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41.
Roy Mauldin Edward Kosciuch Fred Eisele Greg Huey David Tanner Steve Sjostedt Don Blake Gao Chen Jim Crawford Douglas Davis 《Atmospheric environment (Oxford, England : 1994)》2010,44(4):572-581
Measurements of OH, H2SO4, and MSA at South Pole (SP) Antarctica were recorded as a part of the 2003 Antarctic Chemistry Investigation (ANTCI 2003). The time period 22 November, 2003–2 January, 2004 provided a unique opportunity to observe atmospheric chemistry at SP under both natural conditions as well as those uniquely defined by a solar eclipse event. Results under natural solar conditions generally confirmed those reported previously in the year 2000. In both years the major chemical driver leading to large scale fluctuations in OH was shifts in the concentration levels of NO. Like in 2000, however, the 2003 observational data were systematically lower than model predictions. This can be interpreted as indicating that the model mechanism is still missing a significant HOx sink reaction(s); or, alternatively, that the OH calibration source may have problems. Still a final possibility could involve the integrity of the OH sampling scheme which involved a fixed building site. As expected, during the peak in the solar eclipse both NO and OH showed large decreases in their respective concentrations. Interestingly, the observational OH profile could only be approximated by the model mechanism upon adding an additional HOx radical source in the form of snow emissions of CH2O and/or H2O2. This would lead one to think that either CH2O and/or H2O2 snow emissions represent a significant HOx radical source under summertime conditions at SP. Observations of H2SO4 and MSA revealed both species to be present at very low concentrations (e.g., 5 × 105 and 1 × 105 molec cm?3, respectively), but similar to those reported in 2000. The first measurements of SO2 at SP demonstrated a close coupling with the oxidation product H2SO4. The observed low concentrations of MSA appear to be counter to the most recent thinking by glacio-chemists who have suggested that the plateau's lower atmosphere should have elevated levels of MSA. We speculate here that the absence of MSA may reflect efficient atmospheric removal mechanisms for this species involving either dynamical and/or chemical processes. 相似文献
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Douglas W. Cooper 《Journal of the Air & Waste Management Association (1995)》2013,63(2):205-208
Factors which help minimize pressure drop at a given level of collection efficiency for a bed packed with roughly spherical collectors are studied here by using the quality factor, the ratio of the single collector collection efficiency to the force per unit area on the single collector. This analysis indicates that energy-efficient designs can be obtained as follows: choose a representative particle size; if impaction predominates, design for an impaction parameter near one; if interception predominates, design for the smallest packing diameters feasible; if gravitational settling predominates, design for the largest packing diameters possible; if diffusion predominates, design for collector Reynolds numbers near 102. Some more general cases are also discussed. 相似文献
45.
Douglas W. Dockery James H. Ware Benjamin G. Ferris Jr. Frank E. Speizer Nancy R. Cook Stanislaw M. Herman 《Journal of the Air & Waste Management Association (1995)》2013,63(9):937-942
Pulmonary function of approximately 200 school children in Steubenville, OH was measured before and immediately following air pollution alerts in the fall of 1978 and 1979. TSP concentrations exceeded the National Primary Ambient Air Quality 24 h standards in 1978. SO2 exceeded the standard in 1979. The children were then reexamined in three weekly visits following each alert. Estimated mean Forced Vital Capacity (FVC) was approximately 2% lower following each alert, although the lowest means were observed one to two weeks after the episodes. Forced Expired Volume in 0.75 sec (FEV0.75) did not change during the 1978 study, but was 4% lower immediately following the 1979 alert. The children were measured again in five weekly examinations in the spring and fall of 1980. Air pollution levels did not exceed the standards on either occasion. In the spring of 1980, estimated mean FVC and FEV0.75 showed a decline similar to that observed following the alerts in 1978 and 1979. In the fall of 1980, there were no significant differences in the estimated mean FVC or FEV0.75 between the examinations. A total of 335 children were tested in the four studies, including 194 who participated in more than one study. The evidence for each child from all the studies was combined in a regression analysis of pulmonary function on TSP and SO2 average concentrations in the previous 24 h. The distribution of the individual regression coefficients was centered significantly below zero, implying a decrease in pulmonary function with increasing TSP and SO2 concentrations. The magnitude of the median change was less than 1% of the mean FVC and FEV0.75 over the range of TSP and SO2 concentrations observed. 相似文献
46.
