Abiotic transformation of DDT in aqueous solutions

Significant concentrations of chlorinated pesticides such as 1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethane (DDT) and its two main transformation products, 1,1-dichloro-2,2-bis(4-chlorophenyl)ethane (DDD) and 1,1-dichloro-2,2-bis(4-chlorophenyl)ethylene (DDE) are still present in soil and sediment systems more than 30 years after DDT use was banned in the United States. DDT enters waterways via the runoff from industrial point sources, agricultural lands and atmospheric deposition. We evaluated zero-valent iron (Fe(0)), ferrous sulfide (FeS), as well as combining them with hydrogen peroxide (H(2)O(2)) as viable treatment technologies for degrading DDT in an aqueous solution. Treatment of DDT with Fe(0) and FeS resulted in approximately 88% and 56% transformation of DDT within 150h, respectively. DDE production was insignificant in all systems. The DDT removal was slower with FeS than with Fe(0), but the amounts of DDD and DDE produced did not exceed baseline. Treatment with a 1:1 mixture of Fe(0)-FeS removed about 95% of the added mass of DDT within 4days and generated significant amounts of DDD and minor amounts of DDMU. When small amounts of H(2)O(2) were introduced halfway through the Fe(0) and FeS treatment times, the mass of DDT decreased by 87% and 96%, respectively, within 2days. Our results demonstrate that mixtures of Fe(0)-FeS in combination with H(2)O(2) can be used for rapid and efficient removal of DDT from aqueous solutions.     

Chronic toxicity of sediment-associated linear alkylbenzene sulphonates (LAS) to freshwater benthic organisms

The toxicity of linear alkylbenzene sulphonates (LAS), to freshwater benthic organisms was assessed during exposure to spiked sediment. Lethal and sub-lethal end-points were monitored for two organisms (oligochaete Lumbriculus variegatus and nematode Caenorhabditis elegans). Results demonstrated relatively low toxicity (LOECs>100 mg/kg dry weight). No observed effect concentrations (NOECs) of 81 mg/kg dw (Lumbriculus) and 100 mg/kg dw (Caenorhabditis) were determined. For the oligochaete, no specific endpoint was particularly sensitive to LAS. For the nematode, egg production was the most sensitive endpoint. Significant degradation was measured over the 28-day duration of the Lumbriculus study, equating to a half-life of 20 days in sediment.     

Offspring size effects mediate competitive interactions in a colonial marine invertebrate

Over the past 30 years, numerous attempts to understand the relationship between offspring size and fitness have been made, and it has become clear that this critical relationship is strongly affected by environmental heterogeneity. For marine invertebrates, there has been a long-standing interest in the evolution of offspring size, but there have been very few empirical and theoretical examinations of post-metamorphic offspring size effects, and almost none have considered the effect of environmental heterogeneity on the offspring size/fitness relationship. We investigated the post-metamorphic effects of offspring size in the field for the colonial marine invertebrate Botrylloides violaceus. We also examined how the relationship between offspring size and performance was affected by three different types of intraspecific competition. We found strong and persistent effects of offspring size on survival and growth, but these effects depended on the level and type of intraspecific competition. Generally, competition strengthened the advantages of increasing maternal investment. Interestingly, we found that offspring size determined the outcome of competitive interaction: juveniles that had more maternal investment were more likely to encroach on another juvenile's territory. This suggests that mothers have the previously unrecognized potential to influence the outcome of competitive interactions in benthic marine invertebrates. We created a simple optimality model, which utilized the data generated from our field experiments, and found that increasing intraspecific competition resulted in an increase in predicted optimal size. Our results suggest that the relationship between offspring size and fitness is highly variable in the marine environment and strongly dependent on the density of conspecifics.     

Meta-analysis of nitrogen removal in riparian buffers

Riparian buffers, the vegetated region adjacent to streams and wetlands, are thought to be effective at intercepting and reducing nitrogen loads entering water bodies. Riparian buffer width is thought to be positively related to nitrogen removal effectiveness by influencing nitrogen retention or removal. We surveyed the scientific literature containing data on riparian buffers and nitrogen concentration in streams and groundwater to identify trends between nitrogen removal effectiveness and buffer width, hydrological flow path, and vegetative cover. Nitrogen removal effectiveness varied widely. Wide buffers (>50 m) more consistently removed significant portions of nitrogen entering a riparian zone than narrow buffers (0-25 m). Buffers of various vegetation types were equally effective at removing nitrogen but buffers composed of herbaceous and forest/herbaceous vegetation were more effective when wider. Subsurface removal of nitrogen was efficient, but did not appear to be related to buffer width, while surface removal of nitrogen was partly related to buffer width. The mass of nitrate nitrogen removed per unit length of buffer did not differ by buffer width, flow path, or buffer vegetation type. Our meta-analysis suggests that buffer width is an important consideration in managing nitrogen in watersheds. However, the inconsistent effects of buffer width and vegetation on nitrogen removal suggest that soil type, subsurface hydrology (e.g., soil saturation, groundwater flow paths), and subsurface biogeochemistry (organic carbon supply, nitrate inputs) also are important factors governing nitrogen removal in buffers.     

