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641.
642.
This article outlines the general design concepts and new chemistry necessary to achieve truly cost-effective management of an important part of the hazardous waste incineration system—i.e., the unit operations needed to treat wastewater generated by rotary kiln incinerators burning wastes containing halogens and heavy metals. 相似文献
643.
The estimation of octanol/water coefficients by means of chromatographic and structural parameters may be a useful method for the prediction of ecotoxicological behaviour of chemical compounds. Experimental aspects and validity of some parameters are discussed with respect to heterocyclic aromatic hydrocarbons, including benzofurans. It is concluded that reverse phase chromatographic systems and molecular connectivities are promising predictors of log Kow. 相似文献
644.
645.
Francesco Bagordo Tiziana Grassi Adele Idolo Francesca Serio Giovanni Gabutti Antonella De Donno 《Food and environmental virology》2013,5(3):169-175
The purpose of this study was to evaluate “in field” the accumulation of virus in shellfish and compare it with the concentration of bacterial indicators. Individuals of Mytilus galloprovincialis were placed in two sampling station located in a contaminated coastal bay and in one control station located one kilometer offshore. The presence of Rotavirus and E. coli was assessed weekly both in seawater and in shellfish samples. The Rotavirus genome was detected in water, preliminarily concentrated by tangential flow ultrafiltration method, and in hepatopancreas of mussels by Real-Time PCR. E. coli was enumerated in water matrices by a filtering method and in mussels by the MPN method. Rotaviruses were not recorded in seawater, while in mussels they were detected since third week after placement. E. coli in mussels were always below the limits set in the Regulation (EC) 854/2004. This study suggests the need for a viral indicator to insure the safety for consumption of shellfish. 相似文献
646.
The possibility of transforming waste plastics into valuable hydrocarbons via catalytic cracking and reforming is attracting
increasing interest. Pyrolysis coupled with Gas Chromatographic separation and Mass Spectrometry detection (Py-GC/MS) has
been used in this work to study the product selectivity of various catalysts in the conversion of pure and residual polyethylene
samples into hydrocarbon products. Five acid solids of comparable aluminium contents but different textural and acid properties
were tested as catalysts, including three zeolites (standard ZSM-5, nanocrystalline n-ZSM-5 and Beta) and two mesostructured
solids (Al-MCM-41 and Al-SBA-15). Thermal cracking of the pure and residual polymers generated a similar range of products
to each other, with a high proportion of linear paraffins and olefins of varying lengths. The presence of zeolitic materials
resulted in complete elimination of heavy linear products, an increase in the light hydrocarbon fraction and a marked selectivity
towards the formation of single-ring aromatic species, particularly benzene, toluene and xylene. Aromatic formation was particularly
notable with the small crystal size n-ZSM-5 (aromatic selectivity up to 53.9%) and less marked in the case of standard ZSM-5
(up to 36.4%) and Beta zeolite (up to 35.0%). Mesostructured catalysts like Al-MCM-41 and Al-SBA-15 favoured the production
of light C2–C5 hydrocarbons (up to 57.9%) while the formation of aromatic products was significantly lower than with zeolitic materials.
The paper examines the extent and the causes for this product selectivity and discusses its connection with the acid and textural
properties of each catalyst. It was also observed that, under the experimental conditions employed, the products generated
were not significantly affected by the nature and origin of the polymers employed. 相似文献
647.
Superoxide production by marine microalgae 总被引:5,自引:0,他引:5
Judith-Anne?MarshallEmail author Miguel?de?Salas Tatsuya?Oda Gustaaf?Hallegraeff 《Marine Biology》2005,147(2):533-540
A survey was conducted for production of the reactive oxygen species superoxide by 37 species (65 strains) of microalgae including dinoflagellates, raphidophytes, chlorophytes, prasinophytes, eustigmatophytes and prymnesiophytes. Ichthyotoxic raphidophyte species of Chattonella were found to produce the highest environmental levels of superoxide (177×104 total chemiluminescence units). However, ichthyotoxic dinoflagellates (Karenia, Alexandrium) and the prymnesiophyte Prymnesium were also found to produce significant levels of superoxide (4×104, 3×104 and 5×104 chemiluminescence units, respectively), equivalent to that of other raphidophyte species of Heterosigma and Fibrocapsa (6×104 and 2×104, respectively). A direct relationship between cell size and superoxide production was observed (r2=0.94), with larger cells producing more superoxide per cell. Chattonella produced the most superoxide per cell (expressed as cellular chemiluminescence units), followed by the dinoflagellate species Karenia, Alexandrium, Takayama and Gymnodinium. Small cells, such as the raphidophyte Heterosigma and the prymnesiophyte Prymnesium produced very little superoxide per cell (cellular chemiluminescence units), but potentially could still produce high total levels of superoxide if present at high biomass levels. Species commonly used as aquaculture bivalve feeds such as Dunaliella, Tetraselmis, Nannochloropsis and Pavlova produced negligible levels of superoxide, even at high biomass. We speculate that superoxide, while not the sole ichthyotoxic principle, may play a wider role in algal toxicity than previously considered, and propose a broad classification of microalgae based upon superoxide production.Communicated by M.S. Johnson, Crawley 相似文献
648.