Douglas W. Grosse 《Journal of the Air & Waste Management Association (1995)》2013,63(5):603-614
The U.S. Congress and the U.S. Environmental Protection Agency believe that treatment and recovery techniques should be given maximum priority when considering methods for managing the nation's generated hazardous waste. A prohibition for the disposal of certain categories of hazardous wastes either directly onto or into the land without being treated to an accepted degree prior to such disposal practice has been promulgated.1 Wastes containing toxic metals and cyanide complexes have been selected as a group to be restricted. Due to the high generation rate associated with this category, a large capacity of waste treatment processing will be required. Existing and emerging treatment alternatives which are or have the potential to be employed for waste treatment of metal bearing wastes are presented in this paper. 相似文献
47.
Globally, urban growth will add 1.5 billion people to cities by 2030, making the difficult task of urban water provisions
even more challenging. In this article, we develop a conceptual framework of urban water provision as composed of three axes:
water availability, water quality, and water delivery. For each axis, we calculate quantitative proxy measures for all cities
with more than 50,000 residents, and then briefly discuss the strategies cities are using in response if they are deficient
on one of the axes. We show that 523 million people are in cities where water availability may be an issue, 890 million people
are in cities where water quality may be an issue, and 1.3 billion people are in cities where water delivery may be an issue.
Tapping into groundwater is a widespread response, regardless of the management challenge, with many cities unsustainably
using this resource. The strategies used by cities deficient on the water delivery axis are different than for cities deficient
on the water quantity or water quality axis, as lack of financial resources pushes cities toward a different and potentially
less effective set of strategies. 相似文献
48.
Douglas A. Wilcox 《Environmental management》1989,13(3):365-370
The east-west density gradient and the pattern and mode of migration of the wetland exotic, purple loosestrife (Lythrum salicaria L.), were assessed in a survey of populations along the New York State Thruway from Albany to Buffalo to determine if the highway corridor contributed to the spread of this species. During the peak flowering season of late July to early August, individual colonies of purple loosestrife were identified and categorized into three size classes in parallel belt transects consisting of the median strip and highway rights-of-way on the north and south sides of the road. Data were also collected on the presence of colonies adjacent to the corridor and on highway drainage patterns. Although a distinct east-west density gradient existed in the corridor, it corresponded to the gradient on adjacent lands and was greatly influenced by a major infestation at Montezuma National Wildlife Refuge. The disturbed highway corridor served as a migration route for purple loosestrife, but topographic features dictated that this migration was a short-distance rather than long-distance process. Ditch and culvert drainage patterns increased the ability of purple loosestrife to migrate to new wetland sites. Management strategies proposed to reduce the spread of this wetland threat include minimizing disturbance, pulling by hand, spraying with glyphosate, disking, and mowing.Contribution 719 of the National Fisheries Research Center-Great Lakes, US Fish and Wildlife Service, 1451 Green Road, Ann Arbor, Michigan 48105, USA. 相似文献
49.
Amleto A. Pucci Douglas A. Harriman Elisabeth M. Ervin Lisa Bratton Alison Gordon 《Journal of the American Water Resources Association》1989,25(6):1267-1272
ABSTRACT: The U.S. Geological Survey collected ground-water samples from the upper and middle aquifers of the Potomac-Raritan-Magothy aquifer system in a 400-square-mile area of New Jersey from 1984 through 1986. Concentrations of lead were greater than the U.S. Environmental Protection Agency maximum contaminant level (MCL) of 50 micrograms per liter in water from 16 of 239 wells. The cencentrations of cadmium were greater than the MCL of 10 micrograms per liter in water from 10 to 241 wells. One-half of the wells that exceeded the lead MCL were in known areas of saltwater intrusion, as were all 10 wells that exceeded the cadmium MCL. The association of elevated concentrations of these metals with elevated concentrations of chloride indicates a mochanism related to saltwater intrusion. 相似文献
50.
Douglas Gunnison John W. Barko 《Journal of the American Water Resources Association》1989,25(1):193-201
ABSTRACT: This article, based on a review of the literature, examines several aspects of the rhizosphere ecology of submersed macrophytes. These include the role of the rhizosphere microflora in affecting plant growth through influences on nutrient availability and production of plant growth regulating compounds. Interactions between components of the sediment microflora and plant roots are considered in relation to plant nitrition and growth. Possible applications of this information to the management of submersed macrophytes are considered. 相似文献