The study of ultrasound-assisted oxidative desulfurization process applied to the utilization of pyrolysis oil from waste tires

In recent years, the increasing world population and rapid industrial development has increased the consumption of fossil fuel-derived oils. In response to the resulting exhaustion of fossil fuel energy, many countries around the world are investigating methods of waste energy recovery and reuse, including oil recovery from the pyrolysis process of waste tires. This study investigates the efficiency of an ultrasound-assisted oxidative desulfurization (UAOD) process in sulfur reduction from diesel oil and the pyrolysis oil from waste tires treatment. The results indicate that the oxidation efficiency increases as the doses of transition metal catalyst are increased. Longer sonication time also enhances the oxidation process, apparently through the biphasic transfer of oxidants, which results in a high yield of organic sulfur oxidation products. The best desulfurization efficiency was 99.7% (2.67 ppm sulfur remaining) and 89% (800 ppm sulfur remaining) for diesel and pyrolysis oils, respectively, via a process executed by two UAOD units connected in series and combined with solid adsorption using 30 g of Al₂O₃ in 6 cm columns. These batch experiment results demonstrate clean waste energy recovery and utilization, while fulfilling the requirements of Taiwan EPA environmental regulations (sulfur concentrations less than 5000 ppm).     

Synthesis of mesoporous magnesium oxide: Its application to CO2 chemisorption

Mesoporous magnesium oxide (MgO) was synthesized using mesoporous carbon CMK-3 obtained from mesoporous SBA-15 as exotemplate. P123 was used as the structure-directing template and rice husk ash (RHA) as the silica source for the synthesis of SBA-15, which was subsequently treated with sucrose and sulphuric acid to obtain mesoporous carbon (CMK-3). X-ray powder diffraction (XRD) results and the type-IV adsorption isotherm with H1 hysteresis obtained by N₂ adsorption/desorption study for SBA-15, CMK-3 and mesoporous MgO suggests its resemblance with materials synthesized using conventional silica sources. Mesoporous MgO was subjected for CO₂ adsorption study in TGA; adsorption was 8 and 10 wt% at 25 and 100 °C, respectively. Finally, mesoporous MgO is selective to CO₂ gas, thermally stable and regenerable. Thus, this study contributes a better route to enhance CO₂ gas adsorption and use ecological waste rice husk for the synthesis of such efficient mesoporous materials.     

Anthropogenic mercury emission inventory with emission factors and total emission in Korea

Mercury emissions concentrations, emission factors, and the total national emission from major anthropogenic sources in Korea for the year 2007 were estimated. Uncontrolled and controlled mercury emission factors and the total emission from each source types are presented. The annual national mercury emission from major anthropogenic sources for the year 2007, on average was 12.8 ton which ranged from 6.5 to 20.2 ton. Averaged emissions of elemental, oxidized, and particulate mercury were estimated at 8.25 ton, 3.69 ton, and 0.87 ton, respectively. Due to the removal of a major portion of particulate and oxidized mercury species, elemental mercury was dominant in stack emission. About 54.8% of mercury emission was contributed by industrial sources, 45.0% by stationary combustion sources and 0.02% by mobile sources. Thermal power plants, oil refineries, cement kilns and incinerators (municipal, industrial, medical, sewage sludge) were the major mercury emitters, contributing about 26%, 25%, 21% and 20%, respectively to the total mercury emission. Other sources (crematory, pulp and paper manufacturing, nonferrous metals manufacturing, glass manufacturing) contributed about 8% of the total emission. Priority should be given in controlling mercury emissions from coal-fired power plants, oil refineries, cement kilns and waste incinerators. More measurements including natural and re-emission sources are to be carried out in the future in order to have a clear scenario of mercury emission from the country and to apply effective control measures.     

Comparison of portable and onboard navigation system for the effects in real driving

Navigation systems are very useful and popular tools which display a user’s location and make use of graphics, text and voice information to guide him to a predetermined destination. Recently, some researches had revealed that drivers choose to receive driving directions using portable devices owing to their price and convenience. This study aimed to survey whether the driving efficiency and controlling are different as using portable and onboard navigation systems. A smartphone (2.7″ screen) and driving support system we instructed (8.9″ display interface) were adopted as the portable and onboard navigation systems respectively. Thirty subjects were paid to participate in this study, and field experiments were executed in urban and rural environments. Participants were randomly divided into two groups with equal numbers and drove according to instructions provided by one of these systems. The results indicated that the performance of drivers using the portable navigation system is better than that of the onboard one, in terms of efficiency and car handling, both in the urban and rural environments, despite the fact that the display screen of the phone is so small.     

APPLYING GRADIENT PROJECTION AND CONJUGATE GRADIENT TO THE OPTIMUM OPERATION OF RESERVOIRS1

The recent versions of nonlinear programming techniques such as the conjugate gradient and the gradient projection algorithms are used to obtain the optimal operating conditions of a multiple reservoirs system with multiple purposes. These algorithms are compared with other techniques in the literature. The conjugate gradient method incorporates the advantages of both the generalized Newton-Raphson, also known as the quasilinearization technique, and the gradient approach while avoiding their major drawbacks. To illustrate the technique, a water resources system with three reservoirs and a tabular objective function is solved by the two algorithms.     

Evaluation of surface water quality impacts of hazardous chemical sites

Common deficiencies in the typical evaluation of the surface water quality impacts of hazardous chemical sites are discussed. Particular attention is given to deficiencies in monitoring stormwater runoff, as well as the input of contaminated groundwaters that lead to impairment of the beneficial uses of nearby surface waters because of site-derived hazardous and deleterious chemicals. An alternative approach, Evaluation Monitoring, is presented in this paper. Evaluation Monitoring shifts the monitoring program from periodic sampling and analysis of stormwater runoff and ambient waters for a suite of chemical parameters, to examining the receiving waters to determine what, if any, water quality use impairments are occurring in surface waters due to the runoff-associated constituents and shallow groundwater input.