Velini ED Galo ML Carvalho FT Martins D Cavenaghi AL Trindade ML Bravin LF Negrisoli E Antuniassi UR Simionato JL Santos SC 《Journal of environmental science and health. Part. B》2005,40(1):85-100
The general objective of this work was to develop a monitoring and management model for aquatic plants that could be used in reservoir cascades in Brazil, using the reservoirs of AES-Tietê as a study case. The investigations were carried out at the reservoirs of Barra-Bonita, Bariri, Ibitinga, Promiss?o, and Nova-Avanhandava, located in the Tietê River Basin; Agua Vermelha, located in the Grande River Basin; Caconde, Limoeiro, and Euclides da Cunha, which are part of the Pardo River Basin; and the Mogi-Gua?u reservoir, which belongs to the Mogi-Gua?u River basin. The main products of this work were: development of techniques using satellite-generated images for monitoring and planning aquatic plant control; planning and construction of a boat to move coating plant masses and an airboat equipped with a DGPS navigation and application flow control system. Results allowed to conclude that the occurrence of all types of aquatic plants is directly associated with sedimentation process and, consequently, with nutrient and light availability. Reservoirs placed at the beginning of cascades are more subject to sedimentation and occurrence of marginal, floating and emerged plants, and are the priority when it comes to controlling these plants, since they provide a supply of weeds for the other reservoirs. Reservoirs placed downstream show smaller amounts of water-suspended solids, with greater transmission of light and occurrence of submerged plants. 相似文献
649.
We report the chemical composition of PM10-associated water-soluble species in Mexico City during the second semester of 2000. PM10 samples were collected at four ambient air quality monitoring sites in Mexico City. We determined soluble ions (chloride, nitrate, sulfate, ammonium, sodium, potassium), ionizable transition metals (Zn, Fe, Ti, Pb, Mn, V, Ni, Cr, Cu) and soluble protein. The higher PM(10) levels were observed in Xalostoc (45-174 microg m(-3)) and the lowest in Pedregal (19-54 microg m(-3)). The highest SO2 average concentrations were observed in Tlalnepantla, NO2 in Merced and O3 and NO(x) in Pedregal. The concentration range of soluble sulfate was 6.7-7.9 and 19-25.5 microg m(-3) for ammonium, and 14.8-29.19 for soluble V and 3.2-7.7 ng m(-3) for Ni, suggesting a higher contribution of combustion sources. PM-associated soluble protein levels varied between 0.038 and 0.169 mg m(-3), representing a readily inhalable constituent that could contribute to adverse outcomes. The higher levels for most parameters studied were observed during the cold dry season, particularly in December. A richer content of soluble metals was observed when they were expressed by mass/mass units rather than by air volume units. Significant correlations between Ni-V, Ni-SO4(-2), V-SO4(-2), V-SO2, Ni-SO2 suggest the same type of emission source. The variable soluble metal and ion concentrations were strongly influenced by the seasonal meteoclimatic conditions and the differential contribution of emission sources. Our data support the idea that PM10 mass concentration by itself does not provide a clear understanding of a local PM air pollution problem. 相似文献
650.
Temporal variations of polycyclic aromatic hydrocarbon (PAH) concentrations in leaves of a Mediterranean evergreen oak, Quercus ilex L., were investigated in order to assess the suitability of this species to biomonitor PAH air contamination. Leaf samples were collected at six sites of the urban area of Naples (Italy) and at a control site in the Vesuvius National Park, in May and September 2001, and in January and May 2002. PAH extraction was conducted by sonication in dichloromethane-acetone and quantification by GC-MS. In winter, leaf total PAH concentrations showed, at all the urban sites, values 2-fold higher than in all the other samplings, reflecting the temporal trend reported for PAH air contamination in the Naples urban area. Moreover, leaf PAH concentrations showed, at all the urban sites, a decrease in May 2002 after the winter accumulation. At the control site leaf PAH concentrations showed lower values and smaller temporal variations than at the urban sites. The findings support the suitability of Q. ilex leaves to monitor temporal variations in PAH contamination. The highest winter concentrations of total PAHs were due to the medium molecular weight PAHs that increased with respect to both low and high molecular weight PAHs. The medium molecular weight PAHs showed the same temporal trend both at the urban and remote sites. 相似文献