Predicting the Thermal Effects of Dam Removal on the Klamath River

The Klamath River once supported large runs of anadromous salmonids. Water temperature associated with multiple mainstem hydropower facilities might be one of many factors responsible for depressing Klamath salmon stocks. We combined a water quantity model and a water quality model to predict how removing the series of dams below Upper Klamath Lake might affect water temperatures, and ultimately fish survival, in the spawning and rearing portions of the mainstem Klamath. We calibrated the water quantity and quality models and applied them for the hydrometeorological conditions during a 40-year postdam period. Then, we hypothetically removed the dams and their impoundments from the models and reestimated the rivers water temperatures. The principal thermal effect of dam and reservoir removal would be to restore the timing (phase) of the rivers seasonal thermal signature by shifting it approximately 18 days earlier in the year, resulting in river temperatures that more rapidly track ambient air temperatures. Such a shift would likely cool thermal habitat conditions for adult fall chinook (Oncorhynchus tshawytscha) during upstream migration and benefit mainstem spawning. By contrast, spring and early summer temperatures could be warmer without dams, potentially harming chinook rearing and outmigration in the mainstem. Dam removal might affect the rivers thermal regime during certain conditions for over 200 km of the mainstem.     

Monitoring the Response of Butterfly Communities to Prescribed Fire

Federal land managers in the western United States are interested in the potential of prescribed fire as a tool to decrease fuel loads, increase vegetational heterogeneity, and increase faunal diversity in various ecosystems. I tested whether implementation of a prescribed fire program by the US Forest Service in a watershed in the central Great Basin had significant effects on butterfly species richness and composition. I monitored butterfly communities during the first two years after implementation in five to seven burn units and controls in the watershed. To estimate baseline spatial and temporal variation in butterfly communities in the greater ecosystem, I also monitored butterflies in five untreated canyons outside the project area. Butterfly species richness and butterfly species composition (measured as community similarity) did not differ significantly between burn units and controls. Geographic location had statistically significant effects on species richness. Butterfly species composition of individual locations varied over time, as did the magnitude of that variation. These results emphasize that standardized, repeatable monitoring protocols are vital for evaluating the effects of experimental management treatments and for predicting and assessing the effects of future management strategies and environmental changes.     

Evidence for trans-cuticular uptake of HNO3 vapor by foliage of Eastern white pine (Pinus strobus L.)

Forest declines in Europe and the northeastern United States are widely believed to be associated with deposition of air pollutants, perhaps including nitric acid vapor. The experiments presented here, which were conducted in indoor chambers, involved measurement of steady-state rates of nitric acid deposition on foliage of seedlings of eastern white pine. Nitric acid concentrations ranged from 37 to 1260 ppb, but were mostly in the 130-180 ppb range. Between 130 and 180 ppb, much of the deposited nitric acid could be removed by washing leaf surfaces with water. Amounts of nitrate removed by washing increased with exposure duration to a maximum of 7.6 nmol cm(-2) after about 8 h. Although nitrate concentrations in the washings remained constant after 8 h, nitric acid deposition nonetheless continued at a steady-state rate. We have termed this steady-state deposition 'trans-cuticular' on the assumption that the nitric acid diffuses through the cuticle. Resistance to trans-cuticular uptake (69 m(2) s mol(-1)) far exceeded resistance to diffusion across the unstirred layer at the surface of the leaf (5 m(2) s mol(-1)). High concentrations used in these experiments preclude quantitative extrapolation to ambient conditions; however, we have demonstrated that the white pine cuticle is both a major storage pool and a major barrier to uptake of deposited nitric acid.     

Phytoplankton distribution along the eastern coast of the USA. I. Phytoplankton composition

The composition of phytoplankton and the general distribution patterns of the major taxonomic groups are discussed for the eastern coastal waters of the USA. A species list of 609 phytoplankters is given with dominant cold- and warm-water forms noted along the coast. The ubiquitous species along the east coast were Skeletonema costatum, Thalassionema nitzschioides, and Coccolithus huxleyi.     

Nutrient and trace elements in soil and desert vegetation of southern Idaho

Concentrations of thirty elements were measured in strong-acid extracts of soil, sagebrush (Artemisia tridentata spp.) leaves and perennial grass from the Idaho National Engineering Laboratory (INEL) and two reference sites in southern Idaho. A bicarbonate-chelating extract of soil was used to estimate plant-available concentrations. The results provide baseline data prior to start-up of a coal-fired steam generation facility on the INEL and other developments in the region. In addition, existing impact from effluents from thirty years of a nuclear fuel reprocessing facility on the INEL was evaluated. Based on the spatial distribution of element concentrations, as well as comparison with references sites, we conclude that concentrations of Zn, and perhaps Ni, Cd, and V, are currently elevated around the fuel reprocessing facility. The spatial distribution of these elements is similar to that of ¹³⁷Cs in soil, a radionuclide which is emitted by the facility. Sagebrush and soil appear more responsive than perennial grass for long-term monitoring of element concentrations in this semi-arid environment.     

ENERGY,ENVIRONMENTAL, AND ECONOMIC IMPLICATIONS OF SOME RECENT ALBERTA WATER RESOURCES PROJECTS1

ABSTRACT: Most of us are aware, or feel we are aware, of the impacts of major water resources projects on our lives. “Dam-lovers” note the life-saving flood-risk reduction and recreational benefits of a proposed reservoir, while “dam-haters” bemoan the future drowning out of the wildlife habitat of its river valley, and the recreational disbenefits to stream (as opposed to lake) fishermen. Water supply projects can often be given such a revered status, assuming the “obvious” tenet that water, air, food, and shelter are basic requirements of decent living, that the economic viability of the project may not even be assessed. Water resources planners are supposed to impartially weigh the environmental and economic benefits, and especially now, the energy implications of all proposed water projects, but many times the partial views of political or public advocates may be hard to ignore. The assumptions used in the planning of four recent water projects in the Province of Alberta will be presented and some revisions suggested which materially affect their Benefit/Cost ratios. In one project that is still in the public hearing stage, the economic analysis will be revealed, indicating that the original B/C ratio of about 1.6:1 might be more realistically placed at 0.6:1. In another project just completed, the apparent lack of an economic or energy analysis that has resulted in a perpetual and unnecessary energy load on the province, will be described.