavior. As a consequence, there are some difficulties in evaluating the translocation of PAHs, CBs, PCBs and phenols from soil-roots-plant system. The uptake concentrations of various compounds from soil, in which plants grown, were dependent on plant variety and plant part, and they showed different uptake concentrations. Among the different plant parts, roots were found to be the most contaminated and fruits the least contaminated. 相似文献
257.
D. S. Rosa C. G. F. Guedes C. M. Oliveira M. I. Felisberti 《Journal of Polymers and the Environment》2008,16(4):230-240
Mixtures of poly-β-(hydroxybutyrate-co-valerate) PHB-V with virgin and post-consumer low density polyethylene (LDPE) were
prepared by melt mixing in proportions of 100/0, 90/10, 80/20, 70/30 and 0/100 (wt/wt%). The mixtures were analysed by infrared
spectroscopy, differential scanning calorimetry (DSC), dynamic mechanical thermal analysis (DMTA), melting flow index (MFI),
tensile tests, scanning electron microscopy (SEM) and biodegradation in simulated soil. The DMTA and DSC curves of post-consumer
LDPE suggested that this polymer was a mixture of LDPE and linear low density polyethylene (LLDPE). Virgin and post-consumer
LDPE had lower MFI than PHB-V, but the blends showed higher index as the content of LDPE increased. The addition of LDPE reduced
the tensile strength and Young’s modulus of the mixtures compared with PHB-V. SEM indicated poor interfacial adhesion between
PHB-V and LDPE. PHB-V degraded slow and gradually, while both LDPE showed virtually no degradation under the conditions studied.
The biodegradability of the blends depended on their composition and of the type of LDPE. LDPE improved the biodegradability
of the mixtures. 相似文献
258.
Relationships between street characteristics and perceived attractiveness for walking reported by elderly people 总被引:2,自引:0,他引:2
Hieronymus C. Borst Henk M.E. Miedema Sanne I. de Vries Jamie M.A. Graham Jef E.F. van Dongen 《Journal of environmental psychology》2008,28(4):353-361
Walking is important for the health of elderly people. Previous studies have found a relationship between neighbourhood characteristics, physical activity and related health aspects. The multivariate linear regression model presented here describes the relationships between the perceived attractiveness of streets for walking along and (physical) street characteristics. Two hundred and eighty-eight independently living elderly people (between 55 and 80 years old) participated in the study. Street characteristics were assessed along homogeneous street subsections defined as ‘links’. Positively related to perceived attractiveness of links were the following street characteristics: slopes and/or stairs, zebra crossings, trees along the route, front gardens, bus and tram stops, shops, business buildings, catering establishments, passing through parks or the city centre, and traffic volume. Litter on the street, high-rise buildings, and neighbourhood density of dwellings were negatively related to perceived link attractiveness. Overall, the results suggest that three main aspects affect perceived attractiveness of streets for walking, namely tidiness of the street, its scenic value and the presence of activity or other people along the street. The results are discussed within the context of these three aspects. 相似文献
259.
The water disinfecting behavior of silver-modified clinoptilolite–heulandite rich tuff (ZSAg) as an antibacterial agent against coliform microorganisms from water in a continuous mode was investigated. Silver recovery from the disinfected effluents by the sodium-modified clinoptilolite–heulandite rich tuff (ZSNa) was also considered. Escherichia coli (ATCC 8739) and total coliform microorganisms, as indicators of microbiological contamination of water, were chosen to achieve the disinfection of synthetic wastewater or municipal wastewater. Ammonium (NH4+) and chloride (Cl−) ions were added to the synthetic wastewater as an interfering chemical species on the disinfection processes. The antibacterial activity of the ZSAg as a bactericide was measured by the coliform concentration as evaluated by the APHA method. The amount of silver in the disinfected effluents was determined using atomic absorption spectroscopy. The inactivation of the ZSAg was calculated from the breakthrough curves based on the model reported by Gupta et al. It was found that when the silver concentration in the effluent is less than 0.6 μg/mL, the bacterial survival percentage increased and the volume of disinfected water diminished. The total silver amounts found in the effluent at the end of the disinfection processes varied depending on the water treated (synthetic or municipal wastewater). The presence of NH4+ ions in synthetic wastewater influent notably improved the disinfected water volume (zero NVC/100 mL), in comparison to the disinfection of the same influent without NH4+ ions. A contrary water disinfection behavior was observed in the presence of Cl− ions. The silver recovery does not depend on the mass of the sodium zeolitic bed according with the wastewater to be treated (synthetic or municipal wastewater) and the presence of NH4+ or Cl− ions in the influent also influenced the silver recovery from wastewater. The ZSNa did not have antibacterial activity. Therefore the amount of bactericide agent (silver-modified natural zeolite), coliform microorganisms from water (E. coli or consort of coliform microorganisms) as well as the water quality (synthetic wastewater or municipal wastewater) influenced both the disinfection process and the silver recovery in a column system. 相似文献
260.
A stow net (90 m2 opening) was used, at regular intervals between July 1989 and June 1993, to collect fish over ca. 4 h on both the flood and
ebb tides at five sites distributed at regularly spaced distances throughout the Elbe Estuary. Overall, 53.4% of the species
were marine, and some of these were abundant, e.g.Clupea harengus, Pleuronectes flesus, Pomatoschistus minutus, Merlangius merlangus and Sprattus sprattus. However, in terms of number of individuals, such species contributed only 9.1%, compared with 90.0% by anadromous species,
which was predominantly due to exceptionally high catches of Osmerus eperlanus. The ichthyofaunal compositions on the flood and ebb tides were similar, even downstream where salinities change markedly
during each tidal cycle. Although this is probably due in part to groups of fish being swept first upstream on the flood tide
and then back downstream on the ebb tide, several species clearly tended to occupy particular regions of the estuary. Each
year the species composition changed sequentially from the most downstream site (max. salinity=ca. 31.4‰) to the most upstream
site (max. salinity=ca. 1.5‰), mainly as a result of a sequential decline in the number and abundance of marine species and
a progressive increase in the contributions of both anadromous and freshwater species. However, the marine species diagnostic
of differences in the compositions among regions varied between years. Thus, for example, the diagnostic species for the downstream
sites were C. harengus and M. merlangus in 1990/1991 and S. sprattus in 1992/1993, reflecting differences in the recruitment strengths of these marine species in the two years. The ichthyofaunal
composition exhibited pronounced annual cyclical changes in each region and thus occurred irrespective of whether or not the
salinity in a region underwent pronounced changes during the year. This cyclicity was attributable to intra-annual variations
in the times of recruitment of certain marine species, particularly in the downstream region, and to seasonal migrations of
diadromous species into each region, as well as to the movements of freshwater species into the upstream region in winter
and early spring.
Received: 18 November 1999 / Accepted: 25 October 2000 相似文献